• Energy Research
• Restricted close
• Open Source close
• 6. Clean water close
• 11. Sustainability close
• Research at ASB close

Abstract Anaerobic digestion of animal by-products was investigated in batch and semi-continuously fed, reactor experiments at 55 °C and for some experiments also at 37 °C. Separate or mixed by-products from pigs were tested. The methane potential measured by batch assays for meat- and bone flour, fat, blood, hair, meat, ribs, raw waste were: 225, 497, 487, 561, 582, 575, 359, 619 dm 3 kg −1 respectively, corresponding to 50–100% of the calculated theoretical methane potential. Dilution of the by-products had a positive effect on the specific methane yield with the highest dilutions giving the best results. High concentrations of long-chain fatty acids and ammonia in the by-products were found to inhibit the biogas process at concentrations higher than 5 g lipids dm −3 and 7 g N dm −3 respectively. Pretreatment (pasteurization: 70 °C, sterilization: 133 °C, and alkali hydrolysis (NaOH) had no effect on achieved methane yields. Mesophilic digestion was more stable than thermophilic digestion, and higher methane yield was noticed at high waste concentrations. The lower yield at thermophilic temperature and high waste concentration was due to ammonia inhibition. Co-digestion of 5% pork by-products mixed with pig manure at 37 °C showed 40% higher methane production compared to digestion of manure alone.

Biodegradation rates of benzoate and related aromatic compounds, 3-nitrobenzoate, 4-chlorobenzoate, 4-chlorophenol, and 2,4-dichlorophenol by unexposed (unacclimated) and long-term exposed (acclimated) biomass were quantified using a modified fed-batch technique. The acclimated biomass was taken after approximately 1-year of operation from three lab-scale sequencing batch reactors (SBR). These reactors were operated under various cycling electron acceptor conditions with a continuous feed of a synthetic wastewater containing biogenic and nonbiogenic chemicals including benzoate, 3-nitrobenzoate, and 4-chlorophenol, but not 4-chlorobenzoate or 2,4-dichlorophenol. The unexposed biomass was taken from a full-scale wastewater treatment plant, which constituted one of the original sources of inoculum for the lab-scale SBRs. The acclimated biomass manifested high removal rates of benzoate and related aromatic compounds with additional removal of structurally similar chemicals (4-chlorobenzoate and 2,4-dichlorophenol). The unacclimated biomass showed no removal of 3-nitrobenzoate, 4-chlorobenzoate or 2,4-dichlorophenol. Addition of biogenic substrates reduced the degradation of most aromatic compounds tested, but it enhanced 2,4-dichlorophenol removal. Biodegradation rates of each aromatic compound with the biomass from the anoxic/aerobic SBR were further determined under anaerobic (absence of aeration and NO3-), anoxic (no aeration, but with surplus NO3-), standard oxygen (DO > 0.2 mg/L), and elevated oxygen (DO > 25 mg/L) conditions. The removal rate of both benzoate and 3-nitrobenzoate decreased under anaerobic condition but not under the anoxic condition; 4-chlorophenol biodegradation, on the other hand, was reduced significantly under both anoxic and anaerobic conditions. The removal rates of aromatic compounds, particularly those of 3-nitrobenzoate and 2,4-dichlorophenol, increased significantly under elevated dissolved oxygen conditions. Our results demonstrated that when the biochemical conditions shifted from oxygen-respiration to nitrate respiration, to anaerobiosis, the biodegradation rates of test aromatic compounds decreased or ceased.

Global warming factors (kg CO2-eq.-tonne—1 of waste) have been modelled for 40 different municipal waste management scenarios involving a variety of recycling systems (paper, glass, plastic and organics) and residual waste management by landfilling, incineration or mechanical—biological waste treatment. For average European waste composition most waste management scenarios provided negative global warming factors and hence overall savings in greenhouse gas emissions: Scenarios with landfilling saved 0—400, scenarios with incineration saved 200—700, and scenarios with mechanical-biological treatment saved 200— 750 kg CO2-eq. tonne— 1 municipal waste depending on recycling scheme and energy recovery. Key parameters were the amount of paper recycled (it was assumed that wood made excessive by paper recycling substituted for fossil fuel), the crediting of the waste management system for the amount of energy recovered (hard-coal-based energy was substituted), and binding of biogenic carbon in landfills. Most other processes were of less importance. Rational waste management can provide significant savings in society’s emission of greenhouse gas depending on waste composition and efficient utilization of the energy recovered.

The effect of substrate changes on the performance and microbial community of two-chamber microbial fuel cells (MFCs) was investigated in this study. The MFCs enriched with a single substrate (e.g., acetate, glucose, or butyrate) had different acclimatization capability to substrate changes. The MFC enriched with glucose showed rapid and higher power generation, when glucose was switched with acetate or butyrate. However, the MFC enriched with acetate needed a longer adaptation time for utilizing glucose. Microbial community was also changed when the substrate was changed. Clostridium and Bacilli of phylum Firmicutes were detected in acetate-enriched MFCs after switching to glucose. By contrast, Firmicutes completely disappeared and Geobacter-like species were specifically enriched in glucose-enriched MFCs after feeding acetate to the reactor. This study further suggests that the type of substrate fed to MFC is a very important parameter for reactor performance and microbial community, and significantly affects power generation in MFCs.

Abstract In the present study, thermophilic anaerobic digestion of wheat straw stillage was investigated. Methane potential of stillage was determined in batch experiments at two different substrate concentrations. Results showed that higher methane yields of 324 ml/g-(volatile solids) VS added were obtained at stillage concentrations of 12.8 g-VS/L than at 25.6 g-VS/l. Continuous anaerobic digestion of stillage was performed in an up-flow anaerobic sludge blanket (UASB) reactor at 55 °C with 2 days hydraulic retention time. Results showed that both substrate concentration and organic loading rate (OLR) influenced process performance and methane yields. Maximum methane yield of 155 ml CH 4 /g-COD was obtained at stillage mixtures with water of 25% (v/v) in the feed and at an OLR of 17.1 g-COD/(l.d). Soluble chemical oxygen demand (SCOD) removal at this OLR was 76% (w/w). Increase in OLR to 41.2 g-COD/(l.d) and/or stillage concentration in the feed to 33–50% (v/v) resulted in low methane yields or complete process failure. The results showed that thermophilic anaerobic digestion of wheat straw stillage alone for methane production is feasible in UASB reactor at an OLR of 17.1 g-COD/(l.d) and at substrate concentration of 25% in the feed. The produced methane could improve the process energy and economics of a bioethanol plant and also enable to utilize the stillage in a sustainable manner.

The emission of greenhouse gases (GHGs) is a potential environmental disadvantage of home composting. Because of a lack of reliable GHG emission data, a comprehensive experimental home composting system was set up. The system consisted of six composting units, and a static flux chamber method was used to measure and quantify the GHG emissions for one year composting of organic household waste (OHW). The average OHW input in the six composting units was 2.6-3.5 kg week(-1) and the temperature inside the composting units was in all cases only a few degrees (2-10 °C) higher than the ambient temperature. The emissions of methane (CH(4)) and nitrous oxide (N(2)O) were quantified as 0.4-4.2 kg CH(4)Mg(-1) input wet waste (ww) and 0.30-0.55 kg N(2)OMg(-1)ww, depending on the mixing frequency. This corresponds to emission factors (EFs) (including only CH(4) and N(2)O emissions) of 100-239 kg CO(2)-eq.Mg(-1)ww. Composting units exposed to weekly mixing had the highest EFs, whereas the units with no mixing during the entire year had the lowest emissions. In addition to the higher emission from the frequently mixed units, there was also an instant release of CH(4) during mixing which was estimated to 8-12% of the total CH(4) emissions. Experiments with higher loads of OHW (up to 20 kg every fortnight) entailed a higher emission and significantly increased overall EFs (in kg substance per Mg(-1)ww). However, the temperature development did not change significantly. The GHG emissions (in kg CO(2)-eq.Mg(-1)ww) from home composting of OHW were found to be in the same order of magnitude as for centralised composting plants.

Management of post-consumer solid waste contributes to emission of greenhouse gases (GHGs) representing about 3% of global anthropogenic GHG emissions. Most GHG reporting initiatives around the world utilize two metrics proposed by the Intergovernmental Panel on Climate Change (IPCC): radiative forcing (RF) and global warming potential (GWP). This paper provides a general introduction of the factors that define a GHG and explains the scientific background for estimating RF and GWP, thereby exposing the lay reader to a brief overview of the methods for calculating the effects of GHGs on climate change. An objective of this paper is to increase awareness that the GWP of GHGs has been re-adjusted as the concentration and relative proportion of these GHGs has changed with time (e.g., the GWP of methane has changed from 21 to 25 CO2-eq). Improved understanding of the indirect effects of GHGs has also led to a modification in the methodology for calculating GWP. Following a presentation of theory behind GHG, RF and GWP concepts, the paper briefly describes the most important GHG sources and sinks in the context of the waste management industry. The paper serves as a primer for more detailed research publications presented in this special issue of Waste Management & Research providing a technology-based assessment of quantitative GHG emissions from different waste management technologies.

Anaerobic digestion of palm oil mill effluent (POME) and deoiled POME was investigated both in batch assays and continuous reactor experiments using up-flow anaerobic sludge blanket (UASB) and expanded granular sludge bed (EGSB) reactors. The methane potential determined from batch assays of POME and deoiled POME was 503 and 610 mL-CH(4)/gVS-added, respectively. For the treatment of POME in continuously fed reactors, both in UASB and EGSB reactors more than 90% COD removal could be obtained, at HRT of 5 days, corresponding to OLR of 5.8 gVS/(L-reactor.d). Similar methane yields of 436-438 mL-CH(4)/gVS-added were obtained for UASB and EGSB respectively. However, for treatment of deoiled POME, both UASB and EGSB reactors could operate at lower OLR of 2.6 gVS/(L-reactor.d), with the methane yield of 600 and 555 mL-CH(4)/gVS-added for UASB and EGSB, respectively. The higher methane yield achieved from the deoiled POME was attributed to lower portion of biofibers which are more recalcitrant compared the rest of organic matter in POME. The UASB reactor was found to be more stable than EGSB reactor under the same OLR, as could be seen from lower VFA concentration, especially propionic acid, compared to the EGSB reactor.