• Energy Research
• 2016-2025close
• Closed Access close
• Open Source close
• 11. Sustainability close
• 6. Clean water close

Cities are progressively heightening their climate aspirations to curtail urban carbon emis- sions and establish a future where economies and communities can flourish within the Earth’s eco- logical limits. Consequently, numerous climate initiatives are being launched to control urban car- bon emissions, targeting various sectors, including transport, residential, agricultural, and energy. However, recent scientific literature underscores the disproportionate distribution of climate poli- cies. While cities in the Global North have witnessed several initiatives to combat climate change, cities in the Global South remain uncovered and highly vulnerable to climate hazards. To address this disparity, we employed the Balanced Iterative Reducing and Clustering using the Hierarchies (BRICH) algorithm to cluster cities from diverse geographical areas that exhibit comparable socio- economic profiles. This clustering strives to foster enhanced cooperation and collaboration among cities globally, with the goal of addressing climate change in a comprehensive manner. In summary, we identified similarities, pa􏰀erns, and clusters among peer cities, enabling mutual and generaliza- ble learning among worldwide peer-cities regarding urban climate policy exchange. This exchange occurs through three approaches: (i) inner-mutual learning, (ii) cross-mutual learning, and (iii) outer-mutual learning. Our findings mark a pivotal stride towards a􏰀aining worldwide climate ob- jectives through a shared responsibility approach. Furthermore, they provide preliminary insights into the implementation of “urban climate policy exchange” among peer cities on a global scale.

Abstract To achieve the EU climate and energy objectives, a transition towards a future sustainable energy system is needed. The integration of the huge potential for industrial waste heat recovery into smart energy system represents a main opportunity to accomplish these goals. To successfully implement this strategy, all the several stakeholders' conflicting objectives should be considered. In this paper an evolutionary multi-objective optimization model is developed to perform a sustainability evaluation of an energy system involving an industrial facility as the waste heat source and the neighbourhood as district heating network end users. An Italian case study of heat recovery from a steel casting facility shows how the model allows to properly select the district heating network set of users to fully exploit the available waste energy. Design directions such as the thermal energy storage capacity can be also provided. Moreover, the model enables the analysis of the trade-off between the stakeholders’ different perspectives, allowing to identify possible win-win solutions for both the industrial sector and the citizenship.

Torrefaction is considered as a method for producing biofuels with improved characteristics compared to those of the “raw” biomass (higher calorific value, moisture resistance, better grindability). The torrefaction process is an endothermic process that is usually carried out in a gaseous atmosphere in the absence of oxygen. To reduce the required heat input, it is proposed to employ the oxidative torrefaction and conduct the process in a fluidized bed agitated with flue gases containing less than 6% oxygen. Preliminary studies of the oxidative torrefaction of sunflower husks, including thermogravimetric analysis of the treated material, have shown that the heat treatment time for the biomass should be at least 5 min. A fluidized bed is a reactor with ideal mixing of the treated material where uniform treatment of raw material particles cannot generally be attained. To overcome this disadvantage of the fluidization technique and achieve the required residence time for biomass in a fluidized bed during a continuous torrefaction process, it was proposed to equip a torrefaction reactor with a series of vertical baffles spaced at 50 mm. These baffles induce a loop-like flow of the processed biomass from the inlet to the outlet of the reactor. To investigate the residence time for husk particles in the reactor, a tracer, which was colored to husk particles' color with a water-soluble dye which did not change the weight and size of the particles, was injected into the bed of uncolored particles. Tracer samples were taken every 30 s at the outlet of the reactor and were analyzed using a special procedure to determine the fraction of colored particles in each sample. This enabled us to gauge the time during which the colored particles injected into the fluidized bed reached the point of their discharge from the bed. Studies performed in a “cold” model of the reactor showed that a series of vertical baffles in the bed can provide the required residence time for biomass in a reactor including commercial reactors. Plates can provide the necessary biomass residence time in the reactor.

Abstract In this study, crude cellulose derived from cornstalk, after bleaching, was used as raw material for the synthesis of sodium carboxymethyl cellulose (CMC) by reacting with the cellulose with NaOH and chloroacetic acid at 75 °C for 1.5 h. Effects of alkali dosage, concentration of chloroacetic acid on the physical and chemical properties of the CMC products were investigated. It was revealed that the reactants alkali reagent/chloroacetic acid/cellulose at the molar ratio of 4.6:2.8:1and 4:2.5:1, or at the molar ratio of NaOH/ClCH 2 COOH ≈1.6–1.64, resulted in CMC products of relatively high water solubility. The viscosity-average molecular weight M v of these two CMC products obtained at molar ratios of 4.0:2.5:1 and 4.6:2.8:1 is in the range of 1.94 × 10 4 –2.48 × 10 4 g mol −1 , and the average DS of the two products are 0.57 and 0.85, respectively. As the solute concentration is above 2 wt%, the viscosity of the CMC-water solution exhibits nonlinear (exponential) increasing with increasing the solute concentration (typical of non-Newton fluids).

Abstract Limiting the increase of global temperature requires electrification of the railway transport, which is relatively a distinct mode of transport in terms of economy, business and socialization of a country. However, battery complemented railway transport systems such as fuel cell hybrid railway propulsion systems are constrained by the high cost of the battery, and suboptimal performance of the fuel cell under varying loads. Optimized selection of battery can reduce its costs associated with sizing, life and utilization. Similarly, managing the load distribution between the battery and fuel cell can reduce the load variations concern for fuel cell. In this study, model-based selective characterization of the battery and fuel cell is done to identify the optimal features and constraints. Following characterization, the load allocation to battery and fuel cell is determined with the targets of collaborative utilization of optimal features and mitigation of constraints. Subsequently, considering this load allocation and results of characterization, conditions are proposed for reliable sizing and optimized selection of battery. The significance of the proposed conditions in reliable sizing is explored. Based on these conditions, certain commercially developed batteries are evaluated for optimized selection of battery. The results signify this study as a foundation for research on the reliable sizing and optimized selection of battery in fuel cell hybrid railway propulsion systems.

Changes in the main weather features are becoming perceivable in Italy. In the last years, the average temperature and the intensity of rainstorms are increasing. Such phenomena could lead to changes in the earth-atmosphere interaction. Accounting for the high vulnerability of the Italian territory, an obvious consequence would concern the effects on the hydro-geological hazards, including landslides and floods. As a matter of fact, the higher frequency of high magnitude flood and landslide events represent an alarm bell. It is necessary to explore with all available instruments the consequences of the potential climate changes. Since quantitative predictions are not possible, the only way to run is depicting rational scenarios for the most vulnerable contexts adopting a multidisciplinary approach. Based on projections of potential climate changes in the 21st century, the report examines their potential impact in the context of the Italian peninsula. After a general overview about typical slope responses to weather changes, some quantitative scenarios have been depicted for representative geomorphological contexts. The last part of the paper examines changes in the expected risk, based on the characteristics of the Italian territory and its vulnerability, looking at the initiatives to undertake for its mitigation.

Abstract Microorganisms used in syngas fermentation require nutrients to grow and convert syngas (CO, H2 and CO2) into various products. Many of the essential nutrients can be provided by biochar. Poultry litter biochar (PLBC) contains minerals and trace metals and has a high pH buffering capacity, making it suitable as a nutrient supplement. The effects of PLBC loadings from 1 to 20 g L−1 on syngas fermentation were determined in 250 ml bottle assays. Results showed that 10 and 20 g L−1 PLBC significantly increased ethanol production compared to standard yeast extract (YE) medium. Fermentations in a 3L continuous stirred tank reactor (CSTR) with 10 g L−1 PLBC with and without 4-morpholineethanesulfonic acid (MES) showed 64% and 36% more ethanol production, respectively, than standard medium. The acetic acid accumulated at the beginning of fermentation was completely converted to ethanol in all media tested in the CSTR. These results demonstrate the feasibility of using PLBC medium without costly MES in the CSTR to enhance ethanol production from syngas for potential use at commercial scale.

Abstract District heating (DH) enables the utilisation and distribution of heating from sources unfeasible for stand-alone applications and combined with cogeneration of heat and power (CHP), has been the cornerstone of Denmark’s realisation of a steady national primary energy supply over the last four decades. However, progressively more energy-efficient houses and a steadily improving heat pump (HP) performance for individual dwellings is straining the competitive advantage of the CHP–DH combination as DH grid losses are growing in relative terms due to decreasing heating demands of buildings and relatively high DH supply temperatures. A main driver for the DH water temperature is the requirements for domestic hot water (DHW) production. This article investigates two alternatives for DHW supply: (a) DH based on central HPs combined with a heat exchanger, and (b) a combination of DH based on central HPs and a small booster HP using DH water as low-temperature source for DHW production. The analyses are conducted using the energyPRO simulation model and are conducted with hourly varying factors; heating demands, DH grid losses, HP coefficient of performance (COP) and spot market prices in order to be able to analyse the relative performance of the two options and their performance over the year. Results are also compared to individual boilers and individual HPs. The results indicate that applying booster HPs enables the DH system to operate at substantially lower temperature levels, improving the COP of central DH HPs while simultaneously lowering DH grid losses significantly. Thus, DH performance is increased significantly. Additionally, performance for the DH HP with booster combination is considerably better than individual boiler or HP solutions.

Among various bioreactors examined in anaerobic digestion and dark fermentation, UASB bioreactor has shown to be a promising alternative. However, mass transfer resistance and biomass washout have been the issues that reported as draw backs of the granular system in the literature. Another problem associated with such a system is its long start-up period as a result of biomass washout and long microbial granulation stage. In this paper, the results obtained from an UASFF bioreactor in methane (AD process) and hydrogen (DF process) production from POME, are presented to assess mass transfer of substrate into the granules and also study the role of internal packing used in the middle part of reactor in the process stability. The value of effectiveness factor, η, for AD and DF processes were calculated to be 0.96 and 0.94, respectively, indicating that there was no mass transfer resistance due to internal and/or external factors. The results showed that the packing material could retain biomass in the reactor and had outstanding contribution in the granulation enhancement. Its role as a supplementing treatment stage was more significant at low HRTs and up-flow velocities.