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Abstract. Reliable quantification of the sources and sinks of greenhouse gases, together with trends and uncertainties, is essential to monitoring the progress in mitigating anthropogenic emissions under the Paris Agreement. This study provides a consolidated synthesis of CH4 and N2O emissions with consistently derived state-of-the-art bottom-up (BU) and top-down (TD) data sources for the European Union and UK (EU27+UK). We integrate recent emission inventory data, ecosystem process-based model results, and inverse modelling estimates over the period 1990–2018. BU and TD products are compared with European National GHG Inventories (NGHGI) reported to the UN climate convention secretariat UNFCCC in 2019. For uncertainties, we used for NGHGI the standard deviation obtained by varying parameters of inventory calculations, reported by the Member States following the IPCC guidelines recommendations. For atmospheric inversion models (TD) or other inventory datasets (BU), we defined uncertainties from the spread between different model estimates or model specific uncertainties when reported. In comparing NGHGI with other approaches, a key source of bias is the activities included, e.g. anthropogenic versus anthropogenic plus natural fluxes. In inversions, the separation between anthropogenic and natural emissions is sensitive to the geospatial prior distribution of emissions. Over the 2011–2015 period, which is the common denominator of data availability between all sources, the anthropogenic BU approaches are directly comparable, reporting mean emissions of 20.8 Tg CH4 yr−1 (EDGAR v5.0) and 19.0 Tg CH4 yr−1 (GAINS), consistent with the NGHGI estimates of 18.9 ± 1.7 Tg CH4 yr−1. TD total inversions estimates give higher emission estimates, as they also include natural emissions. Over the same period regional TD inversions with higher resolution atmospheric transport models give a mean emission of 28.8 Tg CH4 yr−1. Coarser resolution global TD inversions are consistent with regional TD inversions, for global inversions with GOSAT satellite data (23.3 Tg CH4yr−1) and surface network (24.4 Tg CH4 yr−1). The magnitude of natural peatland emissions from the JSBACH-HIMMELI model, natural rivers and lakes emissions and geological sources together account for the gap between NGHGI and inversions and account for 5.2 Tg CH4 yr−1. For N2O emissions, over the 2011–2015 period, both BU approaches (EDGAR v5.0 and GAINS) give a mean value of anthropogenic emissions of 0.8 and 0.9 Tg N2O yr−1 respectively, agreeing with the NGHGI data (0.9 ± 0.6 Tg N2O yr−1). Over the same period, the average of the three total TD global and regional inversions was 1.3 ± 0.4 and 1.3 ± 0.1 Tg N2O yr−1 respectively, compared to 0.9 Tg N2O yr−1 from the BU data. The TU and BU comparison method defined in this study can be operationalized for future yearly updates for the calculation of CH4 and N2O budgets both at EU+UK scale and at national scale. The referenced datasets related to figures are visualized at https://doi.org/10.5281/zenodo.4288969 (Petrescu et al., 2020).

Abstract The combined production of electricity, heat and cold by a polygeneration system connected to a district heating and cooling network can provide high energy utilization efficiency. The inherent complexity of simultaneous production of different services and the high variability in the energy demand make combined cooling and heating systems performance highly dependent on the operational strategy. In this paper, an operational optimization method based on the moving average of real-time measurements of energy demands and ambient conditions is proposed. Real energy demand data from a district heating and cooling network close to Barcelona, Spain, are used to test the method. A complex polygeneration system is considered, consisting of an internal combustion engine, a double-effect absorption chiller, an electric chiller, a boiler and a cooling tower. A detailed modelling of the system is provided, considering partial load behavior of the components and ambient conditions effects. Results of the real-time optimal management are discussed and compared to traditional operational strategies and to the ideal optimal management achievable with perfectly accurate forecast of energy demands. Moreover, the optimal width of the window adopted for the moving average of real-time data is identified.

Energy consumption is now one of the most important issues for network carriers, since the majority of the energy needed for their operation is consumed in the wireless access and optical transport networks. The continuous growth in the wireless customers and traffic volumes and the consequent energy demand on modern carriers’ broadband infrastructures require reconsidering their energy efficiency, by starting from the formulation of new, more complete and representative network models that should become the foundations for modern energy-aware control plane architectures. Accordingly, this work presents a novel comprehensive energy model for next-generation wireless access-over-optical-transport networks characterized by hybrid power systems (i.e., multiple dynamically available power sources). The objective is to identify the energy-related information that need to be handled at the control plane layer to support energy-aware networking practices. Such information can be made available to suitable energy-aware routing and wavelength assignment algorithms that may exploit them to optimize the overall network energy-consumption and reducing the associated carbon footprint. The proposed model may be taken as a reference for the implementation of new energy-aware control plane protocols (routing and signaling) that make use of power-related considerations to achieve energy-efficiency and energy-awareness in wavelength-routed network infrastructures. Peer Reviewed

In this work, we analyze the performance parameters of the inverted organic solar cells (OSC) partially fabricated under an air environment, comparing them with those of similar solar cells manufactured totally under a nitrogen environment. Both solar cells use PTB7 and PC70BM as the active blend layer. The electrical parameters were extracted from the current density–voltage characteristic ( J–V ) under light and dark conditions. At the beginning, the OSCs partially fabricated under an air environment showed a similar performance as those manufactured under an N2 environment. After 120 h, the power conversion efficiency of the OSCs partially fabricated under an air environment decreased 32% with respect to its initial value. The degradation process under the ISOS-D1 protocols was also analyzed.

It has previously been reported that the use of microwave heating, together with the presence of co-solvents, improves the efficiency of furfural production from biomass. Solid acid catalysts can be a good alternative to mineral acids, since they can prevent corrosion and can be reused. However, the formation of humines should be minimized. Several delaminated and fluorinated hectorites, with different types and strengths of acid sites, were synthesized and tested as catalysts for the production of furfural from commercial xylose and from an acid biomass extract of almond shells. A new methodology was developed to prepare crystalline fluorohectorite at 800 °C in just 3 h. The presence of F significantly increased the acidity strength in the protonated fluorohectorite (H-FH) taking into account its high ammonia desorption temperature (721 °C). Additionally, this sample had fourteen times higher total acidity by m2 than the reference H-βeta acid catalyst. H-FH was the most efficient catalyst at short reaction times (1 h) for the transformation of xylose to furfural under microwaves using toluene as co-solvent, regardless of whether the xylose was commercial (20% furfural yield) or an extract of almond shells (60% furfural yield). However, the acidity of the extract affected the fluorohectorite structure and composition.

The increase in operating temperature of PV generators leads to degradation of their performance. These adverse effects of high temperatures are considered as one of the most important problems that solar panel operation faces in hot weather areas. A lot of research has been undertaken to study this aspect and find ways of limiting the harm caused by such high temperatures. To overcome this harm and to maintain the operating temperature of the PV cells within the optimum range specified by manufacturers, cooling the solar panels often becomes indispensable. This paper discusses the heat transfer through the solar panel layers and studies the effect of high temperature on the solar panel performance in a hot desert environment. It also presents the development of a new solar panel structure viz. by installing an aluminum heat sink to reduce the effect of temperature rise and thus improve the solar panel performance. The study focuses on a pole-mounted solar panel for a street lighting apparatus in extremely hot desert conditions with fluctuating wind speeds. It will be shown that adding an aluminum heat sink to the solar panel bottom mitigates the effect of increased temperature and hence modifies the solar panel operating point by increasing both the efficiency and the lifetime. The solar cell temperature is decreased by 16.4% as a result of the aluminum heat sink installation on the solar panel back sheet and consequently, the accumulated energy produced by the the solar panel is increased by 13.23% per day.

Abstract Distillation of close-boiling mixtures, such as propylene–propane and ethyl benzene–styrene systems, is an energy intensive process. Vapor recompression techniques and heat pumping-assisted columns have been adopted for such applications for their high potential of energy savings. In direct vapor recompression columns, the vapors leaving the top of the column are compressed, and in the reboiler of the same column, these vapors are condensed to provide heat for vapor generation. Internal heat integrated distillation columns or iHIDiCs are new developments employing the same concept of vapor recompression. These new column configurations can have significantly lower energy demands than common vapor recompression units. In iHIDiCs, rectifying section is operated at a higher pressure (i.e. higher temperature) than in stripping, and therefore its heat can be used to generate vapor in stripping section. So far, design of these column configurations is performed based on engineering experience, simulation or experimental studies on given cases, including dynamic control simulations. Within previous and most recent research efforts on iHIDiCs, there exist no generalized design methods or systematic approaches for design of these internal integrated distillation columns. The present paper presents a systematic design procedure for iHIDiCs. A design hierarchy for iHIDiCs is developed, which includes two phases of design, thermodynamic and hydraulics. This design procedure is applied using commercial simulation-based design methods. In thermodynamic design, temperature profiles for column sections are used as a design tool to guide designers. On the other hand, hydraulic capacities of stages for heat exchange are analyzed to determine the maximum physical space area available for heat exchange. Hence, feasibility regions for both heat integration and hydraulic design are identified.

Abstract Liquefied Natural Gas (LNG) is becoming vital in relation to energy transition and fighting climate change. Because of its cryogenic temperature (111 K), LNG is an exergy “mine” that can be exploited in the regasification process for multiple industrial applications. But this exergy is usually wasted. This research presents a Combined Cold and Power (CCP) system with exergy recovery from LNG-regasification. This exergy is exploited for the combined production of electricity and low-temperature refrigeration distributed through a CO 2 District Cooling Network. These systems entail many benefits, but also pending challenges. The CCP system is modelled using real operation data, and its performance is analyzed and benchmarked against that of a cryogenic power plant, both at design and off-design operating conditions. The proposed CCP system reports an equivalent electricity saving of 139 kWh/t-LNG with an exergetic efficiency of 40%, turning into useful energy up to 64% of the maximum cold recoverable in the regasification process. The performance enhances as the heat source temperature rises. Higher LNG flow rates contribute to increase the electricity and refrigeration production, but irreversibilities also increase. Finally, findings show that a low LNG regasification pressure is preferable in spite of the negative effect on the power generation.