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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Joy Sankar Roy; Younès Messaddeq;

    The global challenge of sustainable and affordable wastewater treatment technology looms large as water pollution escalates steadily with the rapid pace of industrialization and population growth. The photocatalytic wastewater treatment is a cutting-edge and environmentally friendly technology that uses photons from light source to degrade and remove organic and inorganic contaminants from water. Thus, utilizing solar energy for photocatalytic wastewater treatment holds great promise as a renewable solution to alleviate pressures on the global water crisis. Employing solar concentrators to intensify sunlight for photocatalysis represents a promising avenue for future applications of a low-cost and rapid sustainable wastewater purification process. This groundbreaking approach will unveil fresh technological avenues for a cost-effective, sustainable, and swift wastewater purification process utilizing sunlight. This review article explores diverse solar concentrating systems and their potential applications in the wastewater treatment process.

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    Energies
    Article . 2024 . Peer-reviewed
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Energies
      Article . 2024 . Peer-reviewed
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    Authors: Chinnadurai Kathiravan; Murugesan Selvam; Balasundram Maniam; Leo Paul Dana; +1 Authors

    The goal of this study is to look into how changes in crude oil prices affect GDP per capita and exchange rate fluctuations.to investigate the influence of crude oil price shocks on GDP per capita and exchange rate movements. This research employed yearly time series data for the price of crude oil, exchange rate (USD/INR), and GDP per capita, from 1990 to 2020. Arithmetical tools such as Descriptive, Unit Root, Granger Causality Test, and OLS Model were applied. The present study discovered a strong bi-directional Granger causality effect of Dubai crude oil prices on exchange rates, as well as a bi-directional Granger influence of exchange rates on WTI crude oil prices. The diagnostic tests were successfully passed by the estimated models. According to the OLS model, the exchange rate was driven only by the price of Dubai crude oil, although the price of WTI crude oil influenced both the GDP per capita and the exchange rate over the research period. The key policy recommendation derived from this analysis is that the Reserve Bank of India (RBI) must depreciate the rupee, first to restore much-needed exchange rate stability, then to stimulate domestic manufacturers, and finally, to attract foreign capital inflows.

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    Energies
    Article . 2023 . Peer-reviewed
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    Energies
    Article . 2023
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Energies
      Article . 2023 . Peer-reviewed
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      Energies
      Article . 2023
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    Authors: Jacek Majorowicz; Stephen E. Grasby;

    We summarize the feasibility of using geothermal energy from the Western Canada Sedimentary Basin (WCSB) to support communities with populations >3000 people, including those in northeastern British Columbia, southwestern part of Northwest Territories (NWT), southern Saskatchewan, and southeastern Manitoba, along with previously studied communities in Alberta. The geothermal energy potential of the WCSB is largely determined by the basin’s geometry; the sediments start at 0 m thickness adjacent to the Canadian shield in the east and thicken to >6 km to the west, and over 3 km in the Williston sub-basin to the south. Direct heat use is most promising in the western and southern parts of the WCSB where sediment thickness exceeds 2–3 km. Geothermal potential is also dependent on the local geothermal gradient. Aquifers suitable for heating systems occur in western-northwestern Alberta, northeastern British Columbia, and southwestern Saskatchewan. Electrical power production is limited to the deepest parts of the WCSB, where aquifers >120 °C and fluid production rates >80 kg/s occur (southwestern Northwest Territories, northwestern Alberta, northeastern British Columbia, and southeastern Saskatchewan. For the western regions with the thickest sediments, the foreland basin east of the Rocky Mountains, estimates indicate that geothermal power up to 2 MWel. (electrical), and up to 10 times higher for heating in MWth. (thermal), are possible.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2021 . Peer-reviewed
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    Energies
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    Energies
    Article . 2021
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Energies
      Article . 2021 . Peer-reviewed
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      Energies
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      Energies
      Article . 2021
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    Authors: Liang Hao; Minli Bai; Liu Xuanyu; Yang Li; +5 Authors

    In this work, three-dimensional thermal simulations of single 18650 lithium-ion battery cell and 75 V lithium-ion battery pack composed of 21 18650 battery cells are performed based on a multi-scale multi-domain (MSMD) battery modeling approach. Different cooling approaches’ effects on 18650 lithium-ion battery and battery pack thermal management under fast discharging and external shorting conditions are investigated and compared. It is found that for the natural convection, forced air cooling, and/or mini-channel liquid cooling approaches, the temperature of battery cell easily exceeds 40 °C under 3C rate discharging condition. While under external shorting condition, the temperature of cell rises sharply and reaches the 80 °C in a short period of time, which can trigger thermal runaway and may even lead to catastrophic battery fire. On the other hand, when the cooling method is single-phase direct cooling with FC-72 as coolant or two-phase immersed cooling by HFE-7000, the cell temperature is effectively limited to a tolerable level under both high C rate discharging and external shorting conditions. In addition, two-phase immersed cooling scheme is found to lead to better temperature uniformity according to the 75 V battery pack simulations.

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    Energies
    Article . 2021 . Peer-reviewed
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    Energies
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    Energies
    Article . 2021
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Energies
      Article . 2021 . Peer-reviewed
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      Energies
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      Energies
      Article . 2021
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    Authors: Kyle R. Gluesenkamp; Andrea Frazzica; Andreas Velte; Steven Metcalf; +11 Authors

    The thermal masses of components influence the performance of many adsorption heat pump systems. However, typically when experimental adsorption systems are reported, data on thermal mass are missing or incomplete. This work provides original measurements of the thermal masses for experimental sorption heat exchanger hardware. Much of this hardware was previously reported in the literature, but without detailed thermal mass data. The data reported in this work are the first values reported in the literature to thoroughly account for all thermal masses, including heat transfer fluid. The impact of thermal mass on system performance is also discussed, with detailed calculation left for future work. The degree to which heat transfer fluid contributes to overall effective thermal mass is also discussed, with detailed calculation left for future work. This work provides a framework for future reporting of experimental thermal masses. The utilization of this framework will enrich the data available for model validation and provide a more thorough accounting of adsorption heat pumps.

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    Energies
    Article . 2020 . Peer-reviewed
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    Article . 2020
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      Energies
      Article . 2020 . Peer-reviewed
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      CNR ExploRA
      Article . 2020
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    Authors: Aran Shoaei; Farnam Farshbaf-Roomi; Qingsong Wang;

    Due to their contact-free and low-maintenance features, magnetic gears (MGs) have been increasingly investigated to amplify the torque of electric motors in electric vehicles (EVs). In order to meet the requirements of propelling EVs, it is essential to design an MG with a high torque density. In this paper, a novel flux-focusing Halbach coaxial MG (FFH-CMG) is proposed, which combines the advantages of flux focusing and Halbach permanent magnet (PM) arrays. The proposed structure has a higher torque performance and greater efficiency than conventional structures. A multi-objective design optimization based on a surrogate model is implemented to achieve the maximum volumetric torque density (VTD), torque-per-PM volume (TPMV), and efficiency, as well as the minimum torque ripple, in the proposed FFH-CMG. The employed optimization approach has a higher accuracy and is less time-consuming compared to the conventional optimization methods based on direct finite-element analysis (FEA). The performance of the proposed FFH-CMG is then investigated through 2D-FEA. According to the simulation results, the optimized FFH-CMG can achieve a VTD of 411 kNm/m3, and a TPMV of 830 kNm/m3, which are significantly larger than those of the existing MGs and make the proposed FFH-CMG very suitable for EV applications.

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    Energies
    Article . 2024 . Peer-reviewed
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    Energies
    Article . 2024
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      Energies
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      Energies
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    Authors: Francis Kus; Robin Hughes; Arturo Macchi; Poupak Mehrani; +1 Authors

    Reduced order models (ROMs) are increasingly applied to entrained flow gasification development due to reduced computational requirements relative to computational fluid dynamics (CFD) models. However, they require greater a posteriori knowledge of the reactor physics. A significant parameter influencing ROM outputs is the jet half-angle of the solid fuel and oxidant mixture in the gasifier. Thus, it is important to understand the geometry of the jet in the gasifier, and how it is dependent on operating parameters, such as solid and carrier gas flow rates. In this work, an existing model for jet half-angles, which considers the ratio of surrounding gas density to jet core density, is extended to a dry solids jet with impinging gas. The model is fitted to experimental jet half-angles. The jet half-angle of a non-reactive flow was measured using laser-sheet imaging for solid fluxes in the range of 460–880 kg/m2·s and carrier gas fluxes in the range of 43–90 kg/m2·s at the transport line outlet. Jet half-angles ranged from 5.6° to 11.3°, increasing with lower solid/gas loading ratios. CFD simulations of two reactive conditions, with solid and gas fluxes similar to experiments, were used to test the applicability of the proposed jet half-angle model.

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    Energies
    Article . 2018 . Peer-reviewed
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    Energies
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    Energies
    Article . 2018
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      Energies
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      Energies
      Article . 2018
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    Authors: Mohsen Rostami; Nima Talebzadeh; Paul G. O’Brien;

    Numerical calculations are performed to determine the potential of using one-dimensional transparent photonic crystal heat mirrors (TPCHMs) as transparent coatings for solar receivers. At relatively low operating temperatures of 500 K, the TPCHMs investigated herein do not provide a significant advantage over conventional transparent heat mirrors that are made using transparent conducting oxide films. However, the results show that TPCHMs can enhance the performance of transparent solar receiver covers at higher operating temperatures. At 1000 K, the amount of radiation reflected by a transparent cover back to the receiver can be increased from 40.4% to 60.0%, without compromising the transmittance of solar radiation through the cover, by using a TPCHM in the place of a conventional transparent mirror with a In2O3:Sn film. For a receiver operating temperature of 1500 K, the amount of radiation reflected back to the receiver can be increased from 25.7% for a cover that is coated with a In2O3:Sn film to 57.6% for a cover with a TPCHM. The TPCHM that is presented in this work might be useful for high-temperature applications where high-performance is required over a relatively small area, such as the cover for evacuated receivers or volumetric receivers in Sterling engines.

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    Energies
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    Energies
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    Energies
    Article . 2020
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      Energies
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      Energies
      Article . 2020
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    Authors: Yun Li; Ping Guo; Fanhua Zeng; Zhouhua Wang; +2 Authors

    As kerogen is the main organic component in shale, the adsorption capacity, diffusion and permeability of the gas in kerogen plays an important role in shale gas production. Based on the molecular model of type II kerogen, an organic nanoporous structure was established. The Grand Canonical Monte Carlo (GCMC) and Molecular Dynamics (MD) methods were used to study the adsorption and diffusion capacity of mixed gas systems with different mole ratios of CO2 and CH4 in the foregoing nanoporous structure, and gas adsorption, isosteric heats of adsorption and self-diffusion coefficient were obtained. The selective permeation of gas components in the organic pores was further studied. The results show that CO2 and CH4 present physical adsorption in the organic nanopores. The adsorption capacity of CO2 is larger than that of CH4 in organic pores, but the self-diffusion coefficient of CH4 in mixed gas is larger than that of CO2. Moreover, the self-diffusion coefficient in the horizontal direction is larger than that in the vertical direction. The mixed gas pressure and mole ratio have limited effects on the isosteric heat and the self-diffusion of CH4 and CO2 adsorption. Regarding the analysis of mixed gas selective permeation, it is concluded that the adsorption selectivity of CO2 is larger than that of CH4 in the organic nanopores. The larger the CO2/CH4 mole ratio, the greater the adsorption and permeation selectivity of mixed gas in shale. The permeation process is mainly controlled by adsorption rather than diffusion. These results are expected to reveal the adsorption and diffusion mechanism of gas in shale organics, which has a great significance for further research.

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    Energies
    Article . 2017 . Peer-reviewed
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    Energies
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    Article . 2017
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      Energies
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    Authors: Jonathan Banks; Spencer Poulette; Jens Grimmer; Florian Bauer; +1 Authors

    The campus of the Karlsruhe Institute of Technology (KIT) contains several waste heat streams. In an effort to reduce greenhouse gas emissions by optimizing thermal power consumption on the campus, researchers at the KIT are proposing a ‘DeepStor’ project, which will sequester waste heat from these streams in an underground reservoir during the summer months, when the heat is not required. The stored heat will then be reproduced in the winter, when the campus’s thermal power demand is much higher. This paper contains a preliminary geochemical risk assessment for the operation of this subsurface, seasonal geothermal energy storage system. We used equilibrium thermodynamics to determine the potential phases and extent of mineral scale formation in the plant’s surface infrastructure, and to identify possible precipitation, dissolution, and ion exchange reactions that may lead to formation damage in the reservoir. The reservoir in question is the Meletta Beds of the Upper Rhein Graben’s Froidefontaine Formation. We modeled scale- and formation damage-causing reactions during six months of injecting 140 °C fluid into the reservoir during the summer thermal storage season and six months of injecting 80 °C fluid during the winter thermal consumption season. Overall, we ran the models for 5 years. Anhydrite and calcite are expected mineral scales during the thermal storage season (summer). Quartz is the predicted scale-forming mineral during the thermal consumption period (winter). Within ~20 m of the wellbores, magnesium and iron are leached from biotite; calcium and magnesium are leached from dolomite; and sodium, aluminum, and silica are leached from albite. These reactions lead to a net increase in both porosity and permeability in the wellbore adjacent region. At a distance of ~20–75 m from the wellbores, the leached ions recombine with the reservoir rocks to form a variety of clays, i.e., saponite, minnesotaite, and daphnite. These alteration products lead to a net loss in porosity and permeability in this zone. After each thermal storage and production cycle, the reservoir shows a net retention of heat, suggesting that the operation of the proposed DeepStor project could successfully store heat, if the geochemical risks described in this paper can managed.

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    Energies
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    https://dx.doi.org/10.26083/tu...
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Joy Sankar Roy; Younès Messaddeq;

    The global challenge of sustainable and affordable wastewater treatment technology looms large as water pollution escalates steadily with the rapid pace of industrialization and population growth. The photocatalytic wastewater treatment is a cutting-edge and environmentally friendly technology that uses photons from light source to degrade and remove organic and inorganic contaminants from water. Thus, utilizing solar energy for photocatalytic wastewater treatment holds great promise as a renewable solution to alleviate pressures on the global water crisis. Employing solar concentrators to intensify sunlight for photocatalysis represents a promising avenue for future applications of a low-cost and rapid sustainable wastewater purification process. This groundbreaking approach will unveil fresh technological avenues for a cost-effective, sustainable, and swift wastewater purification process utilizing sunlight. This review article explores diverse solar concentrating systems and their potential applications in the wastewater treatment process.

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    Energies
    Article . 2024 . Peer-reviewed
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    Authors: Chinnadurai Kathiravan; Murugesan Selvam; Balasundram Maniam; Leo Paul Dana; +1 Authors

    The goal of this study is to look into how changes in crude oil prices affect GDP per capita and exchange rate fluctuations.to investigate the influence of crude oil price shocks on GDP per capita and exchange rate movements. This research employed yearly time series data for the price of crude oil, exchange rate (USD/INR), and GDP per capita, from 1990 to 2020. Arithmetical tools such as Descriptive, Unit Root, Granger Causality Test, and OLS Model were applied. The present study discovered a strong bi-directional Granger causality effect of Dubai crude oil prices on exchange rates, as well as a bi-directional Granger influence of exchange rates on WTI crude oil prices. The diagnostic tests were successfully passed by the estimated models. According to the OLS model, the exchange rate was driven only by the price of Dubai crude oil, although the price of WTI crude oil influenced both the GDP per capita and the exchange rate over the research period. The key policy recommendation derived from this analysis is that the Reserve Bank of India (RBI) must depreciate the rupee, first to restore much-needed exchange rate stability, then to stimulate domestic manufacturers, and finally, to attract foreign capital inflows.

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    Energies
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    Authors: Jacek Majorowicz; Stephen E. Grasby;

    We summarize the feasibility of using geothermal energy from the Western Canada Sedimentary Basin (WCSB) to support communities with populations >3000 people, including those in northeastern British Columbia, southwestern part of Northwest Territories (NWT), southern Saskatchewan, and southeastern Manitoba, along with previously studied communities in Alberta. The geothermal energy potential of the WCSB is largely determined by the basin’s geometry; the sediments start at 0 m thickness adjacent to the Canadian shield in the east and thicken to >6 km to the west, and over 3 km in the Williston sub-basin to the south. Direct heat use is most promising in the western and southern parts of the WCSB where sediment thickness exceeds 2–3 km. Geothermal potential is also dependent on the local geothermal gradient. Aquifers suitable for heating systems occur in western-northwestern Alberta, northeastern British Columbia, and southwestern Saskatchewan. Electrical power production is limited to the deepest parts of the WCSB, where aquifers >120 °C and fluid production rates >80 kg/s occur (southwestern Northwest Territories, northwestern Alberta, northeastern British Columbia, and southeastern Saskatchewan. For the western regions with the thickest sediments, the foreland basin east of the Rocky Mountains, estimates indicate that geothermal power up to 2 MWel. (electrical), and up to 10 times higher for heating in MWth. (thermal), are possible.

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    Authors: Liang Hao; Minli Bai; Liu Xuanyu; Yang Li; +5 Authors

    In this work, three-dimensional thermal simulations of single 18650 lithium-ion battery cell and 75 V lithium-ion battery pack composed of 21 18650 battery cells are performed based on a multi-scale multi-domain (MSMD) battery modeling approach. Different cooling approaches’ effects on 18650 lithium-ion battery and battery pack thermal management under fast discharging and external shorting conditions are investigated and compared. It is found that for the natural convection, forced air cooling, and/or mini-channel liquid cooling approaches, the temperature of battery cell easily exceeds 40 °C under 3C rate discharging condition. While under external shorting condition, the temperature of cell rises sharply and reaches the 80 °C in a short period of time, which can trigger thermal runaway and may even lead to catastrophic battery fire. On the other hand, when the cooling method is single-phase direct cooling with FC-72 as coolant or two-phase immersed cooling by HFE-7000, the cell temperature is effectively limited to a tolerable level under both high C rate discharging and external shorting conditions. In addition, two-phase immersed cooling scheme is found to lead to better temperature uniformity according to the 75 V battery pack simulations.

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      Article . 2021
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    Authors: Kyle R. Gluesenkamp; Andrea Frazzica; Andreas Velte; Steven Metcalf; +11 Authors

    The thermal masses of components influence the performance of many adsorption heat pump systems. However, typically when experimental adsorption systems are reported, data on thermal mass are missing or incomplete. This work provides original measurements of the thermal masses for experimental sorption heat exchanger hardware. Much of this hardware was previously reported in the literature, but without detailed thermal mass data. The data reported in this work are the first values reported in the literature to thoroughly account for all thermal masses, including heat transfer fluid. The impact of thermal mass on system performance is also discussed, with detailed calculation left for future work. The degree to which heat transfer fluid contributes to overall effective thermal mass is also discussed, with detailed calculation left for future work. This work provides a framework for future reporting of experimental thermal masses. The utilization of this framework will enrich the data available for model validation and provide a more thorough accounting of adsorption heat pumps.

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    Energies
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    Article . 2020
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    Authors: Aran Shoaei; Farnam Farshbaf-Roomi; Qingsong Wang;

    Due to their contact-free and low-maintenance features, magnetic gears (MGs) have been increasingly investigated to amplify the torque of electric motors in electric vehicles (EVs). In order to meet the requirements of propelling EVs, it is essential to design an MG with a high torque density. In this paper, a novel flux-focusing Halbach coaxial MG (FFH-CMG) is proposed, which combines the advantages of flux focusing and Halbach permanent magnet (PM) arrays. The proposed structure has a higher torque performance and greater efficiency than conventional structures. A multi-objective design optimization based on a surrogate model is implemented to achieve the maximum volumetric torque density (VTD), torque-per-PM volume (TPMV), and efficiency, as well as the minimum torque ripple, in the proposed FFH-CMG. The employed optimization approach has a higher accuracy and is less time-consuming compared to the conventional optimization methods based on direct finite-element analysis (FEA). The performance of the proposed FFH-CMG is then investigated through 2D-FEA. According to the simulation results, the optimized FFH-CMG can achieve a VTD of 411 kNm/m3, and a TPMV of 830 kNm/m3, which are significantly larger than those of the existing MGs and make the proposed FFH-CMG very suitable for EV applications.

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    Energies
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    Authors: Francis Kus; Robin Hughes; Arturo Macchi; Poupak Mehrani; +1 Authors

    Reduced order models (ROMs) are increasingly applied to entrained flow gasification development due to reduced computational requirements relative to computational fluid dynamics (CFD) models. However, they require greater a posteriori knowledge of the reactor physics. A significant parameter influencing ROM outputs is the jet half-angle of the solid fuel and oxidant mixture in the gasifier. Thus, it is important to understand the geometry of the jet in the gasifier, and how it is dependent on operating parameters, such as solid and carrier gas flow rates. In this work, an existing model for jet half-angles, which considers the ratio of surrounding gas density to jet core density, is extended to a dry solids jet with impinging gas. The model is fitted to experimental jet half-angles. The jet half-angle of a non-reactive flow was measured using laser-sheet imaging for solid fluxes in the range of 460–880 kg/m2·s and carrier gas fluxes in the range of 43–90 kg/m2·s at the transport line outlet. Jet half-angles ranged from 5.6° to 11.3°, increasing with lower solid/gas loading ratios. CFD simulations of two reactive conditions, with solid and gas fluxes similar to experiments, were used to test the applicability of the proposed jet half-angle model.

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    Energies
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    Article . 2018
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    Authors: Mohsen Rostami; Nima Talebzadeh; Paul G. O’Brien;

    Numerical calculations are performed to determine the potential of using one-dimensional transparent photonic crystal heat mirrors (TPCHMs) as transparent coatings for solar receivers. At relatively low operating temperatures of 500 K, the TPCHMs investigated herein do not provide a significant advantage over conventional transparent heat mirrors that are made using transparent conducting oxide films. However, the results show that TPCHMs can enhance the performance of transparent solar receiver covers at higher operating temperatures. At 1000 K, the amount of radiation reflected by a transparent cover back to the receiver can be increased from 40.4% to 60.0%, without compromising the transmittance of solar radiation through the cover, by using a TPCHM in the place of a conventional transparent mirror with a In2O3:Sn film. For a receiver operating temperature of 1500 K, the amount of radiation reflected back to the receiver can be increased from 25.7% for a cover that is coated with a In2O3:Sn film to 57.6% for a cover with a TPCHM. The TPCHM that is presented in this work might be useful for high-temperature applications where high-performance is required over a relatively small area, such as the cover for evacuated receivers or volumetric receivers in Sterling engines.

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    Article . 2020
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    Authors: Yun Li; Ping Guo; Fanhua Zeng; Zhouhua Wang; +2 Authors

    As kerogen is the main organic component in shale, the adsorption capacity, diffusion and permeability of the gas in kerogen plays an important role in shale gas production. Based on the molecular model of type II kerogen, an organic nanoporous structure was established. The Grand Canonical Monte Carlo (GCMC) and Molecular Dynamics (MD) methods were used to study the adsorption and diffusion capacity of mixed gas systems with different mole ratios of CO2 and CH4 in the foregoing nanoporous structure, and gas adsorption, isosteric heats of adsorption and self-diffusion coefficient were obtained. The selective permeation of gas components in the organic pores was further studied. The results show that CO2 and CH4 present physical adsorption in the organic nanopores. The adsorption capacity of CO2 is larger than that of CH4 in organic pores, but the self-diffusion coefficient of CH4 in mixed gas is larger than that of CO2. Moreover, the self-diffusion coefficient in the horizontal direction is larger than that in the vertical direction. The mixed gas pressure and mole ratio have limited effects on the isosteric heat and the self-diffusion of CH4 and CO2 adsorption. Regarding the analysis of mixed gas selective permeation, it is concluded that the adsorption selectivity of CO2 is larger than that of CH4 in the organic nanopores. The larger the CO2/CH4 mole ratio, the greater the adsorption and permeation selectivity of mixed gas in shale. The permeation process is mainly controlled by adsorption rather than diffusion. These results are expected to reveal the adsorption and diffusion mechanism of gas in shale organics, which has a great significance for further research.

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    Authors: Jonathan Banks; Spencer Poulette; Jens Grimmer; Florian Bauer; +1 Authors

    The campus of the Karlsruhe Institute of Technology (KIT) contains several waste heat streams. In an effort to reduce greenhouse gas emissions by optimizing thermal power consumption on the campus, researchers at the KIT are proposing a ‘DeepStor’ project, which will sequester waste heat from these streams in an underground reservoir during the summer months, when the heat is not required. The stored heat will then be reproduced in the winter, when the campus’s thermal power demand is much higher. This paper contains a preliminary geochemical risk assessment for the operation of this subsurface, seasonal geothermal energy storage system. We used equilibrium thermodynamics to determine the potential phases and extent of mineral scale formation in the plant’s surface infrastructure, and to identify possible precipitation, dissolution, and ion exchange reactions that may lead to formation damage in the reservoir. The reservoir in question is the Meletta Beds of the Upper Rhein Graben’s Froidefontaine Formation. We modeled scale- and formation damage-causing reactions during six months of injecting 140 °C fluid into the reservoir during the summer thermal storage season and six months of injecting 80 °C fluid during the winter thermal consumption season. Overall, we ran the models for 5 years. Anhydrite and calcite are expected mineral scales during the thermal storage season (summer). Quartz is the predicted scale-forming mineral during the thermal consumption period (winter). Within ~20 m of the wellbores, magnesium and iron are leached from biotite; calcium and magnesium are leached from dolomite; and sodium, aluminum, and silica are leached from albite. These reactions lead to a net increase in both porosity and permeability in the wellbore adjacent region. At a distance of ~20–75 m from the wellbores, the leached ions recombine with the reservoir rocks to form a variety of clays, i.e., saponite, minnesotaite, and daphnite. These alteration products lead to a net loss in porosity and permeability in this zone. After each thermal storage and production cycle, the reservoir shows a net retention of heat, suggesting that the operation of the proposed DeepStor project could successfully store heat, if the geochemical risks described in this paper can managed.

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