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The importance of emission control has increased sharply due to increased need of energy from combustion. However, biomass utilization in energy production is not free from problems because of physical and chemical characteristics which are substantially different from conventional energy sources. In this situation, the quantity and quality of emissions as well as used renewable source as wood or corn grain are often unknown. To assess this problem the paper addresses the objectives to quantify the amount of greenhouse gases during the combustion of corn as compared to the emissions in fossil combustion (natural gas, LPG and diesel boiler). The test was carried out in Friuli Venezia Giulia in 2006-2008 to determine the air pollution (CO, NO, NO2, NOx, SO2 and CO2) from fuel combustion in the family boilers with power between 20-30 kWt. The flue gas emission was measured with a professional semi-continuous multi-gas analyzer, (Vario plus industrial, MRU air Neckarsulm-Obereisesheim). Data showed a lower emission of fossil fuel compared to corn in family boilers in reference to pollutants in the flue gas (NOx, SO2 and CO). In particular way the biomass combustion make a higher concentration of carbon monoxide (for a incomplete combustion because there aren’t a good mixing between fuel and air) and nitrogen oxides (in relation at higher content of nitrogen in herbaceous biomass in comparison of another fuel). Proceedings of the 19th European Biomass Conference and Exhibition, 6-10 June 2011, Berlin, Germany, pp. 1296-1304

The main challenge for concrete industry - and in general for construction materials - is to serve the two major needs of human society, the protection of the environment, on one hand, and the requirements of buildings and infrastructures by the world?s growing population, on the other. In the past concrete industry has satisfied these needs well. However, for a variety of reasons, the situation has changed dramatically in the last years. First of all, the concrete industry is the largest consumer of natural resources. Secondly, Portland cement, the binder of modern concrete mixtures, is not as environmentally friendly. The world's cement production, in fact, contributes to the earth's atmosphere about 7% of the total CO2 emissions, CO2 being one of the primary greenhouse gas (GHG) responsible for global warming and climate change. As a consequence, concrete industry in the future has to face two antithetically needs. In other words, how the concrete industry can feed the growing population needs being - at the same time - sustainable? The answer to this question is represented by the ?3R-Green Strategy? widely discussed in the first chapter of this PhD thesis: Reduction in consumption of gross energy for construction materials production, Reduction in polluting emissions and Reduction in consuming not renewable natural resources. In particular, this thesis is focused on the alternative binders to Portland cement such as alkali-activated slag cements and calcium sulphoaluminate cement-based binders in order to manufacture sustainable mixtures for special applications such as repair mortars, lightweight reinforced plasters and concretes for slabs on ground. The experimental results show the feasibility of manufacturing both EN 1504-3 R3 class mortars and Portland-free concretes for jointless slabs on ground with calcium sulphoaluminate cement, supplementary cementitious materials (fly ash, ground granulated blast furnace slag) and hydrated lime instead of Portland cement. Moreover, alkali-activated mortars and concretes seem to be a reasonable alternative to natural hydraulic lime-based and/or traditional Portland cement-based mixtures for rehabilitation or restoration of ancient masonry buildings and existing concretes structures. Finally, a new sustainability index was developed taking into account the environmental impact, the performances and the durability of mixtures. In particular, in the environmental impact section, the natural raw materials consumption, the greenhouse gas emissions and the energy consumption have been considered. Furthermore, depending on the applications and the environments, design parameters and properties related to durability have been assigned to each mixture. less

An ecological- and biological-based urban planning model, which focuses on the health of the people living in the city, is aimed at improving and prospering the welfare level of the society. The best scenario for creating more sustainable living spaces is to direct people's behavior towards a more environmentally friendly system. For this purpose, the "sustainable green campus" model has been considered at Kirklareli University. Kirklareli University, which was established in 2010 in Kirklareli city. The Green Campus Model covers the renovation of the indoor and outdoor areas of Kirklareli University, Kayali Campus, and its human-oriented, ecological, and environmentally friendly development. The sustainable green campus model includes the evaluation of the spatial and social living areas of Kirklareli University within the framework of sustainability. With the green campus approach, it aims to be a sustainable, environmentally oriented campus where renewable energy sources are used, naturally energy consumption can be controlled, and recycling and treatment systems are used effectively. © Peter Lang AG 2020.

The project between tthe Deutsche Biomasseforschungszentrum (DBFZ) and the Karlsruhe Institute of Technology (KIT) focuses on the pr rovision of alternative fuels by thermochemical conversion. Biogenic residues and wastes which are not used yet or which could be utilised more efficiently are studied. The selection of possible feedstock was supported by a techhnical potential analysis including the competition to th he food industry. The technical suitability of raw materials for the fast pyrolysis (FP) process was of special in nterest. As a possible feedstock following types of biomass were studied: corn stover, corn cobs, biogenic floating re efuse (river Rhine and Baltic Sea), scrap wood, bark, rape s straw, sunflower straw, draff, diverse residues of flour production and hay. A process development unit (PDU) with a biomass feeding rate of 10 kg/h and a twin screw m mixer reactor was used for all experiments. It was found that different types of biomass form different char, condensate e and gas yields due to varying ash levels and lignocellulosic composition. Elemental formulas for feedstock, char, organic condensate and gas were estimated independent on t the feedstock due to similar elemental compositions. Pyrolysis gas analysis during the experiments gave information on the mass yields. A CO/CO2-ratio of 1 (i.e. wood) corresponds to organic condensate yields of about 50 wt.-%%, whereas a ratio of 0.3-0.7 (straw) corresponds to 18-32 wt. .-% respectively. Proceedings of the 20th European Biomass Conference and Exhibition, 18-22 June 2012, Milan, Italy, pp. 973-977

The aim of the joint activity between CNR ITAE and University of Malta, funded in the framework of a bilateral agreement is the preliminary study of the possible application of thermally-activated technologies for the refrigeration of fish on-board of fishing vessels, with particular attention to the Mediterranean area. In such a context, the two partners, given their expertise in the adsorption and absorption cooling technologies, dedicated the first year of the joint project on several activities needed to define possible integration solutions on-board. The following report is then organized as follows: - Section 3 reports an analysis of the state-of-the-art concerning existing refrigeration systems currently employed in the fishing vessels' application as well as innovative activities recently performed on the possible integration of thermally-driven technologies for the refrigeration. - Section 4 focuses on the definition of possible integration between the waste heat recovered from the engines of the fishing vessel and the sorption technology for refrigeration. This analysis takes into account different possible applications, in terms of refrigeration temperatures as well as capacities. Furthermore, different possible waste heat streams at different temperature levels are investigated. - Section 5 identifies the typical working boundary conditions under which the fishing vessel operates, in terms of cooling demand, also considering different climatic zones (i.e. different geographical areas in which the vessel operates) and vessels' typology. - Section 6 investigates possible working pairs, both for adsorption and absorption technologies, which are promising for the given boundary conditions in Section 5. This activity is needed to set the operational limits that each technology and working pair cannot overcome. - Section 7 reports the calculations performed for each working pair and operating conditions, both taking into account thermodynamic constraints as well as analysing literature results on different prototypes realized and tested. - Section 8 introduces a dynamic model, implemented in TRNSYS environment, of an absorption refrigerator, which was validated and will be used in the following activities to investigate the defined schematics in Section 4. - Section 9 defines the Key Performance Indicators (KPIs) that will be used in the following activities to compare the achievable results of the different configurations.

Esta dissertação explora o modo como a empresa multinacional Unilever tem por objetivo a reconciliação da lógica Comercial e a de Sustentabilidade nas suas principais atividades de negócio, de modo a atingir o hibridismo organizacional. Baseando-se num estudo de caso, demonstra como a Unilever interliga estas duas lógicas através de três fatores distintos: liderança, comunicação e ações. O estudo qualitativo revela que o sucesso desta integração e a sustentação das mesmas não deriva de um único fator em específico, mas sim da interação planeada entre esses três fatores. De acordo com os resultados da minha análise, desenvolvi um modelo que demonstra como as duas lógicas mudam ao longo do tempo, influenciadas por dinâmicas tanto internas como externas. This dissertation explores how the multinational company Unilever aims at reconciling two logics, a Sustainability and a Commercial Logic within its core business activities to achieve organizational hybridity. Based on a case study, it shows that Unilever reconciles the two logics through three distinct drivers: leadership, communication and actions. The qualitative study reveals that there is not a specific single driver that can lead to a successful integration and sustaining of logics, but rather the planned interplay between the three drivers. Resulting from my findings, I developed a model that elucidates how the two logics change over time through both internal and external dynamics.

The current fashion design, production, and consumption system, known as ‘fast fashion’, is characterized by the manufacturing of low-quality garments in a short period of time carried out in developing countries. In parallel with the deficits in social responsibility and human rights, the prevailing ‘take-make-dispose’ system in the fashion industry is one of the main causes of environmental pollution that concerns the climate change, scarcity of natural resources and health problems for the living beings. Due to these facts, discussions on Circular Design strategies – for waste reduction, components recycling, and materials reuse – became increasingly relevant throughout the globe. This paper’s aspiration is to outline a perspective towards a Circular Fashion. The concept of the Design for Sustainability requires a holistic view throughout de-signing strategies as well as the establishment of cyclical systems for the production site. Notwithstanding, the efficient integration of social and cultural dimensions are vital for Sustainable Fashion’s triumph. This work is supported by FEDER funds through the Competitiveness Factors Operational Programme - COMPETE and by national funds through FCT – Foundation for Science and Technology within the scope of the project POCI-01-0145-FEDER-007136. info:eu-repo/semantics/publishedVersion

It is widely known that fossil fuels are limited; consequently, the generation of new sources of energy in a clean and environmentally friendly manner is a research priority. Bioethanol appears to be one potential solution, especially second-generation production from renewable biomass.In order to use lignocellulosic feedstock to produce bioethanol, its polysaccharide components, cellulose and hemicellulose, must be hydrolysed into soluble sugars, which can then be converted into ethanol by fermentative microorganisms such as Geobacillus thermoglucosidasius TM242 used by the company ReBio Technologies Ltd.To date, the cost of commercial enzymes used during the hydrolysis process remains a major economic consideration in the production of second-generation bioethanol as an alternative fuel. The research project presented in this thesis aims to improve this rate-limiting step of microbial bioethanol production through an investigation of the different enzymes associated with hemicellulose hydrolysis. Firstly, the TM242 genome sequence revealed a number of genes encoding glycoside-hydrolases. Six of these genes were cloned and expressed in E. coli and the recombinant enzymes characterised; three of them, two β-xylosidases and an α arabinofuranosidase, are relevant to xylan hydrolysis, and were found to be highly active and thermostable. Crystallisation of one of the β-xylosidases permitted the determination of a high-resolution (1.7 Å) structure of the apo-enzyme along with a lower resolution (2.6 Å) structure of the enzyme-substrate complex, resulting in the first reported structure of a GH52 family member (Espina et al., 2014).Secondly, as the TM242 microorganism lacks xylanase enzymes, four genes encoding xylanases from closely-related Geobacillus strains were cloned and expressed in E. coli, with one of them being also successfully cloned and expressed in G. thermoglucosidasius TM242. This heterologous xylanase was secreted in active form representing an enhanced biomass utilisation by TM242.In conclusion, it is felt that the findings presented here have the potential to make a valuable contribution towards second-generation bioethanol production.

This document collects the summaries of the interviews carried out with various stakeholders in the Requena-Utiel region from March to October 2021. The topics covered in these interviews focused on the governance of the aquifer, the creation of the Central Board of Users of the Requena-Utiel Underground Mass and the relationships between the different users, their perception of the quantitative and qualitative state of the aquifer and the future actions to take for sustainable management. The questionnaire written by the team from Bo��azi��i University, Turkey, was taken into account when preparing the interviews. This project is part of the PRIMA Programme supported by the European Union's Horizon 2020 Research and Innovation Programme under Grant Agreement No 1923.