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Abstract Coal gasification is accompanied with formation of tars that cause equipment problems and have to be removed from the raw gas. Our previous studies proved that nickel supported ceria-zirconia catalyst (Ni/CZ) reveals high activity towards decomposition of toluene and 1-methylnaphthalene (1-MN) via steam reforming reaction (SR). However, the components of the raw gas from coal gasification (i.e. H2, CO, CO2 and CH4) may influence the performance of Ni/CZ catalyst. The influence of particular components of the raw gas on catalyst performance during SR of model tar compounds have been studied and discussed in this paper. It has been found that H2 and CO addition to the steam reforming feed drastically decreases the activity of Ni/CZ catalyst, whereas CO2 presence enhances conversion of toluene and 1-MN mixture owing to the occurrence of dry reforming reaction (DR). It has also been observed that methane, which is present in the raw gas from coal gasification consumes partly both the H2O and CO2, causing some decrease in conversion of model tar compounds. The influence of contact time (tc) on hydrocarbons conversion and the participation of (DR) have been examined. As was observed, lower contact times lead to decrease in hydrocarbons conversion in SR, making the same participation of DR more pronounced than for higher tc values. This work proves that Ni/CZ catalyst can be used for removal of tarry compounds via the catalytic hot gas cleaning of the raw gas form coal gasification.

AbstractA bioreactor system composed of a stirred tank and three tubular bioreactors in series was established, and continuous ethanol fermentation was carried out using a general Saccharomyces cerevisiae strain and a very high gravity medium containing 280 g L−1 glucose, supplemented with 5 g L−1 yeast extract and 3 g L−1 peptone. Sustainable oscillations of glucose, ethanol, and biomass were observed when the tank was operated at the dilution rate of 0.027 h−1, which significantly affected ethanol fermentation performance of the system. After the tubular bioreactors were packed with 1/2″ Intalox ceramic saddles, the oscillations were attenuated and quasi‐steady states were achieved. Residence time distributions were studied for the packed bioreactors by the step input response technique using xylose as a tracer, which was added into the medium at a concentration of 20 g L−1, indicating that the backmixing alleviation assumed for the packed tubular bioreactors could not be established, and its contribution to the oscillation attenuation could not be verified. Furthermore, the role of the packing's yeast cell immobilization in the oscillation attenuation was investigated by packing the tubular bioreactors with packings with significant difference in yeast cell immobilization effects, and the experimental results revealed that only the Intalox ceramic saddles and wood chips with moderate yeast cell immobilization effects could attenuate the oscillations, and correspondingly, improved the ethanol fermentation performance of the system, while the porous polyurethane particles with good yeast cell immobilization effect could not. And the viability analysis for the immobilized yeast cells illustrated that the extremely lower yeast cell viability within the tubular bioreactors packed with the porous polyurethane particles could be the reason for their inefficiency, while the yeast cells loosely immobilized onto the surfaces of the Intalox ceramic saddles and wood chips could be renewed during the fermentation, guaranteeing their viability and making them more efficient in attenuating the oscillations. The packing Raschig rings without yeast cell immobilization effect did not affect the oscillatory behavior of the tubular bioreactors, further supporting the role of the yeast cell immobilization in the oscillation attenuation. Biotechnol. Bioeng. 2009;102: 113–121. © 2008 Wiley Periodicals, Inc.

Abstract Specification by central government of the heating levels which are to be maintained in British school buildings has recently been altered. This paper is concerned with examining the nature of changes that have been made by comparing present requirements with their counterparts during the preceding one hundred years. Attention is focused on the apparently contradictory implications of these changes for those charged with responsibility for maintaining heating levels in school buildings while, at the same time, conserving fuel. It is suggested that the new statutory requirements present those who are responsible with a duty which may, in practical terms, prove difficult or costly to discharge. Although discussion is specifically restricted to British school buildings, issues are raised which are pertinent to attempts to integrate regulation of heating with control of fuel consumption in other types of non-domestic buildings both in Britain and abroad.

In order to enhance the efficiency and benefits of the sludge anaerobic digestion process, K2FeO4 was added to a sludge anaerobic digestion system, and its effects on the system were comprehensively investigated. Results showed that sludge anaerobic digestion was greatly improved by adding 500 mg/L K2FeO4. Biogas and methane productions were increased by 26.6 and 28.4%, respectively. Sludge reduction, protein removal, and the conversion efficiency of dissolved organics were all improved. The mechanism revealed that the disintegration of sludge flocs, enhancement of protease activity, and decrease of soluble sulfide toxicity on microorganisms contributed to biogas production and sludge reduction. Biogas quality was improved, benefitting from the decreasing H2S content in biogas; as additionally, the cost of biogas desulfuration was reduced. In the biogas slurry treatment, the PO43--P concentrations were decreased by 39%, which also reduced the cost of the dephosphorization processes at certain extent.

Abstract Real-world vehicle operating mode data (2.5 million 1 Hz records), collected by instrumenting the vehicles of 82 volunteer drivers with OBD datalogger and GPS while they drove their routine travel routes, were analyzed to quantify vehicle emissions estimate errors due to road grade and driving style in rural, hilly Vermont. Data were collected in winter and summer for MY 1996 and newer passenger cars and trucks only. EPA MOVES2010b was used to estimate running exhaust emissions associated with measured vehicle activity. Changes in vehicle specific power (VSP) and MOVES operating mode (OpMode) due to proper accounting for real-world road grade indicated emission rate errors between 10% and 48%, depending on pollutant, chiefly because grade-related changes in VSP could shift activity by as many as six OpModes, depending on road type. The correct MOVES OpMode assignment was made only 33–55% of the time when road grade was not included in the VSP calculation. Driving style of individual drivers was difficult to assess due to unknown traffic operations data, but the largest differences between individual drivers were observed on rural restricted roads, where traffic conditions and control have minimal impact. The results suggest the importance of (1) measuring and incorporating real-world road grade in order to correctly assign MOVES emission rates; and (2) developing a driving style typology to account for differences in the MOVES emissions estimates due to driver variability.

Abstract This paper describes the point of view of a gas utility regarding systems for cooling and heating by solid sorption. Indeed, the context is favorable to the emergence of such systems first, of course, due to the regulatory constraints on certain refrigerant fluids, but also for their specific technical characteristics (the storage capacity, for example). The gas utilities have in fact shown an increasingly keen interest in all types of sorption systems, as a way of diversifying natural gas utilization, particularly in the summer. After a review of that context, this paper highlights the advantages of solid sorption and describes the criteria for choosing an installation in air conditioning and cooling production applications. Finally, it discusses the difficulties likely to be encountered in developing sorption systems, as well as the prospects for the future.

Abstract Process heaters are typically located outside and subject to the weather. Although heaters are typically tuned at a given set of conditions, actual operating conditions vary significantly from season to season and sometimes even within a given day. Unfortunately, most heaters are not properly adjusted for actual operating conditions. Ambient air temperature, pressure and humidity all significantly impact process heater efficiency. This paper shows how changing ambient conditions can reduce efficiency if proper adjustments are not made. Combustion efficiency is related to air:fuel ratio and to air–fuel mixing. A general industry rule-of-thumb is that operating at 2–3% excess O 2 (dry basis) results in the best combination of efficiency and flexibility. At higher O 2 levels, efficiency is reduced because the additional O 2 and N 2 absorb heat, much of which exits the exhaust stack. At lower O 2 levels, efficiency can be substantially reduced because some fuel is uncombusted. Low O 2 levels can also lead to soot and coke buildup on process tubes reducing heat transfer to the process fluid and reducing efficiency. Several examples demonstrate how ambient conditions affect heater efficiency. Calculations and graphs for a wide range of operating conditions demonstrate how efficiency can be affected by changes in ambient conditions for process heaters.

Abstract Distributed energy system becomes increasingly popular due to high efficiency and low pollution emissions. When it operates following the electricity load, thermal energy storage system can be used to accommodate surplus cooling and heating and improve the energy efficiency. This study investigates the energy and economic performance of thermal storage systems for surplus cooling and heating in distributed energy system, considering the impacts of climates, building combinations and cooling/heating supply systems. Results show that the thermal storage system can improve the primary energy efficiency and is more useful when residential buildings adopt centralized heating and decentralized cooling systems. By varying climates and building combinations, the thermal storage system can improve the primary energy efficiency by 0.28%–3.69%. The economic performance is not promising with a long payback period. The main reason is that the overall utilization rate of the surplus energy is low (less than 45%), especially when the cooling/heating load is low continually during spring and autumn. Additionally, the effect of static and dynamic thermal storage model is analyzed. Results show that the static model would over-estimate the performance of the thermal storage system significantly and the dynamic model is recommended.

Microbial production of ethanol might be a potential route to replace oil and chemical feedstocks. Bioethanol is by far the most common biofuel in use worldwide. Lignocellulosic biomass is the most promising renewable resource for fuel bioethanol production. Bioconversion of lignocellulosics to ethanol consists of four major unit operations: pretreatment, hydrolysis, fermentation, and product separation/distillation. Conventional bioethanol processes for lignocellulosics apply commercial fungal cellulase enzymes for biomass hydrolysis, followed by yeast fermentation of resulting glucose to ethanol. The fungus Neurospora crassa has been used extensively for genetic, biochemical, and molecular studies as a model organism. However, the strain's potential in biotechnological applications has not been widely investigated and discussed. The fungus N. crassa has the ability to synthesize and secrete all three enzyme types involved in cellulose hydrolysis as well as various enzymes for hemicellulose degradation. In addition, N. crassa has been reported to convert to ethanol hexose and pentose sugars, cellulose polymers, and agro-industrial residues. The combination of these characteristics makes N. crassa a promising alternative candidate for biotechnological production of ethanol from renewable resources. This review consists of an overview of the ethanol process from lignocellulosic biomass, followed by cellulases and hemicellulases production, ethanol fermentations of sugars and lignocellulosics, and industrial application potential of N. crassa.