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As a relatively mature technology, biomass molded fuel (BMF) is widely used in distributed and centralized heating in China and has received considerable government attention. Although many BFM incentive policies have been developed, decreased domestic traditional fuel prices in China have caused BMF to lose its economic viability and new policy recommendations are needed to stimulate this industry. The present study built a regionalized net present value (NPV) model based on real production process simulation to test the impacts of each policy factor. The calculations showed that BMF production costs vary remarkably between regions, with the cost of agricultural briquette fuel (ABF) ranging from 86 US dollar per metric ton (USD/t) to 110 (USD/t), while that of woody pellet fuel (WPF) varies from 122 USD/t to 154 USD/t. The largest part of BMF’s cost composition is feedstock, which accounts for up 50%–60% of the total; accordingly a feedstock subsidy is the most effective policy factor, but in consideration of policy implementation, it would be better to use a production subsidy. For ABF, the optimal product subsidy varies from 26 USD/t to 57 USD/t among different regions of China, while for WPF, the range is 36 USD/t to 75 USD/t. Based on the data, a regional BMF development strategy is also proposed in this study.

It is critical and challenging to develop high performance transition metal phosphides (TMPs) electrocatalysts for oxygen evolution reaction (OER) to address fossil energy shortages. Herein, we report the synthesis of Co2P embedded in N-doped porous carbon (Co2P@N-C) via a facile one-step strategy. The obtained catalyst exhibits a lower overpotential of 352 mV for OER at a current density of 10 mA cm−2 and a small Tafel slope of 84.6 mV dec−1, with long-time reliable stability. The excellent electrocatalytic performance of Co2P@N-C can be mainly owed to the synergistic effect between the Co2P and highly conductive N-C substrate, which not only affords rich exposed active sites but also promotes faster charge transfer, thus significantly promoting OER process. This work presents a promising and industrially applicable synthetic strategy for the rational design of high performance nonnoble metal electrocatalysts with enhanced OER performance.

Coal will continue to be the main energy source in China for the immediate future, although the environmental pollution and ecological impacts of each stage in the full life cycle of coal mining, transportation, and combustion generate large quantities of external costs. The Late Permian coals in southwestern (SW) China usually contain high amounts of fluorine (F), arsenic (As), and ash, which together with high-F clays cause abnormally high levels of endemic fluorosis, As poisoning, and lung cancer in areas where coal is mined and burned. In this paper, we estimate the external costs of the life cycle of coal. The results show that the externalities of coal in SW China are estimated at USD 73.5 billion or 284.3 USD/t, which would have accounted for 6.5 % of the provincial GDP in this area in 2018. The external cost of human health accounts for 87.2% of the total external costs, of which endemic skeletal fluorosis diseases and related lung cancers have the most important impact. Our study provides a more precise estimate of externalities compared with its counterparts in other provinces in China. Therefore, several policy recommendations would be proposed to internalize the external cost.

This paper proposes a polygeneration system based on a multi-input chemical looping combustion system, which generates methanol and electricity, through the use of natural gas and coal. In this system, the chemical looping hydrogen (CLH) production system and the coal-based methanol production system are integrated. A high quality fuel, natural gas, is used to improve the conversion ratio of coal. The Gibbs energy of the two kinds of fuels is fully used. Benefitting from the chemical looping process, 27% CO2 can be captured without energy penalty. With the same outputs of methanol and electricity, the energy savings ratio of the new system is about 12%. Based on the exergy analyses, it is disclosed that the integration of synthetic utilization of natural gas and coal plays a significant role in reducing the exergy destruction of the new system. The promising results obtained in this paper may lead to a clean coal technology that will utilize natural gas and coal more efficiently and economically.

Carbon capture and storage (CCS) is the most promising method of curbing atmospheric carbon dioxide levels from 2020 to 2050. Accurate predictions of geology and sealing capabilities play a key role in the safe execution of CCS projects. However, popular forecasting methods often oversimplify the process and fail to guide actual CCS projects in the right direction. This study takes a specific block in Shenhua, China as an example. The relative permeability of CO2 and brine is measured experimentally, and a multi-field coupling CO2 storage prediction model is constructed, focusing on analyzing the sealing ability of the block from the perspective of injection modes. The results show that when injected at a constant speed, the average formation pressure and wellbore pressure are positively correlated with the CO2 injection rate and time; when the injection rate is 0.5 kg/s for 50 years, the average formation pressure increases by 38% and the wellbore pressure increases by 68%. For different injection modes, the average formation pressures of various injection methods are similar during injection. Among them, the pressure increases around the well in the decreasing injection mode is the smallest. The CO2 concentration around the wellbore is the largest, and the CO2 diffusion range continues to expand with injection time. In summary, formation pressure increases with the increase in injection rate and injection time, and the decreasing injection mode has the least impact on the increase in formation pressure. The CO2 concentration is the largest around the well, and the CO2 concentration gradually decreases. The conclusion helps determine the geological carrying capacity of injection volumes and provides insights into the selection of more appropriate injection modes. Accurate predictions of CO2 storage capacity are critical to ensuring project safety and monitoring potentially hazardous sites based on reservoir characteristics.

The greenhouse’s energy consumption is a major limiting factor for output and development. To address this, it is necessary to adopt green and low-carbon heating technologies to replace traditional fuels. This will not only help conserve energy but will also reduce emissions, thereby improving the thermal environmental conditions for agriculture. This paper aims to research and develop a vertical heat exchange tube array device specifically designed for greenhouses. The focus is on enhancing the passive heat absorption and heat storage efficiency of the device and its influence on the thermal environment of the greenhouse. In order to improve the heat absorption and storage efficiency of the heat exchanger device and its impact on the greenhouse thermal environment, experimental comparative analysis was conducted using air, water, and phase-change materials as working fluids inside the pipes. Through a combination of experiments and simulations, it was verified that the heat exchanger device is capable of actively regulating the greenhouse thermal environment. The results show that heat exchangers of all three types of working fluids can effectively improve the stability of soil temperature and play a “shifting the peak and filling the valley” role in regulating the indoor air temperature while positively regulating the relative humidity of the air. Notably, when the working fluid is a phase-change material, it has the most significant impact on the thermal environment of the greenhouse.

Nuclear graphite plays a crucial role in thermal-spectrum thorium molten salt reactors (TMSRs) as both the neutron moderator and the construct for the coolant flowing channel. When subjected to irradiation and elevated temperatures, graphite components experience considerable deformation due to a combination of dimensional changes, thermal expansion, irradiation creep, elastic deformation, and changes in thermomechanical characteristics. The lifespan of the graphite component is a limiting factor in TMSR designs as it strongly correlates with the dimensional changes of the graphite. To evaluate the thermal and mechanical reactions of graphite component under TMSR core conditions, it is necessary to couple models of thermal-hydraulics, neutronics, and thermal-mechanics. This paper presents an enhanced methodology for analyzing the deformation of graphite components using the finite element method. Then, this method was applied to analyze a 10-year deformation history of a hexagonal prism assembly (HPA) and it was compared with the traditional hexagonal round channel assembly (RCA). The results demonstrate that the stress–strain field of both types of graphite components undergo significant variations with the increasing neutron fluence from irradiation. HPA graphite exhibits a slower deformation as compared to RCA graphite when subjected to identical operating conditions. In this case, HPA graphite has a lifespan of approximately 10 years, while RCA graphite lasts only 8.8 years.

An urgent demand for recycling spent lithium-ion batteries (LIBs) is expected in the forthcoming years due to the rapid growth of electrical vehicles (EV). To address these issues, various technologies such as the pyrometallurgical and hydrometallurgical method, as well as the newly developed in-situ roasting reduction (in-situ RR) method were proposed in recent studies. This article firstly provides a brief review on these emerging approaches. Based on the overview, a life cycle impact of these methods for recovering major component from one functional unit (FU) of 1 t spent EV LIBs was estimated. Our results showed that in-situ RR exhibited the lowest energy consumption and greenhouse gas (GHG) emissions of 4833 MJ FU−1 and 1525 kg CO2-eq FU−1, respectively, which only accounts for ~23% and ~64% of those for the hydrometallurgical method with citric acid leaching. The H2O2 production in the regeneration phase mainly contributed the overall impact for in-situ RR. The transportation distance for spent EV LIBs created a great hurdle to the reduction of the life cycle impact if the feedstock was transported by a 3.5–7.5 t lorry. We therefore suggest further optimization of the spatial distribution of the recycling facilities and reduction in the utilization of chemicals.