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Abstract Lignin is considered as a renewable and sustainable resource for producing value-added aromatic chemicals and functional carbon materials. Herein, we develop a one-step catalyst-free depolymerization strategy to convert lignin into aryl monomers and carbon nanospheres simultaneously. Importantly, microwave-assisted depolymerization (MAD) in conjunction with dichloromethane (CH2Cl2) vapors is developed. The total mass yield of guaiacols reached the highest amount of 225.1 mg/g at 600 °C, and the highest yields of phenols (49.0 mg/g) and aromatic hydrocarbons (155.1 mg/g) were obtained at 700 °C. Hydrogen radicals and hydrogen chloride (HCl) are in-situ formed from CH2Cl2, significantly decreasing the activation barrier and reforming pyrolysis vapors to promote the formation of aryl monomers. Interestingly, uniform carbon nanospheres with an average size of 140 nm were produced as co-products at 700 °C. The microwave “hot-spots”, allied with the continuous surface erosion and the decrease in surface energy of lignin-derived carbon precursors by CH2Cl2 vapor, can be considered the driving force for the ultimate formation of carbon nanospheres. The CH2Cl2/MAD system produces aryl monomers (26.8 wt% yield) and carbon nanospheres (36.6 wt% yield) at 700 °C. We provide a facile, intriguing and scalable approach to convert lignin to valuable aryl monomers and sustainable carbon materials that can be applied in the chemistry, energy and environmental fields.

Abstract Commercially available lightweight-flexible CIGS solar cells are investigated under the Low-Intensity-Low-Temperature (LILT) conditions that exist at Mars, Jupiter, and Saturn. Current density-voltage measurements, concentrated solar, and external quantum efficiency measurements are performed under varying temperatures and illumination intensities to determine the applicability and performance of flexible CIGS in outer planetary conditions. The well-known metastability of the CIGS absorber is observed as a result of a barrier to minority carrier extraction at the CIGS/CdS interface under higher intensity illumination. However, despite the low temperatures and low intensities experienced in deeper space, the presence of this barrier does not significantly affect the performance of the solar cells under LILT conditions. This is attributed to the lower photogeneration rate of carriers particularly at conditions relative to Saturn and Jupiter, which appears to be less than the thermionic emission rate across the barrier and therefore the carrier extraction is relatively unaffected under these illumination conditions. At elevated temperatures and/or intensities such as at AM0 and conditions relative to Mars, however, the higher carrier generation rate results in the appearance of large series resistance and a significant loss of fill factor at irradiation levels greater than 1-sun AM0. Proton irradiation of the solar cells systematically reduces the performance, predominately through the formation of defect states in the absorber layer, the presence of which is increasingly more prohibitive in LILT conditions due to the low thermal energy of the minority carriers and the subsequent increased effect of SRH recombination.

Abstract Newly accessible shale deposits and other unconventional sources of natural gas have dramatically increased global gas reserves and are regarded as major future energy sources. Shale gas drilling began in Texas and is expanding throughout the U.S. and globally. In Texas and other regions, large population centers overlie these deposits. As a result, city residents increasingly come into contact with extraction activities. The proximity of drilling activities to residential areas raises a number of concerns, including noise, dust and emissions hazards, public safety, diminished quality of life, and effects on neighborhood aesthetics and property values. Cities in Texas address these concerns through setback ordinances that regulate the distance between gas wells and residences, schools, floodplains, etc. Although the state of Texas permits drilling 200 ft (61 m) from residences, many municipalities in the Dallas–Fort Worth Metroplex (DFW) have established longer setback distances. This paper analyzes the purpose and basis for setback distances among 26 municipalities in DFW. Findings show that there is no uniform setback distance, distances have increased over time, and, rather than technically-based, setbacks are political compromises. For policy makers confronted with urban shale gas drilling, deriving setback distances from advanced emissions monitoring could decrease setback distance ambiguity.

Agriculture Cyber-Physical System (A-CPS) is becoming increasingly important in enhancing crop quality and productivity by utilizing minimum cropland. This paper introduces the innovative idea of the Internet-of-Agro-Things (IoAT) with an explanation of the automatic detection of plant disease for the development of ACPS. Majority of the crops were infected by microbial diseases in conventional agriculture. Also, the constantly mutating pathogens cannot be known to the knowledge of the farmer, due to which, there arises a demand to develop a disease prediction system. To prevent this, we use a trained Convolutional Neural Network (CNN) model to perform an analysis of the crop image captured by a health maintenance system. The image capturing along with continuous sensing and intelligent automation is performed by the solar sensor node. The sensor node houses a developed soil moisture sensor which has a high longevity compared to its peers. A real time implementation of the proposed system is demonstrated using a solar sensor node with a camera module, a microcontroller and a smartphone application using which a farmer can monitor the field. The prototype was deployed for three months and has achieved a robust performance by remaining rust-free and sustaining the varied weather conditions. An accuracy of 99.24% is achieved by the proposed plant disease prediction framework.

DOE-2 building energy simulations were conducted to determine if there were practical architectural and control strategy solutions that would enable electrochromic (EC) windows to significantly improve visual comfort without eroding energy-efficiency benefits. EC windows were combined with overhangs since opaque overhangs provide protection from direct sun which EC windows are unable to do alone. The window wall was divided into an upper and lower aperture so that various combinations of overhang position and control strategies could be considered. The overhang was positioned either at the top of the upper window aperture or between the upper and lower apertures. Overhang depth was varied. EC control strategies were fully bleached at all times, modulated based on incident vertical solar radiation limits, or modulated to meet the design work plane illuminance with daylight. The EC performance was compared to a state-of-the-art spectrally selective low-e window with the same divided window wall, window size, and overhang as the EC configuration. The reference window was also combined with an interior shade which was manually deployed to control glare and direct sun. Both systems had the same daylighting control system to dim the electric lighting. Results were given for south-facing private offices in a typical commercial building. In hot and cold climates such as Houston and Chicago, EC windows with overhangs can significantly reduce the average annual daylight glare index (DGI) and deliver significant annual energy use savings if the window area is large. Total primary annual energy use was increased by 2-5% for moderate-area windows in either climate but decreased by 10% in Chicago and 5% in Houston for large-area windows. Peak electric demand can be reduced by 7-8% for moderate-area windows and by 14-16% for large-area windows in either climate. Energy and peak demand reductions can be significantly greater if the reference case does not have exterior shading or state-of-the-art static glass.

Using the Indian module of the Second Generation Model (SGM), we explore a reference case and three scenarios in which greenhouse gas emissions were controlled. Two alternative policy instruments (carbon taxes and tradable permits) were analyzed to determine comparative costs of stabilizing emissions at (1) 1990 levels (the 1X case), (2) two times the 1990 levels (the 2X case), and (3) three times the 1990 levels (the 3X case). The analysis takes into account India's rapidly growing population and the abundance of coal and biomass relative to other fuels. We also explore the impacts of a global tradable permits market to stabilize global carbon emissions on the Indian economy under the following two emissions allowance allocation methods. 1. 1. Grandfathered emissions: emissions allowances are allocated based on 1990 emissions. 2. 2. Equal per capita emissions: emissions allowances are allocated based on share of global population. Tradable permits represent a lower-cost method to stabilize Indian emissions than carbon taxes, i.e. global action would benefit India more than independent actions.

Abstract Shale gas development (SGD) via horizontal drilling and fracking is touted for economic benefits and spurned for health and environmental impacts. Despite SGD's socioecological salience, few peer-reviewed, empirical studies document the distribution of positive and negative effects. The City of Denton, Texas has ~ 280 active gas wells and over a decade of SGD. Here we use an environmental justice framework to analyze the distribution of SGD's costs and benefits within Denton. Using data on mineral property values from 2002 to 2013 and gas well locations, we ask: who owns Denton's mineral rights (i.e. the greatest financial beneficiaries) and how does this ownership pattern relate to who lives near gas wells (i.e. those who shoulder the nuisances and health impacts)? Our results show that Denton's mineral wealth is widely distributed around the U.S., residents own 1% of the total value extracted, and the city government is a large financial beneficiary. In addition to distributional inequities, our analysis demonstrates that split estate doctrine, legal deference to mineral owners, and SGD's uniqueness in urban centers create disparities in municipal SGD decision-making processes. The environmental justice issues associated with fracking in Denton also provide one possible explanation for residents' November 2014 vote to ban hydraulic fracturing.

This paper contributes an inclusive review of scientific studies in the field of sustainable human building ecosystems (SHBEs). Reducing energy consumption by making buildings more energy efficient has been touted as an easily attainable approach to promoting carbon-neutral energy societies. Yet, despite significant progress in research and technology development, for new buildings, as energy codes are getting more stringent, more and more technologies, e.g., LED lighting, VRF systems, smart plugs, occupancy-based controls, are used. Nevertheless, the adoption of energy efficient measures in buildings is still limited in the larger context of the developing countries and middle income/low-income population. The objective of Sustainable Human Building Ecosystem Research Coordination Network (SHBE-RCN) is to expand synergistic investigative podium in order to subdue barriers in engineering, architectural design, social and economic perspectives that hinder wider application, adoption and subsequent performance of sustainable building solutions by recognizing the essential role of human behaviors within building-scale ecosystems. Expected long-term outcomes of SHBE-RCN are collaborative ideas for transformative technologies, designs and methods of adoption for future design, construction and operation of sustainable buildings.

Abstract Beginning in the 2000s, the Dallas-Fort Worth metropolitan region became home to the world's largest and longest experiment in urban shale gas production, with 25,182 drilling permits issued from 2000 to 2016 in the Barnett Shale. Urban hydrocarbon governance centered on establishing statutory setback distances between drilling sites and nearest houses or other protected uses. Here we analyze qualitative interview data obtained with a rigorous sampling frame to examine processes and outcomes of municipal-level hydrocarbon governance. We find that early municipal responses (2001–2002) revealed lack of technical expertise to respond to unconventional drilling and production. Controversial wells, which residents considered too close to houses, focused governance debates in several municipalities. Municipal policymakers reported that protecting public health and safety were top priorities in determining setbacks. After 2003, policymakers copied ordinance language from neighboring municipalities and established task forces and working groups to reduce political tensions. The role of the hydrocarbon industry included frequent claims seeking to exploit the longstanding separation of mineral and property estates, which encouraged municipalities to reduce setbacks and lower potential exposure to regulatory takings lawsuits. Over time, municipal regulatory power in hydrocarbon governance decreased while industry power increased, offering several implications for corporate responsibility and social license debates.