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This paper aims at reviewing the life cycle assessment (LCA) literature on second generation bioethanol based on lignocellulosic biomass and at identifying issues to be resolved for good LCA practice. Reviews are carried out on respective LCA studies published over the last six years. We use the classification of lignocellulosic biomass to define system boundaries, so that the comparison among LCA results can be thoroughly assessed based on identified system components. A basis for attributing environmental burden for different biomass feedstocks is also suggested. Despite the non-homogeneous systems, we conclude that second generation bioethanol performs better than fossil fuel at least for the two most studied impact categories, net energy output and global warming. For the latter category, carbon sequestration at the biomass generation stage can even consistently offset the GHG emissions from all parts of the life cycle chains at high ethanol percentage (≥85%). The aspect of biogenic carbon and agrochemical input for energy crops and biomass residues, and the effect of removal of the latter from soil have not been treated consistently. In contrast, the exclusion of upstream chain of biomass waste feedstocks is observed in practice. The bioethanol conversion process is mostly based on simultaneous saccharification and co-fermentation, characterized by high yield and low energy input. In this regard, the LCA results tend to under estimate the real impacts of the current technology. The choice of allocation methods strongly influences the final results, particularly when economic value is used as a reference. Substitution of avoided burden seems to be the most popular allocation method in practice, followed by partition based on mass, energy, and economic values.

In this communication, pretreatment of the anaerobically digested (AD) manure and the application of the pretreated AD manure as liquid medium for the simultaneous saccharification and fermentation (SSF) were described. Furthermore, fermentation of pretreated maize silage and wheat straw was investigated using 2l bioreactors. Wet oxidation performed for 20 min at 121 degrees C was found as the most suitable pretreatment conditions for AD manure. High ammonia concentration and significant amount of macro- and micro-nutrients in the AD manure had a positive influence on the ethanol fermentation. No extra nitrogen source was needed in the fermentation broth. It was shown that the AD manure could successfully substitute process water in SSF of pretreated lignocellulosic fibres. Theoretical ethanol yields of 82% were achieved, giving 30.8 kg ethanol per 100 kg dry mass of maize silage.

Over half of the world's forests are disturbed, and the rate at which ecosystem processes recover after disturbance is important for the services these forests can provide. We analyze the drivers' underlying changes in rates of key ecosystem processes (biomass productivity, litter productivity, actual litter decomposition, and potential litter decomposition) during secondary succession after shifting cultivation in wet tropical forest of Mexico.We test the importance of three alternative drivers of ecosystem processes: vegetation biomass (vegetation quantity hypothesis), community‐weighted trait mean (mass ratio hypothesis), and functional diversity (niche complementarity hypothesis) using structural equation modeling. This allows us to infer the relative importance of different mechanisms underlying ecosystem process recovery.Ecosystem process rates changed during succession, and the strongest driver was aboveground biomass for each of the processes. Productivity of aboveground stem biomass and leaf litter as well as actual litter decomposition increased with initial standing vegetation biomass, whereas potential litter decomposition decreased with standing biomass. Additionally, biomass productivity was positively affected by community‐weighted mean of specific leaf area, and potential decomposition was positively affected by functional divergence, and negatively by community‐weighted mean of leaf dry matter content.Our empirical results show that functional diversity and community‐weighted means are of secondary importance for explaining changes in ecosystem process rates during tropical forest succession. Instead, simply, the amount of vegetation in a site is the major driver of changes, perhaps because there is a steep biomass buildup during succession that overrides more subtle effects of community functional properties on ecosystem processes. We recommend future studies in the field of biodiversity and ecosystem functioning to separate the effects of vegetation quality (community‐weighted mean trait values and functional diversity) from those of vegetation quantity (biomass) on ecosystem processes and services.

In wetlands, a distinct zonation of plant species composition occurs along moisture gradients, due to differential flooding tolerance of the species involved. However, "flooding" comprises two important, distinct stressors (soil oxygen demand [SOD] and partial submergence) that affect plant survival and growth. To investigate how these two flooding stressors affect plant performance, we executed a factorial experiment (water depth x SOD) for six plant species of nutrient-rich and nutrient-poor conditions, occurring along a moisture gradient in Dutch dune slacks. Physiological, growth, and biomass responses to changed oxygen availability were quantified for all species. The responses were consistent with field zonation, but the two stressors affected species differently. Increased SOD increased root oxygen deprivation, as indicated by either raised porosity or increased alcohol dehydrogenase (ADH) activity in roots of flood-intolerant species (Calamagrostis epigejos and Carex arenaria). While SOD affected root functioning, partial submergence tended more to reduce photosynthesis (as shown both by gas exchange and 13C assimilation), leaf dark respiration, 13C partitioning from shoots to roots, and growth of these species. These processes were especially affected if the root oxygen supply was depleted by a combination of flooding and increased SOD. In contrast, the most flood-tolerant species (Juncus subnodulosus and Typha latifolia) were unaffected by any treatment and maintained high internal oxygen concentrations at the shoot : root junction and low root ADH activity in all treatments. For these species, the internal oxygen transport capacity was well in excess of what was needed to maintain aerobic metabolism across all treatments, although there was some evidence for effects of SOD on their nitrogen partitioning (as indicated by 865N values) and photosynthesis. Two species intermediate in flooding tolerance (Carex nigra and Schoenus nigricans) responded more idiosyncratically, with different parameters responding to different treatments. These results show that partial submergence and soil flooding are two very different stressors to which species respond in different ways, and that their effects on physiology, survival, and growth are interactive. Understanding species zonation with water regimes can be improved by a better appreciation of how these factors affect plant metabolism independently and interactively.

Using 40-year experiment data from a mono-modal rainfall area of northern Togo, we analyzed soil fertility dynamics when 2 and 3-year fallows were alternated with 3-year rotation of groundnut, cotton and sorghum. The control treatment consisted to continuous cultivate the soil in a rotation of groundnut/cotton/sorghum without fallow periods. For each rotation, two fertilisation rates were applied: no fertilisation and mineral fertiliser application during the cropping and/or the fallow periods. Yields of unfertilised crops, which averaged 1 t ha-1 during the first years of cultivation, were often nil in the long-term. In the long-term, yields of fertilised cotton and sorghum decreased by 32 and 50 %, respectively compared to the average of 2.4 and 1.6 t ha-1 obtained during the first decade of cultivation. The long-term decline in crop productivity was mitigated when fallow periods were alternated with cropping periods, and consequently there was partial compensation in terms of production for the unproductive fallowed plots. Long-term yields of fertilised cotton and sorghum in the periodically fallowed plots were 40 and 50 % higher than those in continuously cropped plots, respectively; they were 90 and 60 % higher than those in continuously cropped plots without fertilisation. Like for crop productivity, soil C, N and exchangeable Ca and Mg decreased less in periodically fallowed plots than in continuously cropped plots. The limited soil C decline when fallows were alternated with crops appears to be the consequence of no-tillage period rather than the effect of the highest C inputs to the soil.

The aim of this report is to demonstrate and evaluate the potential of tall wheatgrass (Elytrigia elongata) to avoid GHG emissions and obtain lower economic costs in marginal areas of Spain. Our research built scenarios based on experimental plots (2 and 3 years growth) in 3 locations of Spain with completely different climate conditions (provinces of Girona, Soria and Palencia). In our experiences, we achieved an adequate establishment and biomass production, and assumed a rank of biomass yields until the end of the life cycle that is usually accepted to be about 15 years in many other studies in United States, Argentina and Eastern Europe where tall wheatgrass is extensively cultivated in marginal areas for sheep livestock production. Using our experimental plots and statistical information for economic inputs costs, we built 5 different scenarios per region considering a large range of biomass yields of tall wheatgrass. The analysis included a comparison with annual grasses economic costs calculated for a wide range of biomass yields of a previous study. We estimated GHG emissions savings for tall wheatgrasses and used our previous study (which had GHG emissions savings as well). Savings were calculated replacing natural gas electricity with electricity from biomass combustion in real power plants in Spain. In a wide range of yields, the results suggest that marginal areas might present a better performance with tall wheatgrass compared to annual winter grasses (cereals whole plant cuttings), thus producing biomass yields with higher GHG savings and lower economic costs at the farm level. Proceedings of the 20th European Biomass Conference and Exhibition, 18-22 June 2012, Milan, Italy, pp. 217-229

How quickly large biomass particles can ignite and burn out when transported into a pulverized-fuel (pf) furnace and suddenly exposed to a hot gas flow containing oxygen is very important in biomass cofiring design and optimization. In this paper, the ignition and burnout of the largest possible biomass (pine wood) particles in a pf furnace (a few millimeters in diameter) are studied experimentally in a single particle combustion reactor rig, in which the ambient gas temperature and oxygen concentration can vary in the ranges 1473–1873 K and 5–20%, respectively. A one dimensional (1D) transient model is also developed to predict their conversion, in which the key processes inside the particle and in the boundary layer outside the particle are properly considered. For the pine wood particles in which large temperature gradients exist, the primary heterogeneous ignition is always detected for all the test conditions. As the particle is further heated and the volume-weighted average temperature reaches the o...

The harvested biomass of switchgrass (Panicum virgatum L.) is generally much lower than its potential; this may be due to several factors including not recovering all the biomass at harvest, weed competition, pests, disease and spatial variation of soil features. The objective of this research was to quantify the yield spatial variation of switchgrass and relate it to soil parameters, in a field of about 5 ha, in 2004 and 2005. Several thematic maps of soil parameters and biomass yield were produced using GIS and geostatistical methods. Soil parameters changed consistently within very short distances and biomass yield varied from 3 to more than 20 Mg ha-1. This remarkable variation indicates that the potential for increasing switchgrass productivity is a real prospect. Furthermore, spatial variation of yield showed similar patterns in the 2 years (r = 0.38**), and therefore a major influence of site characteristics on switchgrass yield can be assumed to occur. Significant correlations were found between biomass yield and soil N, P, moisture and pH as well as between soil parameters. Some soil parameters such as sand content showed patchy spatial distribution. Conversely, a reliable spatial dependence could not be identified for other parameters such as P. Further research is needed.