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Fire hazard during ship transportation of certain modern solid fuels is identified. A particular mechanism which may lead to catastrophic ship fire is discussed. A mathematical model predicting time to such fully developed fire (flashover time) I s proposed. An analytical solution is obtained for the developed model. An important part of this solution is a closed form analytical description of the smoke filling dynamics in a closed compartment. It is demonstrated that flashover time depends on a number of parameters. The relative importance of these parameters is discussed. Particular significance is attributed to fuel soot propensity (fuel soot yield) which is an intrinsic fuel property. This parameter controls the intensity of radiative heat exchange in the compartment, and its influence on flashover time is of paramount importance. It is suggested that fuels are ranked with respect to this parameter in order to describe their relative fire hazards. This ranking should be implemented into the regulatory framework governing fuel transportation by ships.

Fire hazard during ship transportation of certain modern solid fuels is identified. A particular mechanism which may lead to catastrophic ship fire is discussed. A mathematical model predicting time to such fully developed fire (flashover time) I s proposed. An analytical solution is obtained for the developed model. An important part of this solution is a closed form analytical description of the smoke filling dynamics in a closed compartment. It is demonstrated that flashover time depends on a number of parameters. The relative importance of these parameters is discussed. Particular significance is attributed to fuel soot propensity (fuel soot yield) which is an intrinsic fuel property. This parameter controls the intensity of radiative heat exchange in the compartment, and its influence on flashover time is of paramount importance. It is suggested that fuels are ranked with respect to this parameter in order to describe their relative fire hazards. This ranking should be implemented into the regulatory framework governing fuel transportation by ships.

DC to AC inverters are the well-known and improved in various kinds photovoltaic (PV) and gird tied systems. However, these inverters are require interfacing transformers to be synchronized with the grid-connected system. Therefore, the system is bulky and not economy. The transformerless inverter (TLI) topologies and its grid interface techniques are increasingly engrossed for the benefit of high efficiency, reliability, and low cost. The main concern in the TL inverters is common mode voltage (CMV), which causes the switching-frequency leakage current, grid interface concerns and exaggerates the EMI problems. The single-phase inverter two-level topologies are well developed with additional switches and components for eliminating the CMV. Multilevel inverters (MLIs) based grid connected transformerless inverter topology is being researched to avail additional benefits from MLI, even through that are trust topologies presented in the literature. With the above aim, this paper has proposed three -phase three-level T type NP-MLI (TNP-MLI) topology with transformerless PV grid connected proficiency. The CM leakage current should handle over mitigating CMV through removing unwanted switching events in the inverter pulse width modulation (PWM). This paper is proposes PV connected T type NP-MLI interface with three-phase grid connected system with the help of improved space vector modulation (SVM) technique to mitigate the CM leakage current to overcome the above said requests on the PV tied TL grid connected system. This proposed the SVM technique to mitigate the CM leakage current by selecting only mediums, and zero vectors with suitable current control method in order to maintain the inverter current and grid interface requirements. The proposed PV tied TNP-MLI offering higher efficiency, lower breakdown voltage on the devices, smaller THD of output voltage, good reliability, and long life span. The paper also investigated the CM leakage currents envisage and behavior for the three-phase MLI through the inverter switching function, which is not discussed before. The proposed SVM on TL-TNP-MLI offers the reliable PV grid interface with very low switching-frequency leakage current (200mA) for all the PV and inverter operation conditions. The feasibility and effectiveness of the TLI and its control strategy is confirmed through the MATLAB/Simulink simulation model directly as compared with 2kW roof top PV plant connected TL-TNP-MLI experimentation, showing good accordance with theoretical investigation. The simulation and experimental results are demonstrated and presented in the good stability of steady state and dynamics performances. The proposed inverter reduces the cost of grid interface transformer, harmonics filter, and CMV suppressions choke.

DC to AC inverters are the well-known and improved in various kinds photovoltaic (PV) and gird tied systems. However, these inverters are require interfacing transformers to be synchronized with the grid-connected system. Therefore, the system is bulky and not economy. The transformerless inverter (TLI) topologies and its grid interface techniques are increasingly engrossed for the benefit of high efficiency, reliability, and low cost. The main concern in the TL inverters is common mode voltage (CMV), which causes the switching-frequency leakage current, grid interface concerns and exaggerates the EMI problems. The single-phase inverter two-level topologies are well developed with additional switches and components for eliminating the CMV. Multilevel inverters (MLIs) based grid connected transformerless inverter topology is being researched to avail additional benefits from MLI, even through that are trust topologies presented in the literature. With the above aim, this paper has proposed three -phase three-level T type NP-MLI (TNP-MLI) topology with transformerless PV grid connected proficiency. The CM leakage current should handle over mitigating CMV through removing unwanted switching events in the inverter pulse width modulation (PWM). This paper is proposes PV connected T type NP-MLI interface with three-phase grid connected system with the help of improved space vector modulation (SVM) technique to mitigate the CM leakage current to overcome the above said requests on the PV tied TL grid connected system. This proposed the SVM technique to mitigate the CM leakage current by selecting only mediums, and zero vectors with suitable current control method in order to maintain the inverter current and grid interface requirements. The proposed PV tied TNP-MLI offering higher efficiency, lower breakdown voltage on the devices, smaller THD of output voltage, good reliability, and long life span. The paper also investigated the CM leakage currents envisage and behavior for the three-phase MLI through the inverter switching function, which is not discussed before. The proposed SVM on TL-TNP-MLI offers the reliable PV grid interface with very low switching-frequency leakage current (200mA) for all the PV and inverter operation conditions. The feasibility and effectiveness of the TLI and its control strategy is confirmed through the MATLAB/Simulink simulation model directly as compared with 2kW roof top PV plant connected TL-TNP-MLI experimentation, showing good accordance with theoretical investigation. The simulation and experimental results are demonstrated and presented in the good stability of steady state and dynamics performances. The proposed inverter reduces the cost of grid interface transformer, harmonics filter, and CMV suppressions choke.

Microbial fuel cells (MFCs) are biochemical systems having the benefit of producing green energy through the microbial degradation of organic contaminants in wastewater. The efficiency of MFCs largely depends on the cathode oxygen reduction reaction (ORR). A preferable ORR catalyst must have good oxygen reduction kinetics, high conductivity and durability, together with cost-effectiveness. Platinum-based electrodes are considered a state-of-the-art ORR catalyst. However, the scarcity and higher cost of Pt are the main challenges for the commercialization of MFCs; therefore, in search of alternative, cost-effective catalysts, those such as doped carbons and transition-metal-based electrocatalysts have been researched for more than a decade. Recently, perovskite-oxide-based nanocomposites have emerged as a potential ORR catalyst due to their versatile elemental composition, molecular mechanism and the scope of nanoengineering for further developments. In this article, we discuss various studies conducted and opportunities associated with perovskite-based catalysts for ORR in MFCs. Special focus is given to a basic understanding of the ORR reaction mechanism through oxygen vacancy, modification of its microstructure by introducing alkaline earth metals, electron transfer pathways and the synergistic effect of perovskite and carbon. At the end, we also propose various challenges and prospects to further improve the ORR activity of perovskite-based catalysts.

Microbial fuel cells (MFCs) are biochemical systems having the benefit of producing green energy through the microbial degradation of organic contaminants in wastewater. The efficiency of MFCs largely depends on the cathode oxygen reduction reaction (ORR). A preferable ORR catalyst must have good oxygen reduction kinetics, high conductivity and durability, together with cost-effectiveness. Platinum-based electrodes are considered a state-of-the-art ORR catalyst. However, the scarcity and higher cost of Pt are the main challenges for the commercialization of MFCs; therefore, in search of alternative, cost-effective catalysts, those such as doped carbons and transition-metal-based electrocatalysts have been researched for more than a decade. Recently, perovskite-oxide-based nanocomposites have emerged as a potential ORR catalyst due to their versatile elemental composition, molecular mechanism and the scope of nanoengineering for further developments. In this article, we discuss various studies conducted and opportunities associated with perovskite-based catalysts for ORR in MFCs. Special focus is given to a basic understanding of the ORR reaction mechanism through oxygen vacancy, modification of its microstructure by introducing alkaline earth metals, electron transfer pathways and the synergistic effect of perovskite and carbon. At the end, we also propose various challenges and prospects to further improve the ORR activity of perovskite-based catalysts.

A two-dimensional rectangular domain is considered with a discrete arrangement at equal distances from copper metal foam in a solar air heater (SAH). The local thermal non-equilibrium model is used for the analysis of heat transfer in a single-pass rectangular channel of SAH for different mass flow rates ranging from 0.03 to 0.05 kg/s at 850 W/m2 heat flux. Three different pores per inch (PPI) and porosities of copper metal foam with three different discrete thicknesses at equal distances are studied numerically. This paper evaluates the performance of SAH with 10 PPI 0.8769 porosity, 20 PPI 0.8567 porosity, and 30 PPI 0.92 porosity at 22 mm, 44 mm, and 88 mm thicknesses. The Nusselt number for 22 mm, 44 mm, and 88 mm thicknesses is 157.64%, 183.31%, and 218.60%, respectively, higher than the empty channel. The performance factor for 22 mm thick metal foam is 5.02% and 16.61% higher than for 44 mm and 88 mm thick metal foam, respectively. Hence, it is found that metal foam can be an excellent option for heat transfer enhancement in SAH, if it is designed properly.