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It is critical and challenging to develop high performance transition metal phosphides (TMPs) electrocatalysts for oxygen evolution reaction (OER) to address fossil energy shortages. Herein, we report the synthesis of Co2P embedded in N-doped porous carbon (Co2P@N-C) via a facile one-step strategy. The obtained catalyst exhibits a lower overpotential of 352 mV for OER at a current density of 10 mA cm−2 and a small Tafel slope of 84.6 mV dec−1, with long-time reliable stability. The excellent electrocatalytic performance of Co2P@N-C can be mainly owed to the synergistic effect between the Co2P and highly conductive N-C substrate, which not only affords rich exposed active sites but also promotes faster charge transfer, thus significantly promoting OER process. This work presents a promising and industrially applicable synthetic strategy for the rational design of high performance nonnoble metal electrocatalysts with enhanced OER performance.

Both electrical and thermal efficiencies combine in determining and evaluating the performance of a PV/T collector. In this study, two PV/T systems consisting of poly and monocrystalline PV panels were used, which are connected from the bottom by a heat exchanger consisting of a spiral tube through which a nanofluid circulates. In this study, a base fluid, water, and ethylene glycol were used, and iron oxide nanoparticles (nano-Fe2O3) were used as an additive. The mixing was carried out according to the highest specifications adopted by the researchers, and the thermophysical properties of the fluid were carefully examined. The prepared nanofluid properties showed a limited effect of the nanoparticles on the density and viscosity of the resulting fluid. As for the thermal conductivity, it increased by increasing the mass fraction added to reach 140% for the case of adding 2% of nano-Fe2O3. The results of the zeta voltage test showed that the supplied suspensions had high stability. When a mass fraction of 0.5% nano-Fe2O3 was added the zeta potential was 68 mV, while for the case of 2%, it reached 49 mV. Performance tests showed a significant increase in the efficiencies with increased mass flow rate. It was found when analyzing the performance of the two systems for nanofluid flow rates from 0.08 to 0.17 kg/s that there are slight differences between the monocrystalline, and polycrystalline systems operating in the spiral type of exchanger. As for the case of using monocrystalline PV the electrical, thermal, and total PV/T efficiencies with 2% added Fe2O3 ranged between 10% to 13.3%, 43–59%, and 59 to 72%, respectively, compared to a standalone PV system. In the case of using polycrystalline PV, the electrical, thermal, and total PV/T efficiencies ranged from 11% to 13.75%, 40.3% to 63%, and 55.5% to 77.65%, respectively, compared to the standalone PV system. It was found that the PV/T electrical exergy was between 45, and 64 W with thermal exergy ranged from 40 to 166 W, and total exergy from 85 to 280 W, in the case of using a monocrystalline panel. In the case of using polycrystalline, the PV/T electrical, thermal, and total exergy were between 45 and 66 W, 42–172 W, and 85–238 W, respectively. The results showed that both types of PV panels can be used in the harsh weather conditions of the city of Baghdad with acceptable, and efficient productivity.

In underground mining, it is not currently feasible to forecast a coal burst incident. A coal burst usually includes suddenly abrupt energy release in line with the significant deformed shape in a coal mass as well as coal ejection. The major source of the released energy is the energy stored in the coal. The effect of geological characteristics in the coal on the possible released energy due to material and joint damping is classified as a current silent issue. Therefore, innovative research is needed to understand the influence of coal’s joint and cleat characters (directions and densities) on the possible energy release and/or dissipation. A simple and novel analytical solution is developed in this paper to calculate the amount of released energy due to varying joint density. A broad validation is conducted by comparing the outcomes of the developed analytical model with the results of a three-dimensional numerical simulation using the commercial discrete element package 3DEC. An appropriate agreement has been observed between the results from the numerical modelling and the suggested closed form solution. The paper derives a novel analytical solution to calculate the amount of released energy in coal with different joint densities.

Energy storage technology plays a significant role in the pursuit of the high-quality development of the electricity market. Many regions in China have issued policies and regulations of different intensities for promoting the popularization of the energy storage industry. Based on a variety of initial conditions of different regions, this paper explores the evolutionary process of electricity market players considering energy storage technology. The trilateral evolutionary game model is adopted to analyze the strategies of the power plant, the power grid, and the government. After assigning the model according to an actual situation, each equilibrium point corresponds to a real electricity market situation. The results indicate the following: (1) In the process of stabilizing, the role of “Advanced Imitators” leading the strategy of building energy storage changes between the power plant and the power grid. (2) In Eastern, Middle, and Southern China, the power plants and power grids on a greater-than-medium scale will choose to build energy storage without governmental regulations, due to the abundant net profit. (3) In the northeast of China, power plants with a medium-or-lower scale will choose not to build energy storage because of the relatively low on-grid price, and small power grids can make enough profits by operating energy storage facilities. (4) In Northern China, the large power plants and the medium power grids will choose to build energy storage due to the high electricity sale price and the resulting high profit. (5) In Western China, the small power plants and power grids cannot afford to build energy storage due to the low electricity price. The results lead to valuable policy suggestions for the local governments of China in promoting energy storage in the future. To meet the goal of energy storage popularization, regional electricity market plans need relevant policies based on its existing conditions, offering suitable external conditions for adding energy storage.

The prevailing need for a more sustainable management of natural resources depends not only on the decisions made by governments and the will of the population, but also on the knowledge of the role of energy in our society and the relevance of preserving natural resources. In this sense, critical work is being done to instill key concepts—such as the circular economy and sustainable energy—in higher education institutions. In this way, it is expected that future professionals and managers will be aware of the importance of energy optimization, and will learn a series of computational methods that can support the decision-making process. In the context of higher education, this paper reviews the main trends and challenges related to the concepts of circular economy and sustainable energy. Besides, we analyze the role of simulation and serious games as a learning tool for the aforementioned concepts. Finally, the paper provides insights and discusses open research opportunities regarding the use of these computational tools to incorporate circular economy concepts in higher education degrees. Our findings show that, while efforts are being made to include these concepts in current programs, there is still much work to be done, especially from the point of view of university management. In addition, the analysis of the teaching methodologies analyzed shows that, although their implementation has been successful in favoring the active learning of students, their use (especially that of serious games) is not yet widespread.

When the grid voltage is unbalanced, the positive and negative sequence components in the grid voltage cause grid current to be disordered. Under current balance control, proportional integral (PI) closed-loop control will increase the grid currents instantaneously, which affects the safety and reliability of the inverter operation, and PI parameters are difficult to select without the complete system mathematical model. This paper introduces an adaptive dynamic programming (ADP) approach to solve this problem. The best state feedback controller for the system is obtained by driving the ADP by the value iteration ( V I ) algorithm without the need for an accurate mathematical model. In the simulations, the ADP approach can improve the dynamic performance of the system, the current increase can be suppressed when the grid voltage is unbalanced, and the harmonic rate of output currents is reduced.

One of the repeating themes around the provision of the knowledge and skills needed for delivering sustainable communities is the idea of a “common language” for all built environment professionals. This suggestion has been repeated regularly with each new political and professional review within and between different sectors responsible for the delivery of sustainable communities. There have been multiple efforts to address academic limitations, industry fragmentation and promote more interdisciplinary working and sector collaboration. This research explored the role of skills for sustainable communities, particularly within the higher education (HE) sector, and the responses to support the development of a “common language of sustainability” that can be shared between different sectors, professional disciplines and stakeholders. As an interdisciplinary group of academics and practitioners working with the HE sector in the North East of England, we evaluate the progression of sector collaboration to develop a quintuple helix model for HE. We use this as a suitable framework for systematically “mapping” out the mixed sector (academic, public, business, community and environmental organisations) inputs and influences into a representative sample of HE degree modules that are delivered from foundation and undergraduate to postgraduate levels, including examples of part-time and distance-learning modules. We developed a cascade of models which demonstrate increasing levels of collaboration and their potential positive impact on the effectiveness of education on sustainable communities. The methodological assessments of modules were followed by semi-structured group reflective analysis undertaken through a series of online workshops (recorded during the Covid19 lockdown) to set out a collective understanding of the generic skills needed for the delivery of sustainable communities. These generic skills for sustainable communities are presented as a pedagogical progression model of teaching activities and learning outcomes applied to the levels within HE. We propose sustainability education principles and progressions with the hope that they can have an impact on the design or review of current degree modules and programmes. The paper informs future sustainability research to be grounded in holism and systems thinking; better understanding of values, ethics, influencing and political impact; and procedural authenticity.