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Abstract Ti-doped ZnO (ZnO/Ti) thin films were grown on indium tin oxide substrates by a facile electrodeposition route. The morphology, crystal structure and resistive switching properties were examined, respectively. The morphology reveals that grains are composed of small crystals. The (002) preferential growth along c-axis of ZnO/Ti could be observed from structural analysis. The XPS study shows the presence of oxygen vacancies in the prepared films. Typical bipolar and reversible resistance switching effects were observed. High R OFF/R ON ratios (approximately 14) and low operation voltages within 100 switching cycles are obtained. The filament theory and the interface effect are suggested to be responsible for the resistive switching phenomenon.

Abstract Global hydropower growth continues to accelerate with 25% of total capacity installed in just the last 10 years. This accelerating expansion and the important storage facility hydropower means it is increasingly important to understand the reasons for operational failures. This is a challenge because the major reason for failures involves the complex interaction of hydraulic, mechanical and electric subsystems. Historically, reliability modelling has been split in two directions, focusing on different sub-systems, and has not yet been unified. Here these approaches are unified with a novel expression of unbalanced forces. This model with operational data are validated and the important modes of oscillation in the shaft are identified. Finally, the mechanism of the first-order oscillation mode exciting a second-order mode is presented. This integrated and accurate mathematical model is a major advance in the diagnosis and prediction of failures in hydropower operation.

Abstract The phase change of sodium acetate (SA) aqueous solution to sodium acetate trihydrate (SAT) requires large supercooling degree, then the aqueous solution can be at liquid state at fairly low temperature without releasing the stored latent heat. Such a feature makes SAT a promising material for seasonal solar thermal energy storage. The present study firstly summarized the thermo-physical properties of the solid SAT and liquid SA aqueous solution at different temperatures and concentrations, including equilibrium temperatures, densities, specific heats and thermal conductivities. The calculation methods of these properties have been established. Secondly, with the aid of the above properties, a mathematic model of the thermal discharge process of the storage system, i.e. the solidification process of supercooled SA aqueous solution, was built based on the heat transfer between the phase changing material within a single storage tube and the external flowing heat transfer fluid (HTF). The experimentally obtained SAT crystal growth rate and the enthalpy change of solidifying supercooled SA aqueous solution were employed to aid the modelling. The discharge temperature and thermal power of the storage system were numerically obtained and analysed. The influence of the ambient temperature, the mass flow rate as well as the heat transfer coefficient of the HTF on the thermal discharge performance were discussed. Finally, the seasonal thermal storage density of SAT was given and compared to that of water and some sorption materials.

Recent changes to the electric power industry through deregulation and restructuring have had a considerable effect on power engineering education internationally. A number of Australian universities have also noticed a decline in the number of students interested in power engineering subjects, leading to the fewer graduates with power engineering knowledge. With a reduction in graduates and a perception of an ageing workforce a shortage of suitably qualified power engineers for industry may be imminent. This paper provides discussion on the current status of university power engineering education within Australia and includes results from a recent Australia-wide survey of the university and industry sectors of electric power engineering.

AbstractHigh‐performance dye‐sensitized solar cell (DSSC) devices rely on photoanodes that possess excellent light‐harvesting capabilities and high surface areas for sufficient dye adsorption. In this work, morphologically controlled SnO2 microstructures were synthesized and used as an efficient light‐backscattering layer on top of a nanocrystalline TiO2 layer to prepare a double‐layered photoanode. By optimizing the thickness of both the TiO2 bottom layer and the SnO2 top layer, a high power conversion efficiency (PCE) of 7.8 % was achieved, an enhancement of approximately 38 % in the efficiency compared with that of a nanocrystalline TiO2‐only photoanode (5.6 %). We attribute this efficiency improvement to the superior light‐backscattering capability of the SnO2 microstructures.

The many advantages of slug flow pneumatic conveying are outweighed by the lack of understanding of the flow mechanisms. For horizontal slug flow, the unique feature is the stationary layer of material found between the travelling slugs, which was recently shown to be characterised by two constants. This paper looks to utilise the vast data available in the literature, which is representative of the entire mode of flow, and relates the stationary layer and slug velocity to predict the two constants from only these inputs. It was found that, even for the vast range of materials and systems considered, slug flow encompasses a narrow bound of the two constants. Furthermore, an empirical approach that was developed to relate the layer fraction and particle velocity was found to provide good agreement to measurements and may be of use in other investigations that require an additional equation for modelling.

Sustainability has emerged, arguably, as the premiere mission of contemporary architecture. Green assessment tools abound, consultancy services flourish, buildings are marketed on the basis of sustainability performance, and government, media, and corporations seem preoccupied with assessing the quality of the built environment through a green lens. Yet for all the effort, and indeed for all the progress made, fundamental issues resistant to the structural change that is essential for genuine sustainability remain. This paper reviews the state of play of sustainability across the urban landscape. It considers the road travelled so far, and points out some of the major challenges that lie ahead.

Abstract In an effort to minimise electricity consumption and greenhouse gases emissions, the heating, ventilation and air-conditioning sector has focused its attention on developing alternative solutions to electrically-driven vapour-compression cooling. Liquid desiccant air-conditioning systems represent an energy-efficient and more environmentally friendly alternative technology for dehumidification and cooling, particularly in those cases with high latent loads to maintain indoor air quality and comfort conditions. This technology is considered particularly efficient in hot and humid climates. As a matter of fact, the choice of the desiccant solution influences the overall performance of the system. The current paper reviews the working principle of liquid desiccant systems, focusing on the thermodynamic properties of the desiccant solutions and describes an evaluation of the reference thermodynamic properties of different desiccant solutions to identify which thermodynamic, physical, transport property influences the liquid desiccant process and to what extent. The comparison of these thermodynamic properties for the commonly used desiccants is conducted to estimate which fluid could perform most favourably in the system. The economic factors and the effect of different applications and climatic conditions on the system performance are also described. The paper is intended to be the first step in the evaluation of alternative desiccant fluids able to overcome the problems related to the use of the common desiccant solutions, such as crystallization and corrosion to metals. Ionic liquids seem a promising alternative working fluid in liquid desiccant air-conditioning systems and their characteristics and cost are discussed.