• Energy Research
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Abstract Despite the comparatively limited stock of vehicles, heavy-duty road transport is responsible for a major share of CO2 emissions from the European transport sector. Electric trucks powered by overhead lines, so-called trolley trucks or catenary hybrid trucks, have been proposed as a potential GHG mitigation option. However, from the perspective of the energy system, trolley trucks constitute an additional and inflexible electricity demand. Here, we analyse scenarios with an ambitious European market diffusion of trolley trucks and their impact on the electricity system and CO2 emissions. Our results show that trolley trucks can noteworthily reduce the CO2 emissions from heavy road transport even when the additional CO2 emissions from electricity generation are taken into account. Furthermore, the actual impact of the additional load from trolley trucks on the total energy system is limited. Compared to the anticipated electricity demand from passenger cars in 2030, trolley trucks require less energy and the load is more equally distributed over daytime. Our findings thus show that electric trucks are an interesting option for CO2 mitigation in heavy road transport.

The average antimony concentration in municipal solid waste is estimated to be about 10-60 ppm. Thermodynamical models predict a volatile behavior for antimony compounds, yet literature mass balances show that about 50% of the antimony input remains in the grate ashes. This fact can be explained by the formation of thermally stable antimonates in the fuel bed due to interactions with alkali or earth-alkali metals. Thermogravimetric experiments revealed an increased thermal stability for antimony oxide in presence of oxygen and calcium oxide. Spiking experiments on the test incinerator TAMARA showed that chlorination processes have a strong effect on antimony volatilization whereas high fuel-bed temperatures and addition of antimony oxide only have a moderate effect. In the grate ashes, antimony shows a pH-depending leaching property, which is typical for anionic species. This fact supports the thesis that antimony is present in the grate ashes in an anionic speciation.

Abstract The storage of heat in aquifers, also referred to as Aquifer Thermal Energy Storage (ATES), bears a high potential to bridge the seasonal gap between periods of highest thermal energy demand and supply. With storage temperatures higher than 50 °C, High-Temperature (HT) ATES is capable to facilitate the integration of (non-)renewable heat sources into complex energy systems. While the complexity of ATES technology is positively correlated to the required storage temperature, HT-ATES faces multidisciplinary challenges and risks impeding a rapid market uptake worldwide. Therefore, the aim of this study is to provide an overview and analysis of these risks of HT-ATES to facilitate global technology adoption. Risk are identified considering experiences of past HT-ATES projects and analyzed by ATES and geothermal energy experts. An online survey among 38 international experts revealed that technical risks are expected to be less critical than legal, social and organizational risks. This is confirmed by the lessons learned from past HT-ATES projects, where high heat recovery values were achieved, and technical feasibility was demonstrated. Although HT-ATES is less flexible than competing technologies such as pits or buffer tanks, the main problems encountered are attributed to a loss of the heat source and fluctuating or decreasing heating demands. Considering that a HT-ATES system has a lifetime of more than 30 years, it is crucial to develop energy concepts which take into account the conditions both for heat sources and heat sinks. Finally, a site-specific risk analysis for HT-ATES in the city of Hamburg revealed that some risks strongly depend on local boundary conditions. A project-specific risk management is therefore indispensable and should be addressed in future research and project developments.

Strategies for reductions of emissions and depositions are described, with special regard for countries in transition. The influences of structural changes and energy-saving measures, as well as the effects of reductions of multiple pollutants, are analyzed for four countries in Central and Eastern Europe and for different scenarios with varying final energy demands, assume CO2-emission reductions, and country-specific factors. The results show that emission-reduction costs and optimal pollution-control measures differ significantly from those in Western European countries and also among the analyzed countries.

The objective of this paper is to evaluate the combustion process of municipal solid waste combustion in a grate furnace both experimentally and numerically by using data of a reference experiment with over-stoichiometric primary air supply. Measurements were carried out inside the combustion chamber of a pilot plant by monitoring temperatures and sampling gaseous combustion products along the bed surface. The data were assessed using elemental and energy balances. Experimental data of the axial temperature profiles of the flue gas, the fuel bed and the grate bars, as well as local gas flows and the flue gas composition measured above the fuel bed along the grate were used to describe the conversion process, including drying and carbon burnout. These data served as input to model the thermo- and fluid dynamic processes of the gas phase above the bed inside the combustion chamber. For this purpose the commercial code FLUENT was employed to carry out the simulations. Thus, the turbulent temperature, flow and species distributions in the combustion chamber of the pilot waste incinerator TAMARA were predicted. The results of the FLUENT modeling showed that under the prevailing conditions the flue gas burnout is almost completed before entering the first flue due to high temperatures, effective mixing and sufficient residence times of the flue gas inside the combustion chamber. This agrees well with the experimental results inside the first flue. On the basis of the above mentioned results, design and parametric studies can be carried out in a more efficient way by saving cost and time.

In this article, we analyse materials and techniques used in OLED manufacturing in terms of sustainability and highlight upcoming trends which are supposed to further enhance this technologies sustainability.

AbstractUrban land‐use change has the potential to affect local to global biogeochemical carbon (C) and nitrogen (N) cycles and associated greenhouse gas (GHG) fluxes. We conducted a meta‐analysis to (1) assess the effects of urbanization‐induced land‐use conversion on soil nitrous oxide (N2O) and methane (CH4) fluxes, (2) quantify direct N2O emission factors (EFd) of fertilized urban soils used, for example, as lawns or forests, and (3) identify the key drivers leading to flux changes associated with urbanization. On average, urbanization increases soil N2O emissions by 153%, to 3.0 kg N ha−1 year−1, while rates of soil CH4 uptake are reduced by 50%, to 2.0 kg C ha−1 year−1. The global mean annual N2O EFd of fertilized lawns and urban forests is 1.4%, suggesting that urban soils can be regional hotspots of N2O emissions. On a global basis, conversion of land to urban greenspaces has increased soil N2O emission by 0.46 Tg N2O‐N year−1 and decreased soil CH4 uptake by 0.58 Tg CH4‐C year−1. Urbanization driven changes in soil N2O emission and CH4 uptake are associated with changes in soil properties (bulk density, pH, total N content, and C/N ratio), increased temperature, and management practices, especially fertilizer use. Overall, our meta‐analysis shows that urbanization increases soil N2O emissions and reduces the role of soils as a sink for atmospheric CH4. These effects can be mitigated by avoiding soil compaction, reducing fertilization of lawns, and by restoring native ecosystems in urban landscapes.

Abstract This paper presents a detailed meta-analysis of end and primary energy use for heating, cooling and ventilation of 11 low-energy non-residential buildings and one residential building in Germany that belong to the EnOB research program launched by the German Federal Ministry for Economy. In particular, the analysis emphasizes the substantial impact of auxiliary energy use on the efficiency of heating and cooling performance. The investigated buildings employ environmental energy sources and sinks – such as the ground, ground water, rainwater and the ambient air – in combination with thermo-active building systems. These concepts are promising approaches for slashing the primary energy use of buildings without violating occupant thermal comfort. A limited primary energy use of about 100 kWhprim/(m2neta) as a target for the complete building service technology (HVAC and lighting) was postulated for all buildings presented. With respect to this premise, a comprehensive long-term monitoring in high time resolution was carried out over the course of two to five years, with an accompanying commissioning of the building performance. Measurements include the energy use for heating, cooling, and ventilation, as well as the auxiliary equipment, the performance of the environmental heat source and sink, and local climatic site conditions.