• Energy Research
• 2016-2025close
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Abstract Dimethyl ether appears to be a better choice among various diesel alternatives due to its high cetane number and sootless combustion. However, the physical and chemical properties of dimethyl ether are very different from those of diesel. The physical properties influence spray formation and atomization characteristics, while chemical properties determine combustion and emission formation characteristics. Thus, fuel's physical and chemical properties significantly determine engine performance and emissions. In the present work, spray combustion and emission formation characteristics of n-heptane, dimethyl ether, and their blends (10, 25, and 50% dimethyl ether in n-heptane) were numerically studied in a constant volume chamber. Results show that the n-heptane spray combustion has the highest heat release rate with an intense premix combustion phase, whereas dimethyl ether spray combustion has the lowest heat release rate and shortest premix combustion phase. The magnitude of the premixed phase and heat release rate decreases with the increase in dimethyl ether mass fraction in the blends. Soot, carbon monoxide (CO), unburned hydrocarbon (UHC), and nitric oxide (NO) emissions decreased with the increase in the dimethyl ether mass fraction in the blends and were lowest for the dimethyl ether.

Abstract Dimethyl ether appears to be a better choice among various diesel alternatives due to its high cetane number and sootless combustion. However, the physical and chemical properties of dimethyl ether are very different from those of diesel. The physical properties influence spray formation and atomization characteristics, while chemical properties determine combustion and emission formation characteristics. Thus, fuel's physical and chemical properties significantly determine engine performance and emissions. In the present work, spray combustion and emission formation characteristics of n-heptane, dimethyl ether, and their blends (10, 25, and 50% dimethyl ether in n-heptane) were numerically studied in a constant volume chamber. Results show that the n-heptane spray combustion has the highest heat release rate with an intense premix combustion phase, whereas dimethyl ether spray combustion has the lowest heat release rate and shortest premix combustion phase. The magnitude of the premixed phase and heat release rate decreases with the increase in dimethyl ether mass fraction in the blends. Soot, carbon monoxide (CO), unburned hydrocarbon (UHC), and nitric oxide (NO) emissions decreased with the increase in the dimethyl ether mass fraction in the blends and were lowest for the dimethyl ether.

Abstract This study investigates the non-linear relationship between urbanization paths and CO2 emissions in selected South, South-East, and East Asian countries over the period 1971–2014. Based on the STIRPAT (Stochastic Impacts by Regression on Population, Affluence, and Technology) framework, we applied the advanced and robust methods of dynamic seemingly unrelated regression (DSUR), dynamic OLS (DOLS), and fully modified OLS (FMOLS) to estimate the long-term effects. The empirical findings revealed the inverted U-shaped effects of urbanization and urban agglomeration and the U-shaped impact of the largest city ratio on CO2 emissions. Urbanization and urban agglomerations improve environmental quality in the long-run and support ecological modernization theory. However, excessive concentration in the largest cities have severely affected the environmental quality and violates the notion of compact-city efficiencies. Moreover, energy intensity and economic growth positively affect CO2 emissions, while trade openness negatively influences CO2 emissions. Our robustness analysis at the country-level applies the augmented mean group (AMG) panel ARDL technique, which further supports the non-linear effect of urbanization paths on CO2 emissions except for a few countries. The results of the panel Granger non-causality approach unveil bidirectional causality of energy efficiency, economic growth, urbanization, and largest city ratio with CO2 emissions. In contrast, unidirectional causality runs from urban agglomeration to CO2 emissions. Our findings have important policy implications as we suggest green urban infrastructures, eco-friendly dwellings, smart cities, country-specific trade policies, and renewable energy options to improve the environmental quality.

Abstract This study investigates the non-linear relationship between urbanization paths and CO2 emissions in selected South, South-East, and East Asian countries over the period 1971–2014. Based on the STIRPAT (Stochastic Impacts by Regression on Population, Affluence, and Technology) framework, we applied the advanced and robust methods of dynamic seemingly unrelated regression (DSUR), dynamic OLS (DOLS), and fully modified OLS (FMOLS) to estimate the long-term effects. The empirical findings revealed the inverted U-shaped effects of urbanization and urban agglomeration and the U-shaped impact of the largest city ratio on CO2 emissions. Urbanization and urban agglomerations improve environmental quality in the long-run and support ecological modernization theory. However, excessive concentration in the largest cities have severely affected the environmental quality and violates the notion of compact-city efficiencies. Moreover, energy intensity and economic growth positively affect CO2 emissions, while trade openness negatively influences CO2 emissions. Our robustness analysis at the country-level applies the augmented mean group (AMG) panel ARDL technique, which further supports the non-linear effect of urbanization paths on CO2 emissions except for a few countries. The results of the panel Granger non-causality approach unveil bidirectional causality of energy efficiency, economic growth, urbanization, and largest city ratio with CO2 emissions. In contrast, unidirectional causality runs from urban agglomeration to CO2 emissions. Our findings have important policy implications as we suggest green urban infrastructures, eco-friendly dwellings, smart cities, country-specific trade policies, and renewable energy options to improve the environmental quality.

Abstract Socio-technical transformations towards low-carbon energy systems are on the way in developed countries. Conversely, developing countries tend to be locked in fossil fuels and foster coal-based energy structures, emphasizing reliable and cost-effective energy provision and sidelining environmental concerns. In this study, we identified and analysed the predominant factors related to coal-based power generation in Bangladesh. We applied a mixed-method approach, initially conducting a systematic literature review and, subsequently, semi-structured expert interviews to identify and validate relevant factors. We then assessed their relative importance using an Analytical Hierarchy Process based on expert judgments. The results of this assessment reveal that socio-economic aspects and environmental issues scored highest, while technological aspects and sector regulations were considered to be less relevant for large-scale coal power implementation. We conclude that future energy policies created in Bangladesh will need to use appropriate legal instruments and address issues such as human displacement and resettlement, low levels of public acceptance, health hazards and environmental pollution. Participative policy frameworks should be deployed in coal plant projects, and active monitoring systems are necessary to reduce the negative consequences associated with increased electrification and energy consumption. To address foreseeable structural challenges, it furthermore will be crucial to explore sustainable alternatives.

Abstract Socio-technical transformations towards low-carbon energy systems are on the way in developed countries. Conversely, developing countries tend to be locked in fossil fuels and foster coal-based energy structures, emphasizing reliable and cost-effective energy provision and sidelining environmental concerns. In this study, we identified and analysed the predominant factors related to coal-based power generation in Bangladesh. We applied a mixed-method approach, initially conducting a systematic literature review and, subsequently, semi-structured expert interviews to identify and validate relevant factors. We then assessed their relative importance using an Analytical Hierarchy Process based on expert judgments. The results of this assessment reveal that socio-economic aspects and environmental issues scored highest, while technological aspects and sector regulations were considered to be less relevant for large-scale coal power implementation. We conclude that future energy policies created in Bangladesh will need to use appropriate legal instruments and address issues such as human displacement and resettlement, low levels of public acceptance, health hazards and environmental pollution. Participative policy frameworks should be deployed in coal plant projects, and active monitoring systems are necessary to reduce the negative consequences associated with increased electrification and energy consumption. To address foreseeable structural challenges, it furthermore will be crucial to explore sustainable alternatives.

Abstract Double and added double stage organic Rankine cycle systems are configured to recover exhaust gas waste heat of dual fuel engines. To evaluate the performance of the models proposed here, energy, exergy and economic analyses are performed. Several working fluids are evaluated for recommendation for double and added double stage organic Rankine cycle systems. In the double stage organic Rankine cycle, cycle 1 and cycle 2 are connected in parallel. Working fluids R123, R141b, and R601 are used in cycle 1, and R245fa, R236ea, and R1233zd in cycle 2. In the double stage organic Rankine cycle, the working fluid combinations of R601-R1233zd, R601-R245fa and R123-R245fa show better performance when considering power, heat transfer area and payback period, which are 1760 kW, 2108.9 m2 and 4.21 year, respectively for R601-R245fa. In the added double stage organic Rankine cycle, cycle 1 and cycle 2 are connected in two stages and cycle 1 and cycle 3 in parallel. The net power of the working fluid combinations of R123-R245fa and R123-R1233zd are 1799 kW and 1782 kW, respectively, which are higher than those of the others. Further, for R123-R245fa, the heat transfer area and payback period are 3352 m2 and 6.20 year, respectively, which is better compared to those of other working fluid combinations.

Abstract Double and added double stage organic Rankine cycle systems are configured to recover exhaust gas waste heat of dual fuel engines. To evaluate the performance of the models proposed here, energy, exergy and economic analyses are performed. Several working fluids are evaluated for recommendation for double and added double stage organic Rankine cycle systems. In the double stage organic Rankine cycle, cycle 1 and cycle 2 are connected in parallel. Working fluids R123, R141b, and R601 are used in cycle 1, and R245fa, R236ea, and R1233zd in cycle 2. In the double stage organic Rankine cycle, the working fluid combinations of R601-R1233zd, R601-R245fa and R123-R245fa show better performance when considering power, heat transfer area and payback period, which are 1760 kW, 2108.9 m2 and 4.21 year, respectively for R601-R245fa. In the added double stage organic Rankine cycle, cycle 1 and cycle 2 are connected in two stages and cycle 1 and cycle 3 in parallel. The net power of the working fluid combinations of R123-R245fa and R123-R1233zd are 1799 kW and 1782 kW, respectively, which are higher than those of the others. Further, for R123-R245fa, the heat transfer area and payback period are 3352 m2 and 6.20 year, respectively, which is better compared to those of other working fluid combinations.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.