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Hot water heat stores with stratification are a common technology used in solar energy systems and reuse of waste heat. Adding a PCM module at the top of the water tank would give the system higher storage density, and compensate heat loss in the top layer. The work presented here includes experimental results and numerical simulation of the system using an explicit finite-difference method. Experiments and simulations were carried out using different cylindrical PCM modules. With only 1/16 of the volume of the store being PCM, 3/16 of water at the top of the store was held warm for 50% to 200% longer and the average energy density was increased by 20% to 45%. Furthermore, these 3/16 of water were reheated by the heat from the module after being cooled down in only 20 min.

Abstract A heat pump coupled to thermal energy storage (TES) tanks is experimentally tested under simulated summer conditions and the results are presented in this paper. The cold TES tank is used for shifting the cooling load of a small house-like structure. The study evaluates the thermal behaviour of the TES tank for cold storage and the application of the system for space cooling. For the analysis, two different configurations of the tanks are compared: a water tank and a PCM tank. The PCM tank is filled with a commercial macro-encapsulated PCM, which has a phase change temperature of 10 °C. The results point out that the PCM tank is able to supply 14.5% more cold and to maintain the indoor temperature within comfort 20.65% longer than the water tank. However, it needs 4.55 times longer to charge the tank.

Feedbacks between land carbon pools and climate provide one of the largest sources of uncertainty in our predictions of global climate. Estimates of the sensitivity of the terrestrial carbon budget to climate anomalies in the tropics and the identification of the mechanisms responsible for feedback effects remain uncertain. The Amazon basin stores a vast amount of carbon, and has experienced increasingly higher temperatures and more frequent floods and droughts over the past two decades. Here we report seasonal and annual carbon balances across the Amazon basin, based on carbon dioxide and carbon monoxide measurements for the anomalously dry and wet years 2010 and 2011, respectively. We find that the Amazon basin lost 0.48 ± 0.18 petagrams of carbon per year (Pg C yr(-1)) during the dry year but was carbon neutral (0.06 ± 0.1 Pg C yr(-1)) during the wet year. Taking into account carbon losses from fire by using carbon monoxide measurements, we derived the basin net biome exchange (that is, the carbon flux between the non-burned forest and the atmosphere) revealing that during the dry year, vegetation was carbon neutral. During the wet year, vegetation was a net carbon sink of 0.25 ± 0.14 Pg C yr(-1), which is roughly consistent with the mean long-term intact-forest biomass sink of 0.39 ± 0.10 Pg C yr(-1) previously estimated from forest censuses. Observations from Amazonian forest plots suggest the suppression of photosynthesis during drought as the primary cause for the 2010 sink neutralization. Overall, our results suggest that moisture has an important role in determining the Amazonian carbon balance. If the recent trend of increasing precipitation extremes persists, the Amazon may become an increasing carbon source as a result of both emissions from fires and the suppression of net biome exchange by drought.

Aquaculture has become an important sector of animal food production thanks to a fast and continuous growth over the last few decades. Both marine and fresh water fish can be reared in fish farms, and there are species that are mainly produced by aquaculture rather than capture. As most of the reared fish species are sensible to water temperature and its fluctuations, having the control of this parameter in fish farms becomes an important issue that has to be taken into account. In this paper, three different fish farms are studied by simulating the water temperature when a thermal energy storage (TES) system using phase change materials (PCMs) is implemented. The effect and the estimated amounts of PCM required in each particular case are also analyzed. The results show that appreciable effects can be obtained, especially when the TES unit is used in combination with auxiliary sources of energy, such as solar collectors.

Disposal of FBC solid residues currently represents one of the major issues in FBC design and operation, and contributes significantly to FBC operating cost. This issue has triggered research activities on the enhancement of sorbent utilization for in-situ sulfur uptake. The present study addresses the effectiveness of the reactivation by liquid water hydration of FB spent sorbents. Two materials are considered in the study, namely bottom ash from the operation of a full-scale utility FB boiler and the raw commercial limestone used in the same boiler. Hydration-reactivation tests were carried out at temperatures of 40°C and 80°C and for curing times ranging from 15min to 2d, depending on the sample. The influence of hydration conditions on the enhancement of sulfur utilization has been assessed. A combination of methods has been used to characterize the properties of liquid water-hydrated materials.

Earth’s biodiversity and human societies face pollution, overconsumption of natural resources, urbanization, demographic shifts, social and economic inequalities, and habitat loss, many of which are exacerbated by climate change. Here, we review links among climate, biodiversity, and society and develop a roadmap toward sustainability. These include limiting warming to 1.5°C and effectively conserving and restoring functional ecosystems on 30 to 50% of land, freshwater, and ocean “scapes.” We envision a mosaic of interconnected protected and shared spaces, including intensively used spaces, to strengthen self-sustaining biodiversity, the capacity of people and nature to adapt to and mitigate climate change, and nature’s contributions to people. Fostering interlinked human, ecosystem, and planetary health for a livable future urgently requires bold implementation of transformative policy interventions through interconnected institutions, governance, and social systems from local to global levels.

Thermal energy storage (TES) using phase change materials (PCM) can be used for load shaving or peak load shifting when coupled to a heating, ventilation, and air-conditioning (HVAC) system such as heat pump. In these systems the PCM is embedded in packages or used in bulk, so the compatibility of the encapsulation materials and the PCM is a key factor to ensure long operational life of the system. Although corrosion caused by salts is known from the chemical industry, when these salts are used as PCM no corrosion data is available, since the salts are used without being in water solution. Producing new corrosion data is essential for PCM utilisation in new applications. In this study the corrosion rate of two metals and two metal alloys when they are in contact with different salt hydrate PCM is evaluated; in total eleven PCM, being four of them commercial PCM, are tested. Since they are PCM to be used for heating and cooling applications they are classified in two different groups to present the corrosion study. Results present the recommendation of using each PCM with the different metals and metal alloys according to the obtained corrosion rate and visual observation of the samples.

Abstract Open-air swimming pools in Mediterranean climate regions are heated by direct solar radiation with no auxiliary heating systems. In order to extend the swimming season or improve comfort conditions, solar collectors or pool coverings may be used. In this paper, another approach was followed through the use of phase change materials (PCM). Two methods of introducing the PCM were considered: (1) encapsulated in the sidewalls and bottom of the pool, and (2) use the PCM in an external heat exchanger. Heat is stored when water temperature is sufficiently high, while it is released when water temperature drops below comfort levels. A numerical model was built and validated for predicting the evolution of the water temperature, by taking into account meteorological data at three different locations in north-east of Spain. The simulations showed that using phase change materials provided some improvement of water conditions, especially when used in an external heat exchanger.