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    Authors: orcid Thomas Bolognesi;
    Thomas Bolognesi
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    Thomas Bolognesi in OpenAIRE
    Andrea K. Gerlak; orcid Gregory Giuliani;
    Gregory Giuliani
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    Gregory Giuliani in OpenAIRE

    The Social-Ecological Systems (SES) framework serves as a valuable framework to explore and understand social and ecological interactions, and pathways in water governance. Yet, it lacks a robust understanding of change. We argue an analytical and methodological approach to engaging global changes in SES is critical to strengthening the scope and relevance of the SES framework. Relying on SES and resilience thinking, we propose an institutional and cognitive model of change that institutions and natural resources systems co-evolve to provide a dynamic understanding of SES that stands on three causal mechanisms: institutional complexity trap, rigidity trap, and learning processes. We illustrate how Data Cube technology could overcome current limitations and offer reliable avenues to test hypothesis about the dynamics of social-ecological systems and water security by offering to combine spatial and time data with no major technical requirements for users.

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    https://doi.org/10.20944/prepr...
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    https://doi.org/10.20944/prepr...
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    Authors: orcid bw Ana Maria Roxana Petrescu;
    Ana Maria Roxana Petrescu
    ORCID
    Derived by OpenAIRE algorithms or harvested from 3rd party repositories

    Ana Maria Roxana Petrescu in OpenAIRE
    orcid Chunjing Qiu;
    Chunjing Qiu
    ORCID
    Harvested from ORCID Public Data File

    Chunjing Qiu in OpenAIRE
    Philippe Ciais; orcid Rona L. Thompson;
    Rona L. Thompson
    ORCID
    Harvested from ORCID Public Data File

    Rona L. Thompson in OpenAIRE
    +35 Authors

    Abstract. Reliable quantification of the sources and sinks of greenhouse gases, together with trends and uncertainties, is essential to monitoring the progress in mitigating anthropogenic emissions under the Paris Agreement. This study provides a consolidated synthesis of CH4 and N2O emissions with consistently derived state-of-the-art bottom-up (BU) and top-down (TD) data sources for the European Union and UK (EU27+UK). We integrate recent emission inventory data, ecosystem process-based model results, and inverse modelling estimates over the period 1990–2018. BU and TD products are compared with European National GHG Inventories (NGHGI) reported to the UN climate convention secretariat UNFCCC in 2019. For uncertainties, we used for NGHGI the standard deviation obtained by varying parameters of inventory calculations, reported by the Member States following the IPCC guidelines recommendations. For atmospheric inversion models (TD) or other inventory datasets (BU), we defined uncertainties from the spread between different model estimates or model specific uncertainties when reported. In comparing NGHGI with other approaches, a key source of bias is the activities included, e.g. anthropogenic versus anthropogenic plus natural fluxes. In inversions, the separation between anthropogenic and natural emissions is sensitive to the geospatial prior distribution of emissions. Over the 2011–2015 period, which is the common denominator of data availability between all sources, the anthropogenic BU approaches are directly comparable, reporting mean emissions of 20.8 Tg CH4 yr−1 (EDGAR v5.0) and 19.0 Tg CH4 yr−1 (GAINS), consistent with the NGHGI estimates of 18.9 ± 1.7 Tg CH4 yr−1. TD total inversions estimates give higher emission estimates, as they also include natural emissions. Over the same period regional TD inversions with higher resolution atmospheric transport models give a mean emission of 28.8 Tg CH4 yr−1. Coarser resolution global TD inversions are consistent with regional TD inversions, for global inversions with GOSAT satellite data (23.3 Tg CH4yr−1) and surface network (24.4 Tg CH4 yr−1). The magnitude of natural peatland emissions from the JSBACH-HIMMELI model, natural rivers and lakes emissions and geological sources together account for the gap between NGHGI and inversions and account for 5.2 Tg CH4 yr−1. For N2O emissions, over the 2011–2015 period, both BU approaches (EDGAR v5.0 and GAINS) give a mean value of anthropogenic emissions of 0.8 and 0.9 Tg N2O yr−1 respectively, agreeing with the NGHGI data (0.9 ± 0.6 Tg N2O yr−1). Over the same period, the average of the three total TD global and regional inversions was 1.3 ± 0.4 and 1.3 ± 0.1 Tg N2O yr−1 respectively, compared to 0.9 Tg N2O yr−1 from the BU data. The TU and BU comparison method defined in this study can be operationalized for future yearly updates for the calculation of CH4 and N2O budgets both at EU+UK scale and at national scale. The referenced datasets related to figures are visualized at https://doi.org/10.5281/zenodo.4288969 (Petrescu et al., 2020).

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    https://doi.org/10.5194/essd-2...
    Article . 2020 . Peer-reviewed
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    https://essd.copernicus.org/ar...
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    https://dx.doi.org/10.60692/r8...
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      https://doi.org/10.5194/essd-2...
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    Authors: orcid Risi, Guglielmo;
    Risi, Guglielmo
    ORCID
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    Risi, Guglielmo in OpenAIRE
    orcid Becker, Mariia;
    Becker, Mariia
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    Becker, Mariia in OpenAIRE
    orcid Housecroft, Catherine E.;
    Housecroft, Catherine E.
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    Housecroft, Catherine E. in OpenAIRE
    orcid Constable, Edwin C.;
    Constable, Edwin C.
    ORCID
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    Constable, Edwin C. in OpenAIRE

    The syntheses of 4,4′-bis(4-dimethylaminophenyl)-6,6′-dimethyl-2,2′-bipyridine (1), 4,4′-bis(4-dimethylaminophenylethynyl)-6,6′-dimethyl-2,2′-bipyridine (2), 4,4′-bis(4-diphenylaminophenyl)-6,6′-dimethyl-2,2′-bipyridine (3), and 4,4′-bis(4-diphenylaminophenylethynyl)-6,6′-dimethyl-2,2′-bipyridine (4) are reported along with the preparations and characterisations of their homoleptic copper(I) complexes [CuL2][PF6] (L = 1–4). The solution absorption spectra of the complexes exhibit ligand-centred absorptions in addition to absorptions in the visible region assigned to a combination of intra-ligand and metal-to-ligand charge-transfer. Heteroleptic [Cu(5)(Lancillary)]+ dyes in which 5 is the anchoring ligand ((6,6′-dimethyl-[2,2′-bipyridine]-4,4′-diyl)bis(4,1-phenylene))bis(phosphonic acid) and Lancillary = 1–4 have been assembled on fluorine-doped tin oxide (FTO)-TiO2 electrodes in dye-sensitized solar cells (DSCs). Performance parameters and external quantum efficiency (EQE) spectra of the DSCs (four fully-masked cells for each dye) reveal that the best performing dyes are [Cu(5)(1)]+ and [Cu(5)(3)]+. The alkynyl spacers are not beneficial, leading to a decrease in the short-circuit current density (JSC), confirmed by lower values of EQEmax. Addition of a co-absorbent (n-decylphosphonic acid) to [Cu(5)(1)]+ lead to no significant enhancement of performance for DSCs sensitized with [Cu(5)(1)]+. Electrochemical impedance spectroscopy (EIS) has been used to investigate the interfaces in DSCs; the analysis shows that more favourable electron injection into TiO2 is observed for sensitizers without the alkynyl spacer and confirms higher JSC values for [Cu(5)(1)]+.

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    Molecules
    Article . 2020 . Peer-reviewed
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    Molecules
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      ZENODO
      Article . 2020
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      https://dx.doi.org/10.5451/uni...
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    Authors: orcid Hmiel, B.;
    Hmiel, B.
    ORCID
    Harvested from ORCID Public Data File

    Hmiel, B. in OpenAIRE
    Petrenko, V. V.; Dyonisius, M. N.; Buizert, C.; +15 Authors

    Atmospheric methane (CH4) is a potent greenhouse gas, and its mole fraction has more than doubled since the preindustrial era. Fossil fuel extraction and use are among the largest anthropogenic sources of CH4 emissions, but the precise magnitude of these contributions is a subject of debate. Carbon-14 in CH4 (14CH4) can be used to distinguish between fossil (14C-free) CH4 emissions and contemporaneous biogenic sources; however, poorly constrained direct 14CH4 emissions from nuclear reactors have complicated this approach since the middle of the 20th century. Moreover, the partitioning of total fossil CH4 emissions (presently 172 to 195 teragrams CH4 per year) between anthropogenic and natural geological sources (such as seeps and mud volcanoes) is under debate; emission inventories suggest that the latter account for about 40 to 60 teragrams CH4 per year. Geological emissions were less than 15.4 teragrams CH4 per year at the end of the Pleistocene, about 11,600 years ago, but that period is an imperfect analogue for present-day emissions owing to the large terrestrial ice sheet cover, lower sea level and extensive permafrost. Here we use preindustrial-era ice core 14CH4 measurements to show that natural geological CH4 emissions to the atmosphere were about 1.6 teragrams CH4 per year, with a maximum of 5.4 teragrams CH4 per year (95 per cent confidence limit)—an order of magnitude lower than the currently used estimates. This result indicates that anthropogenic fossil CH4 emissions are underestimated by about 38 to 58 teragrams CH4 per year, or about 25 to 40 per cent of recent estimates. Our record highlights the human impact on the atmosphere and climate, provides a firm target for inventories of the global CH4 budget, and will help to inform strategies for targeted emission reductions.

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    Nature
    Article . 2020 . Peer-reviewed
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    Nature
    Article . 2020
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      Nature
      Article . 2020 . Peer-reviewed
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    Authors: Raveendran, Sindhu; orcid Gnansounou, Edgard;
    Gnansounou, Edgard
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    Gnansounou, Edgard in OpenAIRE
    Binod, Parameswaran; orcid Pandey, Ashok;
    Pandey, Ashok
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    Pandey, Ashok in OpenAIRE

    Abstract Sugarcane is a major crop cultivated globally and the residue left over after the crop harvest and extraction of juice is a good biomass source that can be used for the production of several useful chemicals. The sugarcane bagasse is an excellent substrate for the production of various biochemicals and enzymes through fermentation. Now major interest is focused on the utilization of these residue for biofuel production. The sugarcane crop residue is rich in cellulose and hemicellulose, hence it can be used for the production of bioethanol and other liquid transportation fuels. The present review gives a detailed account of the availability of sugarcane residue and various commercially important products that can be produced from this residue. It also provides recent developments in R&D on the bioconversion of sugarcane crop residue for value added products.

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    Renewable Energy
    Article . 2016 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Renewable Energy
      Article . 2016 . Peer-reviewed
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    Authors: Klaus, Valentin; id_orcid0000-0002-7469-6800; orcid Hölzel, Norbert;
    Hölzel, Norbert
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    Harvested from ORCID Public Data File

    Hölzel, Norbert in OpenAIRE
    Prati, Daniel; Schmitt, Barbara; +6 Authors

    Land-use change and intensification play a key role in the current biodiversity crisis. The resulting species loss can have severe effects on ecosystem functions and services, thereby increasing ecosystem vulnerability to climate change. We explored whether land-use intensification (i.e. fertilization intensity), plant diversity and other potentially confounding environmental factors may be significantly related to water use (i.e. drought stress) of grassland plants. Drought stress was assessed using δ13C abundances in aboveground plant biomass of 150 grassland plots across a gradient of land-use intensity. Under water shortage, plants are forced to increasingly take up the heavier 13C due to closing stomata leading to an enrichment of 13C in biomass. Plants were sampled at the community level and for single species, which belong to three different functional groups (one grass, one herb, two legumes). Results show that plant diversity was significantly related to the δ13C signal in community, grass and legume biomass indicating that drought stress was lower under higher diversity, although this relation was not significant for the herb species under study. Fertilization, in turn, mostly increased drought stress as indicated by more positive δ13C values. This effect was mostly indirect by decreasing plant diversity. In line with these results, we found similar patterns in the δ13C signal of the organic matter in the topsoil, indicating a long history of these processes. Our study provided strong indication for a positive biodiversity-ecosystem functioning relationship with reduced drought stress at higher plant diversity. However, it also underlined a negative reinforcing situation: as land-use intensification decreases plant diversity in grasslands, this might subsequently increases drought sensitivity. Vice-versa, enhancing plant diversity in species-poor agricultural grasslands may moderate negative effects of future climate change.

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    The Science of The Total Environment
    Article
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    Research Collection
    Article . 2016
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    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    The Science of The Total Environment
    Article . 2016 . Peer-reviewed
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    https://dx.doi.org/10.7892/bor...
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    Article . 2016
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      The Science of The Total Environment
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      Research Collection
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      The Science of The Total Environment
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: orcid Antoine Descoeudres;
    Antoine Descoeudres
    ORCID
    Harvested from ORCID Public Data File

    Antoine Descoeudres in OpenAIRE
    orcid Stefaan De Wolf;
    Stefaan De Wolf
    ORCID
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    Stefaan De Wolf in OpenAIRE
    orcid Eiji Kobayashi;
    Eiji Kobayashi
    ORCID
    Harvested from ORCID Public Data File

    Eiji Kobayashi in OpenAIRE
    Eiji Kobayashi; +4 Authors

    Silicon heterojunction solar cells use crystalline silicon (c-Si) wafers as optical absorbers and employ bilayers of doped/intrinsic hydrogenated amorphous silicon (a-Si:H) to form passivating contacts. Recently, we demonstrated that such solar cells increase their operating voltages and thus their conversion efficiencies during light exposure. We found that this performance increase is due to improved passivation of the a-Si:H/c-Si interface and is induced by injected charge carriers (either by light soaking or forward-voltage biasing of the device). Here, we discuss this counterintuitive behavior and establish that: (i) the performance increase is observed in solar cells as well as modules; (ii) this phenomenon requires the presence of doped a-Si:H films, but is independent from whether light is incident from the a-Si:H(p) or the a-Si:H(n) side; (iii) UV and blue photons do not play a role in this effect; (iv) the performance increase can be observed under illumination intensities as low as 20 W m(-1) (0.02-sun) and appears to be almost identical in strength when under 1-sun (1000 W m(-1)); (v) the underlying physical mechanism likely differs from annealing-induced surface passivation.

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    Solar Energy Materials and Solar Cells
    Article . 2017 . Peer-reviewed
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    Authors: orcid Hung Nguyen-Viet;
    Hung Nguyen-Viet
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    Hung Nguyen-Viet in OpenAIRE
    Hung Nguyen-Viet; orcid Guéladio Cissé;
    Guéladio Cissé
    ORCID
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    Guéladio Cissé in OpenAIRE
    Guéladio Cissé; +7 Authors

    In resource-constrained settings, the recovery of nutrients and the production of energy from liquid and solid waste are important. We determined the range and magnitude of potential community health impacts of six solid and liquid waste recovery and reuse business models in Hanoi, Vietnam.We employed a health impact assessment (HIA) approach using secondary data obtained from various sources supplemented with primary data collection. For determining the direction (positive or negative) and magnitude of potential health impacts in the population, a semiquantitative impact assessment was pursued.From a public health perspective, wastewater reuse for inland fish farming, coupled with on-site water treatment has considerable potential for individual and community-level health benefits. One of the business models investigated (i.e. dry fuel manufacturing with agro-waste) resulted in net negative health impacts.In Hanoi, the reuse of liquid and solid waste-as a mean to recover water and nutrients and to produce energy-has considerable potential for health benefits if appropriately managed and tailored to local contexts. Our HIA methodology provides an evidence-based decision-support tool for identification and promotion of business models for implementation in Hanoi.

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    International Journal of Public Health
    Article . 2016 . Peer-reviewed
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      International Journal of Public Health
      Article . 2016 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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    Authors: orcid Rantamäki, Antti;
    Rantamäki, Antti
    ORCID
    Harvested from ORCID Public Data File

    Rantamäki, Antti in OpenAIRE
    Rautiainen, Jussi; Sirbu, Alexei; Mereuta, Alexandru; +2 Authors

    A single frequency wafer-fused semiconductor disk laser at 1.56 µm with 1 watt of output power and a coherence length over 5 km in fiber is demonstrated. The result represents the highest output power reported for a narrow-line semiconductor disk laser operating at this spectral range. The study shows the promising potential of the wafer fusion technique for power scaling of single frequency vertical-cavity lasers emitting in the 1.3-1.6 µm range.

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    Optics Express
    Article . 2013 . Peer-reviewed
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    Optics Express
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    Optics Express
    Article . 2013
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      Optics Express
      Article . 2013 . Peer-reviewed
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      Optics Express
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      Optics Express
      Article . 2013
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    Authors: orcid François Arleo;
    François Arleo
    ORCID
    Harvested from ORCID Public Data File

    François Arleo in OpenAIRE
    orcid bw Florian Cougoulic;
    Florian Cougoulic
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    Florian Cougoulic in OpenAIRE
    orcid bw Stéphane Peigné;
    Stéphane Peigné
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    Derived by OpenAIRE algorithms or harvested from 3rd party repositories

    Stéphane Peigné in OpenAIRE

    Abstract We single out the role of fully coherent induced gluon radiation on light hadron production in pA collisions. The effect has the same general features as for quarkonium production, however with a richer color structure as the induced radiation depends on the global color charge of the partonic subprocess final state. Baseline predictions for light hadron nuclear suppression in pPb collisions at the LHC are provided, taking into account only the effect of fully coherent energy loss, which proves to be of the same order of magnitude as gluon shadowing or saturation. This underlines the need to include fully coherent energy loss in phenomenological studies of hadron production in pA collisions.

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    Journal of High Energy Physics
    Article . 2020 . Peer-reviewed
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    Journal of High Energy Physics
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    Journal of High Energy Physics
    Article . 2020
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    https://dx.doi.org/10.48550/ar...
    Article . 2020
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      Journal of High Energy Physics
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      https://dx.doi.org/10.48550/ar...
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