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Cold-start (subzero startup) capability of polymer electrolyte fuel cell (PEFC) is of great importance. In this paper, the effects of the micro-porous-layer (MPL), varying start-up temperatures, start-up current density variation on the cold-start operation are investigated. We found PEFC with anode micro-porous-layer (AMPL), compared with one with CMPL, has higher possibility of successful cold start. By analyzing the anode and cathode pressure revolution of PEFC, the effect of MPL on the super cooled water removal and ice formation at different temperatures (-7,-10,-15 and-20℃) are discussed . In addition, we investigate the ice distribution in MEA through the X-ray device, by comparing the initial image when fuel cells shut down (before the produce the water) and final image after failed cold-start. We also explore the negative voltage phenomenon in the initial process of cold-start operation.

Abstract The increasing energy demand in developing countries has jeopardised energy security, necessitating the employment of solar energy to augment conventional energy sources. It is important to assess the annual performance parameters of solar power plants to understand its place in energy generation. This study analyses the performance and economic viability of a large-scale solar power park located in India. A 50 MWp Solar Photovoltaic Power Park (SPPP) located at Sakunala, in the State of Andhra Pradesh, is one of the largest solar power park in India, and the site receives an average solar radiation of 5.5–6.0 kWh/m2/day. The design, performance analysis, economic feasibility, and greenhouse gas mitigation of the 50 MWp SPPP is presented. The energy yields, performance ratio (PR), capacity utilization factor (CUF), and losses are assessed based on the IEC 61724 standards for two consecutive years (2018–2019 and 2019–2020). The performance results obtained are compared with the PVsyst simulation results. The PR, CUF, and energy yields are estimated as 0.779, 0.24, and 107,326.4 MWh in 2018–2019 and 0.691, 0.22, and 96,707.336 MWh in the year 2019–2020, respectively. The PVsyst simulator evaluates the PR, CUF, and energy yields as 0.80, 0.24, and 106,022 MWh, respectively. Further, the effect of power curtailment policies on solar PV projects is also discussed and the effect of curtailment policy on the economy of the solar power park in terms of payback period and emissions are analysed. The performance of the SPPP is also compared with those of other PV plants installed all over the world.

Straw and other biomasses can cause severe problems when used as fuel in combustion systems. Some of the major problems include high emission of alkalis, HCl, and especially SO2 to the gas phase. T...

Abstract To alleviate the shortage of natural gas resource and ease carbon emissions, a novel solar-driven combined cooling, heating and power (CCHP) system is designed and optimized using the genetic algorithm in the work. Different from the process of direct combustion in a conventional CCHP system, natural gas is firstly converted into syngas by a solar-driven natural gas reforming step, which is consumed in an efficient tri-generation system. Energy, economic and environmental evaluations on five office buildings in different climate zones in China are implemented to validate the advantages of the proposed system. Results show that the annual maximum primary energy saving, total cost saving, and CO2 emission reduction are 69.76%, 49.80%, and 71.55%, respectively. The system located in severe cold zones, where solar energy is abundant and building requires more heat load in whole year, achieves the highest benefits in comparison with separate systems. Furthermore, the sensitivities on the price fluctuations of electricity, natural gas and solar field to the system profits are investigated, which indicates that the influence of electricity price on the system performance is the most significant. Thus, a promising method for reducing the natural gas consumption and improving the utilization efficiency of solar energy is provided.

AbstractGold, silver, platinum and palladium typically crystallize with the face-centred cubic structure. Here we report the high-yield solution synthesis of gold nanoribbons in the 4H hexagonal polytype, a previously unreported metastable phase of gold. These gold nanoribbons undergo a phase transition from the original 4H hexagonal to face-centred cubic structure on ligand exchange under ambient conditions. Using monochromated electron energy-loss spectroscopy, the strong infrared plasmon absorption of single 4H gold nanoribbons is observed. Furthermore, the 4H hexagonal phases of silver, palladium and platinum can be readily stabilized through direct epitaxial growth of these metals on the 4H gold nanoribbon surface. Our findings may open up new strategies for the crystal phase-controlled synthesis of advanced noble metal nanomaterials.

Bioplastics are alternatives of conventional petroleum-based plastics. Bioplastics are polymers processed from renewable sources and are biodegradable. This study aims at conducting an environmental impact assessment of the bioprocessing of agricultural wastes into bioplastics compared to petro-plastics using an LCA approach. Bioplastics were produced from potato peels in laboratory. In a biochemical reaction under heating, starch was extracted from peels and glycerin, vinegar and water were added with a range of different ratios, which resulted in producing different samples of bio-based plastics. Nevertheless, the environmental impact of the bioplastics production process was evaluated and compared to petro-plastics. A life cycle analysis of bioplastics produced in laboratory and petro-plastics was conducted. The results are presented in the form of global warming potential, and other environmental impacts including acidification potential, eutrophication potential, freshwater ecotoxicity potential, human toxicity potential, and ozone layer depletion of producing bioplastics are compared to petro-plastics. The results show that the greenhouse gases (GHG) emissions, through the different experiments to produce bioplastics, range between 0.354 and 0.623 kg CO2 eq. per kg bioplastic compared to 2.37 kg CO2 eq. per kg polypropylene as a petro-plastic. The results also showed that there are no significant potential effects for the bioplastics produced from potato peels on different environmental impacts in comparison with poly-β-hydroxybutyric acid and polypropylene. Thus, the bioplastics produced from agricultural wastes can be manufactured in industrial scale to reduce the dependence on petroleum-based plastics. This in turn will mitigate GHG emissions and reduce the negative environmental impacts on climate change.

People’s attention of transformer condition assessment is increasing in recent year and data mining is applied in transformer condition assessment with its obvious superiority in dealing with complex data and finding potential problems. In this paper, the process of the research on applying data mining to transformer condition assessment is summarized. The research results of data processing methods such as rough set theory, principal component analysis and colony algorithm as well as the research result of transformer condition assessment such as vector machine, neural network, Bayes network, association rules and fuzzy theory are introduced, analyzed and compared in detail. The advise on the choice and quantification of figure, the employ of the pattern recognition method, the blend of multi-information and visualization display are given.

Societal relations in rural areas have entered into a new stage of adjustment over the past decade. However, the adjustment, which might bring about profound societal changes in countryside as well as in China as a whole, have not been paid much attention and very few studies have been conducted from the perspective of ecological resource crises. We use the case of a village as an example to show how water pollution, as one of the contributory factors, possibly affect the transition of clans and societal changes in Chinese villages. Through observation and interviews, we find that there is an apparent rise of “New Clanism” within clans, which gradually abandons the tradition of supremacy of clan interests and places family or individual interests at top priority. We also find that clan boundaries get increasingly obscure since the integrity of clans is undermined by the rise of new interest groups across clans, but the boundaries remain relatively clear due to the consistency (albeit incomplete) of clan interests. Some new clan élites and representatives of new interest groups get involved in village governance, which indicates that their goals have shifted from natural resources to social or political capital. The significance of our findings is that they provide not only a unique perspective for the interaction between society and resources, but also some new ideas for the future study of rural China at the environment-social interface.