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As part of global efforts to reduce dependence on carbon-based energy sources there has been a rapid increase in the installation of renewable energy devices. The installation and operation of these devices can result in conflicts with wildlife. In the marine environment, mammals may avoid wind farms that are under construction or operating. Such avoidance may lead to more time spent travelling or displacement from key habitats. A paucity of data on at-sea movements of marine mammals around wind farms limits our understanding of the nature of their potential impacts. Here, we present the results of a telemetry study on harbour seals Phoca vitulina in The Wash, south-east England, an area where wind farms are being constructed using impact pile driving. We investigated whether seals avoid wind farms during operation, construction in its entirety, or during piling activity. The study was carried out using historical telemetry data collected prior to any wind farm development and telemetry data collected in 2012 during the construction of one wind farm and the operation of another. Within an operational wind farm, there was a close-to-significant increase in seal usage compared to prior to wind farm development. However, the wind farm was at the edge of a large area of increased usage, so the presence of the wind farm was unlikely to be the cause. There was no significant displacement during construction as a whole. However, during piling, seal usage (abundance) was significantly reduced up to 25 km from the piling activity; within 25 km of the centre of the wind farm, there was a 19 to 83% (95% confidence intervals) decrease in usage compared to during breaks in piling, equating to a mean estimated displacement of 440 individuals. This amounts to significant displacement starting from predicted received levels of between 166 and 178 dB re 1 μPa(p-p). Displacement was limited to piling activity; within 2 h of cessation of pile driving, seals were distributed as per the non-piling scenario. Synthesis and applications. Our spatial and temporal quantification of avoidance of wind farms by harbour seals is critical to reduce uncertainty and increase robustness in environmental impact assessments of future developments. Specifically, the results will allow policymakers to produce industry guidance on the likelihood of displacement of seals in response to pile driving; the relationship between sound levels and avoidance rates; and the duration of any avoidance, thus allowing far more accurate environmental assessments to be carried out during the consenting process. Further, our results can be used to inform mitigation strategies in terms of both the sound levels likely to cause displacement and what temporal patterns of piling would minimize the magnitude of the energetic impacts of displacement. Wash_diagWash_diag.xlsx is the historic location data (pre windfarm construction) for the 19 individuals used in the analysis described in Russell et al.

This dataset contains time series of reservoir releases (including any spills), evaporation loss, and rule curves for the Pong and Bhakra reservoirs, India. {"references": ["https://doi.org/10.3390/w11071413", "https://doi.org/10.1016/j.scitotenv.2019.06.021"]}

The present work focuses on the sampling procedure and quantification of the PAH yield from the fast pyrolysis of waste softwood. In particular, fast pyrolysis experiments were conducted using a CDS Pyroprobe 5200 at temperatures between 500 °C and 1000 °C, at a heating rate of 600 °C/s for a sample size of 30 mg. High performance liquid chromatography (HPLC) was used for the determination of the PAH compounds present in the liquid sample fraction, while a micro – GC was employed for the analysis of the main gaseous products (CO, CO2, CH4 and H2). An alternative tar sampling protocol was proposed, which employed the use of a cold trap (50 °C) and an isopropanol filled impinger bottle for the collection of the condensable products. The experiments were compared to heated foil reactor based pyrolysis tests within the same temperature range and heating rate, except for a slightly lower sample size (10 mg). The Pyroprobe and adapted sampling system proved to be more efficient regarding PAH capture and quantification compared to the heated foil reactor. Naphthalene, acenaphthylene and phenanthrene were the main PAH compounds detected. The PAH yields increased with pyrolysis temperature, up to values corresponding to roughly 0.2 wt% of the overall yield at 1000 °C. From the results it was derived that PAH evolution is mainly a product of secondary decomposition of primary tar, since the char yield stabilized for higher temperatures and the yields of CO, H2 and CH4 increased. Overall mass balance closure values were around 80 wt% on average. Char and gas yields were determined with high reproducibility, however gravimetric liquid analysis lacked due to the inability to gravimetrically measure the yield condensing in the impinger bottle. Future work is aimed on improving on this particular aspect. Overall, the alternative tar sampling system proposed was successful in the quantification of PAH from biomass fast pyrolysis experiments offering increased flexibility, accuracy and practicality of use.

1. Tidal stream energy converters (turbines) are currently being installed in tidally energetic coastal sites. However, there is currently a high level of uncertainty surrounding the potential environmental impacts on marine mammals. This is a key consenting risk to commercial introduction of tidal energy technology. Concerns derive primarily from the potential for injury to marine mammals through collisions with moving components of turbines. To understand the nature of this risk, information on how animals respond to tidal turbines is urgently required. 2. We measured the behaviour of harbour seals in response to acoustic playbacks of simulated tidal turbine sound within a narrow coastal channel subject to strong, tidally induced currents. This was carried out using data from animal-borne GPS tags and shore-based observations, which were analysed to quantify behavioural responses to the turbine sound. 3. Results showed that the playback state (silent control or turbine signal) was not a significant predictor of the overall number of seals sighted within the channel. 4. However, there was a localised impact of the turbine signal; tagged harbour seals exhibited significant spatial avoidance of the sound which resulted in a reduction in the usage by seals of between 11 and 41% at the playback location. The significant decline in usage extended to 500 m from the playback location at which usage decreased by between 1 and 9% during playback. 5. Synthesis and applications: This study provides important information for policy makers looking to assess the potential impacts of tidal turbines and advise on development of the tidal energy industry. Results showing that seals avoid tidal turbine sound suggest that a proportion of seals encountering tidal turbines will exhibit behavioural responses resulting in avoidance of physical injury; in practice, the empirical changes in usage can be used directly as avoidance rates when using collision risk models to predict the effects of tidal turbines on seals. There is now a clear need to measure how marine mammals behave in response to actual operating tidal turbines in the long term to learn whether marine mammals and tidal turbines can co-exist safely at the scales currently envisaged for the industry. JApEcol_Hastie_etal_observation_data_DryadLand based observer data (.xlsx) used in the analysis of seal responses to tidal turbine sounds. This is effectively counts of seals observed in the water during acoustic playbacks of tidal turbine sound and silent controls. Data were collected by a series of observers located on a clifftop overlooking the study area (Kyle Rhea, Isle of Skye, Scotland) README file is provided as a tab in the file.JApEcol_Hastie_etal_seal_telemetry_data_DryadHarbour seal telemetry data (.xlsx) used in the analysis of changes in usage with distance from the location of playbacks of tidal turbine sound. The data are regularised lat-lon locations from 10 individual harbour seals tagged with GPS telemetry devices. README is provided as a tab in the file.STIMweighted_J11_1hour_withRampSound file (.wav) used during playbacks of simulated tidal turbine sound to harbour seals to investigate avoidance responses. The file has a 10 second ramp at the start and end of the file, and is frequency weighted for use with a J11 underwater speaker.

Further understanding of the biological role of the Ca2+ ion in an aqueous environment requires quantitative measurements of both the short- and long-range interactions experienced by the ion in an aqueous medium. Here, we present experimental measurements of binding energies for water molecules occupying the second and, quite possibly, the third solvation shell surrounding a central Ca2+ ion in [Ca(H2O)n]2+ complexes. Results for these large, previously inaccessible, complexes have come from the application of finite heat bath theory to kinetic energy measurements following unimolecular decay. Even at n = 20, the results show water molecules to be more strongly bound to Ca2+ than would be expected just from the presence of an extended network of hydrogen bonds. For n > 10, there is very good agreement between the experimental binding energies and recently published density functional theory calculations. Comparisons are made with similar data recorded for [Ca(NH3)n]2+ and [Ca(CH3OH)n]2+ complexes. CalciumWaterDetails of the individual experimental measurements made in order to extract binding energy results.

Triploidy could prevent escaped farm salmon breeding in the wild, while also improving nutrient quality within farmed fillets. Despite these potential advantages, triploid Atlantic salmon have not been widely used in aquaculture, and their reproductive function has yet to be fully evaluated. Here, we compare reproductive function and fillet composition between triploid and diploid farm salmon under standard aquaculture rearing conditions. We show that female triploids are sterile and do not develop gonads. In contrast, males produce large numbers of motile spermatozoa capable of fertilising wild salmon eggs. However, compared with diploids, reproductive development and survival rates of eggs fertilised by triploid males were significantly reduced, with less than 1% of eggs sired by triploid males reaching late eyed stages of development. Analyses of fillets showed that total lipid and fatty acid quantities were significantly lower in triploid compared to diploid Atlantic salmon fillets. However, when fatty acids were normalized to total lipid content, triploid fillets had significantly higher relative levels of important omega-3 Long Chain Polyunsaturated Fatty Acids. Our results show that: (1) escaped triploid farm salmon are very unlikely to reproduce in the wild; and (2) if able to match diploid fillet lipid content, triploid farm salmon could achieve better fillet quality in terms of essential fatty acids. Comparisons between diploid and triploid Atlantic salmonExcel file containing all the data collected during the investigation into the reproductive maturation of triploid Atlantic salmon, their fatty acid biochemistry and how they compare to diploid conspecifics

Environmental dataBioclimatic data and environmental data for all 56 European peatland site (geo referenced by longitude [long], latitude [lat] and altitude [ALT]. MAT = Mean annual temperature (°C), TS = Seasonality in temperature, MAP = Mean annual precipitation (mm), PS = Seasonality in precipitation, tot_sox = Total sulphur deposition SOx (mg m-2 yr-1), tot_noy = Total oxidized nitrogen deposition (mg m-2 yr-1), tot_nhx = Total reduced nitrogen deposition (mg m-2), PT warm = Lang’s moisture index. The four bioclimatic variables (MAT, TS, MAP, PS) were extracted from the WorldClim database (Hijmans, R. J., Cameron, S. E., Parra, J. L., Jones, P. G. & Jarvis, A. Very high resolution interpolated climate surfaces for global land areas. Int. J. Climatol. 25, 1965–1978 (2005)), and averaged over the 2000-2009 period. Atmospheric deposition data were produced using the EMEP (European Monitoring and Evaluation Programme)-based IDEM (Integrated Deposition Model) model (Pieterse, G., Bleeker, A., Vermeulen, A. T., Wu, Y. & Erisman, J. W. High resolution modelling of atmosphere‐canopy exchange of acidifying and eutrophying components and carbon dioxide for European forests. Tellus B 59, 412–424 (2007)) and consisted of grid cell averages of total reduced (NHx) and oxidised (NOy) nitrogen and sulphur (SOx) deposition. The moisture index (PTwarm) was calculated as the ratio between mean precipitation and mean temperature in the warmest quarter (Thornwaite, C. W. & Holzman, B. Measurement of evaporation from land and water surfaces. USDA Technical Bulletin 817, 1–143 (1942))Data 1_environmental data.txtplant community dataAbundance data (% cover) for all vascular plant and bryophyte species from five randomly chosen hummocks and lawns (0.25 m2 quadrats; ten in total) across 56 European Sphagnum-dominated peatlands were collected in two consecutive summers (2010 and 2011). Vascular plants and Sphagnum mosses were identified to the species level. Non-Sphagnum bryophytes were identified to the family level. Lichens were recorded as one group.Data 2_plant community data.txttraits vascular plantsPlant functional traits used to calculate functional indices for the vascular plant communities. Traits were extracted from LEDA (Kleyer, M. et al. The LEDA Traitbase: a database of life‐history traits of the Northwest European flora. J. Ecol. 96, 1266–1274 (2008)). Only trait data available for all species our data-set were extracted.ncomms_Data 3_traits vascular plants.txttraits SphagnumTrait values (means) for Sphagnum spp. C = tissue carbon content (mg g-1), N = tissue nitrogen content (mg g-1), P = tissue phosphorus content (mg g-1), Productivity ( St.w = stem width (mm), l.h.c. = length hyaline cells (µm), w.h.c. = width hyaline cells (µm), l.s.l. = length stem leaves (mm), w.s.l. = width stem leaves. These measured traits were complemented with traits extracted from the literature. These latter traits included plant length (Hill, M. O., Preston, C. D., Bosanquet, S. & Roy, D. B. BRYOATT: attributes of British and Irish mosses, liverworts and hornworts. Centre for Ecology & Hydrology, Huntingdon, UK (2007)), spore diameter and capsule diameter (Sundberg, S., Hansson, J. & Rydin, H. Colonization of Sphagnum on land uplift islands in the Baltic Sea: time, area, distance and life history. Journal of Biogeography 33, 1479–1491 (2006)), productivity (Gunnarsson, U. Global patterns of Sphagnum productivity. J. Bryol. 27, 269–279 (2005))ncomms_Data 4_traits Sphagnum.txt In peatland ecosystems, plant communities mediate a globally significant carbon store. The effects of global environmental change on plant assemblages are expected to be a factor in determining how ecosystem functions such as carbon uptake will respond. Using vegetation data from 56 Sphagnum-dominated peat bogs across Europe, we show that in these ecosystems plant species aggregate into two major clusters that are each defined by shared response to environmental conditions. Across environmental gradients, we find significant taxonomic turnover in both clusters. However, functional identity and functional redundancy of the community as a whole remain unchanged. This strongly suggests that in peat bogs, species turnover across environmental gradients is restricted to functionally similar species. Our results demonstrate that plant taxonomic and functional turnover are decoupled, which may allow these peat bogs to maintain ecosystem functioning when subject to future environmental change.