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This study searches the impact of tourism growth on emission pollutants in Cyprus (north), which is a small island in the Mediterranean and has shown significant development in hotel and casino sectors in the last two decades. Results from time-series analyses reveal that an inverted U-shaped EKC hypothesis is confirmed for Cyprus with and without tourism development. Tourism also exerts positively significant and long-term effects on the levels of carbon emissions, revealing that growth in the tourism sector causes degradation in the environment.

Abstract Liquefaction of poly-isoprene based rubber (PIR) was performed using ethanol as a solvent for the production of liquid fuel and chemicals. An autoclave batch reactor was used to perform the ethanolysis of PIR at different temperature ranges (250–375 °C), with different ethanol to PIR ratio (0.5:1 to 4:1), and at different reaction times (15–75mins). The experimental results showed that a maximum yield of 86 wt % was achieved at temperature of 325 °C, ethanol to PIR ratio 1/1, and reaction time of 30 min. This liquid oil yield is about 14% higher than the yield obtained from the pyrolysis of PIR at 500 °C and about 10% higher than the yield obtained from hydrothermal liquefaction of PIR at 375 °C. Moreover, the utilization of ethanol in the process was also incorporated and product yields were redefined. Furthermore, ethanol contributed to enhance the quality of liquid-oil, particularly in term of viscosity, acidity, and energy density. Furthermore, the FTIR analysis showed methyl and methylene were most dominating functional groups found in the liquid product and GCMS analysis identified that they were presented by alkenes, aromatics, and alkyls.

Abstract. Wake steering is a technique that optimizes the energy production of a wind farm by employing yaw control to misalign upstream turbines with the incoming wind direction. This work highlights the important dependence between wind direction variations and wake steering optimization. The problem is formalized over time as the succession of multiple steady-state yaw control problems interconnected by the rotational constraints of the turbines and the evolution of the wind. Then, this work proposes a reformulation of the yaw optimization problem of each time step by augmenting the objective function by a new heuristic based on a wind prediction. The heuristic acts as a penalization for the optimization, encouraging solutions that will guarantee future energy production. Finally, a synthetic sensitivity analysis of the wind direction variations and wake steering optimization is conducted. Because of the rotational constraints of the turbines, as the magnitude of the wind direction fluctuations increases, the importance of considering wind prediction in a steady-state optimization is empirically demonstrated. The heuristic proposed in this work greatly improves the performance of controllers and significantly reduces the complexity of the original sequential decision problem by decreasing the number of decision variables.

The development of a concrete mixture design process for high-quality concrete production with sustainable values is a complex process because of the multiple required properties at the green/hardened state of concrete and the interdependency of concrete mixture parameters. A new multicriteria decision making (MCDM) technique based on Technique of Order Preference Similarity to the Ideal Solution (TOPSIS) methodology is applied to a fuzzy setting for the selection of concrete mix factors and concrete mixture design methods with the aim towards sustainable concrete quality management. Three objective properties for sustainable quality concrete are adopted as criteria in the proposed MCDM model. The seven most dominant concrete mixture parameters with consideration to sustainable concrete quality issues, i.e., environmental (density, durability) and socioeconomic criteria (cost, optimum mixture ingredients ratios), are proposed as sub-criteria. Three mixture design techniques that have potentiality to include sustainable aspects in their design procedure, two advanced and one conventional concrete mixture design method, are taken as alternatives in the MCDM model. The proposed selection support framework may be utilized in updating concrete design methods for sustainability and in deciding the most dominant concrete mix factors that can provide sustainable quality management in concrete production as well as in concrete construction. The concrete mix factors found to be most influential to produce sustainable concrete quality include the water/cement ratio and density. The outcomes of the proposed MCDM model of fuzzy TOPSIS are consistent with the published literature and theory. The DOE method was found to be more suitable in sustainable concrete quality management considering its applicable objective quality properties and concrete mix factors.

In this paper, stochastic scheduling of a hybrid system (HS) composed of a photovoltaic (PV) array and wind turbines incorporated with a battery storage (HPV/WT/Batt) system in the distribution network was proposed to minimize energy losses, the voltage profile, and the HS cost, and to improve reliability in shape of the energy-not-supplied (ENS) index, considering energy-source generation and network demand uncertainties through the unscented transformation (UT). An improved escaping-bird search algorithm (IEBSA), based on the escape operator from the local optimal, was employed to identify the optimal location of the HS in the network in addition to the optimal quantity of PV panels, wind turbines, and batteries. The deterministic results for three configurations of HPV/WT/Batt, PV/Batt, and WT/Batt were presented, and the results indicate that the HPV/WT/Batt system is the optimal configuration with lower energy losses, voltage deviation, energy not supplied, and a lower HS energy cost than the other configurations. Deterministic scheduling according to the optimal configuration reduced energy losses, ENS, and voltage fluctuation by 33.09%, 53.56%, and 63.02%, respectively, compared to the base network. In addition, the results demonstrated that the integration of battery storage into the HPV/WT enhanced the various objectives. In addition, the superiority of IEBSA over several well-known algorithms was proved in terms of obtaining a faster convergence, better objective value, and lower HS costs. In addition, the stochastic scheduling results based on the UT revealed that the uncertainties increase the power losses, voltage deviations, ENS, and HPV/WT/Batt cost by 2.23%, 5.03%, 2.20%, and 1.91%, respectively, when compared to the deterministic scheduling.

Room occupancy prediction based on indoor environmental quality may be the breakthrough to ensure energy efficiency and establish an interior ambience tailored to each user. Identifying whether temperature, humidity, lighting, and CO2 levels may be used as efficient predictors of room occupancy accuracy is needed to help designers better utilize the readings and data collected in order to improve interior design, in an effort to better suit users. It also aims to help in energy efficiency and saving in an ever-increasing energy crisis and dangerous levels of climate change. This paper evaluated the accuracy of room occupancy recognition using a dataset with diverse amounts of light, CO2, and humidity. As classification algorithms, K-nearest neighbors (KNN), hybrid Adam optimizer–artificial neural network–back-propagation network (AO–ANN (BP)), and decision trees (DT) were used. Furthermore, this research is based on machine learning interpretability methodologies. Shapley additive explanations (SHAP) improve interpretability by estimating the significance values for each feature for classifiers applied. The results indicate that the KNN performs better than the DT and AO-ANN (BP) classification models have 99.5%. Though the two classifiers are designed to evaluate variations in interpretations, we must ensure that they have accurate detection. The results show that SHAP provides successful implementation following these metrics, with differences detected amongst classifier models that support the assumption that model complexity plays a significant role when predictability is taken into account.

The Flameless Combustion (FC) regime has been pointed out as a promising combustion technique to lower the emissions of nitrogen oxides (NOx) while maintaining low CO and soot emissions, as well as high efficiencies. However, its accurate modeling remains a challenge. The prediction of pollutant species, especially NOx, is affected by the usually low total values that require higher precision from computational tools, as well as the incorporation of relevant formation pathways within the overall reaction mechanism that are usually neglected. The present work explores a multiple step modeling approach to tackle these issues. Initially, a CFD solution with simplified chemistry is generated [both the Eddy Dissipation Model (EDM) as well as the Flamelet Generated Manifolds (FGM) approach are employed]. Subsequently, its computational cells are clustered to form ideal reactors by user-defined criteria, and the resulting Chemical Reactor Network (CRN) is subsequently solved with a detailed chemical reaction mechanism. The capabilities of the clustering and CRN solving computational tool (AGNES—Automatic Generation of Networks for Emission Simulation) are explored with a test case related to FC. The test case is non-premixed burner based on jet mixing and fueled with CH4 tested for various equivalence ratios. Results show that the prediction of CO emissions was improved significantly with respect to the CFD solution and are in good agreement with the experimental data. As for the NOx emissions, the CRN results were capable of reproducing the non-monotonic behavior with equivalence ratio, which the CFD simulations could not capture. However, the agreement between experimental values and those predicted by CRN for NOx is not fully satisfactory. The clustering criteria employed to generate the CRNs from the CFD solutions were shown to affect the results to a great extent, pointing to future opportunities in improving the multi-step procedure and its application.