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The increasing demand for energy and commodities has led to escalating greenhouse gas emissions, the chief of which is represented by carbon dioxide (CO2). Blue hydrogen (H2), a low-carbon hydrogen produced from natural gas with carbon capture technologies applied, has been suggested as a possible alternative to fossil fuels in processes with hard-to-abate emission sources, including refining, chemical, petrochemical and transport sectors. Due to the recent international directives aimed to combat climate change, even existing hydrogen plants should be retrofitted with carbon capture units. To optimize the process economics of such retrofit, it has been proposed to remove CO2 from the pressure swing adsorption (PSA) tail gas to exploit the relatively high CO2 concentration. This study aimed to design and numerically investigate a vacuum pressure swing adsorption (VPSA) process capable of capturing CO2 from the PSA tail gas of an industrial steam methane reforming (SMR)-based hydrogen plant using NaX zeolite adsorbent. The effect of operating conditions, such as purge-to-feed ratio and desorption pressure, were evaluated in relation to CO2 purity, CO2 recovery, bed productivity and specific energy consumption. We found that conventional cycle configurations, namely a 2-bed, 4-step Skarstrom cycle and a 2-bed, 6-step modified Skarstrom cycle with pressure equalization, were able to concentrate CO2 to a purity greater than 95% with a CO2 recovery of around 77% and 90%, respectively. Therefore, the latter configuration could serve as an efficient process to decarbonize existing hydrogen plants and produce blue H2.

Abstract The sustainable indicators are characterized by a low degree of aggregation and a high amount of information. An indicator must show a synthetic representation of a real environmental, by using a value or a parameter, so that they can be easily used by policy makers. It is necessary to connect, therefore, the various systems in an appropriately integrated sustainable system. The indicators need to be aggregated based on the structure of the data. Each indicator must to be defined through a weight with reference to another weighted indicator. In this paper is illustrated the calculation of the assigned weights that uses a procedure based on fuzzy logic and to define a model that allows us to estimate the sustainability of a city. The final result is, therefore, a combination of values assigned by expert opinion for the various criteria, processed using fuzzy logic to obtain a weight with significant objectivity and as it is possible to estimate the sustainability of the city through the weights.

Abstract In recent years, distributed energy systems (DESs) have been recognized as a promising option for sustainable development of future energy systems, and their application has increased rapidly with supportive policies and financial incentives. With growing concerns on global warming and depletion of fossil fuels, design optimization of DESs through economic assessments for short-run benefits only is not sufficient, while application of exergy principles can improve the efficiency in energy resource use for long-run sustainability of energy supply. The innovation of this paper is to investigate exergy in DES design to attain rational use of energy resources including renewables by considering energy qualities of supply and demand. By using low-temperature sources for low-quality thermal demand, the waste of high-quality energy can be reduced, and the overall exergy efficiency can be increased. The goal of the design optimization problem is to determine types, numbers and sizes of energy devices in DESs to reduce the total annual cost and increase the overall exergy efficiency. Based on a pre-established DES superstructure with multiple energy devices such as combined heat and power and PV, a multi-objective linear problem is formulated. In modeling of energy devices, the novelty is that the entire available size ranges and the variation of their efficiencies, capital and operation and maintenance costs with sizes are considered. The operation of energy devices is modeled based on previous work on DES operation optimization. By minimizing a weighted sum of the total annual cost and primary exergy input, the problem is solved by branch-and-cut. Numerical results show that the Pareto frontier provides good balancing solutions for planners based on economic and sustainability priorities. The total annual cost and primary exergy input of DESs with optimized configurations are reduced by 21–36% as compared with conventional energy supply systems, where grid power is used for the electricity demand, and gas-fired boilers and electric chillers fed by grid power for thermal demand. A sensitivity analysis is also carried out to analyze the influence of energy prices and energy demand variation on the optimized DES configurations.

Background: Sodium oxybate (SMO) has been shown to be effective in the maintenance of abstinence (MoA) in alcohol-dependent patients in a series of small randomized controlled trials (RCTs). These results needed to be confirmed by a large trial investigating the treatment effect and its sustainability after medication discontinuation. Aims: To confirm the SMO effect on (sustained) MoA in detoxified alcohol-dependent patients. Methods: Large double-blind, randomized, placebo-controlled trial in detoxified adult alcohol-dependent outpatients (80% men) from 11 sites in four European countries. Patients were randomized to 6 months SMO (3.3–3.9 g/day) or placebo followed by a 6-month medication-free period. Primary outcome was the cumulative abstinence duration (CAD) during the 6-month treatment period defined as the number of days with no alcohol use. Secondary outcomes included CAD during the 12-month study period. Results: Of the 314 alcohol-dependent patients randomized, 154 received SMO and 160 received placebo. Based on the pre-specified fixed-effect two-way analysis of variance including the treatment-by-site interaction, SMO showed efficacy in CAD during the 6-month treatment period: mean difference +43.1 days, 95% confidence interval (17.6–68.5; p = 0.001). Since significant heterogeneity of effect across sites and unequal sample sizes among sites ( n = 3–66) were identified, a site-level random meta-analysis was performed with results supporting the pre-specified analysis: mean difference +32.4 days, p = 0.014. The SMO effect was sustained during the medication-free follow-up period. SMO was well-tolerated. Conclusions: Results of this large RCT in alcohol-dependent patients demonstrated a significant and clinically relevant sustained effect of SMO on CAD. Trial registration: ClinicalTrials.gov Identifier: NCT04648423

In this paper we argue for the need to apply a cognitive approach to understand deep dynamics and determinants of technological evolutions. After examining main contributions from innovation studies to the conceptualization of innovation and change in complex socio-technical environments, we highlight the contribution coming from the application of the cognitive approach to evolutionary studies on technologies and we introduce the concept of technological memory as an interpretative tool to understand those changes. We discuss our hypothesis with reference to several observations carried out in different local contexts – Mexico, India and Italy – in relation to technological change in the water sector. In those cases deliberate attempts to substitute traditional technologies with modern ones led to interesting trajectories of change ranging from the collapse of old technologies to the development of multifaceted hybridization patterns. Tema. Journal of Land Use, Mobility and Environment, 2014: INPUT 2014 - Smart City: planning for energy, transportation and sustainability of the urban system

The progressive geography of climate change impacts places the African continent among the most vulnerable regions of the world. In line with the prediction of the Intergovernmental Panel on Climate Change in its first report (1990), the involuntary migration of population is already proving to be one of the most serious of such impacts across the region. The overwhelming majority of victims remain within their own countries. Therefore, coupled with conflict, violence and development projects, slow-onset and rapid-onset disasters have currently made Africa home to the largest number of internally displaced people. Determined to tackle this plight, on 23rd October 2009 the African Union adopted its Convention for the Protection and Assistance of Internally Displaced Persons in Africa (Kampala Convention), articulating the need for a holistic response based on a combined framework of international human rights law and international humanitarian law. Five years since the convention entered into force (on 6th December 2012), this paper aims to taking stock of the progress made in its implementation and, in particular, assessing its effectiveness in protecting people environmentally displaced in the context of climate change. To this end, it identifies the existing and ongoing normative, policy and institutional processes on domestication and implementation of the convention and explores the degree to which these processes provide for the protection due to people displaced by environmental disasters, specially those slow-onset (e.g. desertification). The paper finds that, despite the remarkable efforts towards the implementation of the said convention, the concrete impact of its provisions on enhancing the protection of and assistance to environmental IDPs is still unperceiv

PurposeThe pressure of globalization has raised social concerns related to the protection of the environment, forced companies to use sustainability as a strategic weapon to fulfill the legal obligations and achieve overall competitiveness. It is reported that small- and medium-sized enterprises (SMEs) are globally responsible for approximately 70 percent of the industrial pollution, justifying urgent attention to the operations of these businesses. The purpose of this paper is to analyze the impact of sustainability orientation (SO) and supply chain (SC) integration implemented by SMEs on their sustainable procurement (SP) and design. Moreover, this study examines how SMEs’ SP and design affect their environmental and cost performance (CP).Design/methodology/approachThe authors develop a comprehensive model to test the relationships among SC, SC integration, SP, sustainable design (SD), environmental performance (EP) and CP at the SMEs level. The authors investigate the relationships of the mentoned factors by a data set that is collected from 358 Indian manufacturing SMEs.FindingsThe results indicate that in the SMEs’ context: SO positively influences both SP and SD; external integration positively affects SP; internal integration positively affects SD; SP positively influences EP and has not impact on CP; and SD positively influences both EP and CP.Originality/valueThis study provides a broad view of the relation between driving factors that may direct SMEs toward a better sustainability performance and offers practical managerial insights into these important business entities.

A continuous growth of international trade, especially between developing countries, has greatly increased carbon dioxide (CO2) emissions associated with energy consumption over the past two decades. Given the more intensified intraregional cooperation and trade within the Belt and Road Initiative (BRI), this study aims to trace the imbalance of CO2 embodied in trade between nations in BRI and the rest of the world, providing new insights into the drivers of emissions growth by contrasting consumption, production and technological differences-based perspectives. Results indicate that the BRI contributed to over 50% of global carbon footprint and 92% of its increase in 1995–2015. The BRI was a net exporter of trade-embodied emissions, whose technological-adjusted carbon footprint remained remarkably large due to comparatively high carbon intensity. Geographically, carbon leakage has gradually moved from China and India to other BRI countries, especially to Southeast Asia, West Asia and Africa. Technological change was the key driver of emissions reduction, followed by the change in industrial structure. The growth in final demand per capita was the most important driver for the growth of CO2 emissions in BRI. Improving carbon efficiency remains a critical step for BRI nations to slow down not only emissions growth but also carbon leakage. The paper managed to provide novel insights into the carbon leakage in BRI by contrasting the consumption, production and technological differences-based perspectives, thus being able to better inform policymakers on region-specific low-carbon transition and global climate governance.