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Abstract Bitumen recovery by steam-solvent coinjection involves the coupled thermal/compositional mechanisms for reduction of bitumen viscosity. Reliable design of such processes requires reservoir flow simulation based on a proper phase-behavior model so that the oleic-phase viscosity near the steam-chamber edge can be modeled reliably. However, the effect of bitumen characterization (e.g., the number of pseudo components used) on steam-solvent coinjection simulation has not been studied in detail, and can be realized only after running multiple reservoir simulations, which is time consuming. There are two main objectives in this paper. One is to develop a reliable method for bitumen characterization by improving the fluid characterization method that was recently developed based on perturbation from n-alkanes (PnA). The other is to develop a novel analytical method for assessing the sensitivity of a particular coinjection simulation to bitumen characterization without having to perform reservoir simulations. A simulation case study is given to validate this analytical method. A proper number of pseudo components for bitumen characterization cannot be determined without considering the effect of phase behavior on the oleic-phase viscosity at chamber-edge conditions in steam-solvent coinjection simulation. Results show that the analytical method developed in this research can detect the sensitivity of recovery simulation to bitumen characterization without performing multiple flow simulations using different sets of fluid models. The PnA-based method developed for bitumen characterization gives reliable predictions of phase behavior for bitumen/solvent mixtures with a small amount of experimental data.

SummaryThe German government has adopted a law that requires sewage plants to go beyond the recovery of phosphorus from wastewater and to promote recycling. We argue that there is no physical global short‐ or mid‐term phosphorus scarcity. However, we also argue that there are legitimate reasons for policies such as those of Germany, including: precaution as a way to ensure future generations’ long‐term supply security, promotion of technologies for closed‐loop economics in a promising stage of technology development, and decrease in the current supply risk with a new resource pool.

Abstract The development of predictive mathematical models for water management in polymer electrolyte membrane fuel cells requires detailed understanding of water distribution and water transport across the Nafion layer. The anisotropic microstructure of Nafion suggests the measurement of water content and mass transport should be along the fuel cell functional direction, i.e. across the membrane. Non-invasive, high resolution, microscopy measurements of this type are very challenging. We report here the calibration of a minimal mathematical model for diffusive water transport in Nafion against data from high-resolution water content maps determined with a new magnetic resonance imaging methodology developed for this purpose. A mock fuel cell was designed to permit well-controlled wetting and drying boundary conditions. With no chemical potential driving force involved, we assume the water transport behavior will be dominated by diffusion. Moreover we show that, in this context, our model is mathematically equivalent to the traditional permeation models based upon saturation dependent pressure gradients via a capillary pressure ansatz. The non-linear equilibrium water distribution across the Nafion membrane measured in this work suggests a bi-modal diffusivity. The model constructed associates distinct transport behaviors to water contents above and below a critical threshold, consistent with a rearrangement of a micro-structural pore network. The experimental observation and the model prediction agree with the primary features of Weber's model of Nafion, which predicts distinct modes of transport for hydration fronts traversing the through-plane direction of the membrane.

Abstract A small reverse osmoisis (RO) plant supplied by a photovoltaic (PV) power supply has been installed at the island of Gran Canaria. On behalf of this system the feasibility of small PV-RO systems (1 m3/d) is investigated. The RO-plant is described in detail concerning its technical specifications, its operation constraints and its energy demand. Furthermore the photovoltaic power supply is described in detail. With simulations it is shown how the system is designed to guarantee a reliability of more than 96% in the water supply. A brief economic analysis shows that the water production costs are still high (about 16 $/m3) but can be lowered in future.

Abstract Aquatic centres are large and complex buildings which include at least one indoor swimming pool and several amenities such as gymnasium, cafe, office, spa, sauna and stadium. There are only a few studies that have investigated the energy and water use of aquatic centres. This study developed energy and water benchmarks for aquatic centres in Victoria, Australia using data from 22 aquatic centres. Statistical regression based benchmarking method was used to identify relevant correlations and significances of several variables in regards to the energy and water use of aquatic centres. The analysis indicated that conditioned usable floor area and the number of visitors have the strongest correlation and significance to the energy and water use of aquatic centres respectively. No strong correlation was found between energy and water use. The proposed energy benchmark for aquatic centres ranges between 648 kWh/m2 and 2283 kWh/m2 (conditioned usable floor area) and the proposed water benchmark for aquatic centres ranges between 11 L/Visitor and 110 L/Visitor. An attempt to identify energy and water efficient characteristics of aquatic centres was also undertaken using the detailed data collected.

The biogas production technology has improved over the last years for the aim of reducing the costs of the process, increasing the biogas yields, and minimizing the greenhouse gas emissions. To obtain a stable and efficient biogas production, there are several design considerations and operational parameters to be taken into account. Besides, adapting the process to unanticipated conditions can be achieved by adequate monitoring of various operational parameters. This paper reviews the research that has been conducted over the last years. This review paper summarizes the developments in biogas design and operation, while highlighting the main factors that affect the efficiency of the anaerobic digestion process. The study’s outcomes revealed that the optimum operational values of the main parameters may vary from one biogas plant to another. Additionally, the negative conditions that should be avoided while operating a biogas plant were identified.

This paper proposes a two-part process for producing biocrude with reduced impurities. The biocrude was produced from hydrothermal liquefaction (HTL) of Spirulina sp. and Tetraselmis sp. in a batch reactor at both 300 and 350°C, 5min, and 16%w/w solid feed composition. The resultant biocrudes were vacuum distilled at a maximum temperature of 360°C. It was shown that biocrude quality could be enhanced without using catalyst by vacuum distillation (VD). The biocrude yield for Spirulina sp. was 36wt% at 300°C, 42wt% at 350°C, and for Tetraselmis sp. was 34wt% at 300°C, and 58wt% at 350°C. VD of Spirulina sp. biocrude obtained at 300 and 350°C led to 62 and 67wt% distilled biocrudes yield, respectively. VD of Tetraselmis sp. biocrude obtained at 300°C was 70wt%, and 73wt% at 350°C. The higher heating values (HHV) increased from 32MJ/kg to 40MJ/kg. There were substantial reductions in oxygen, metallic content, and boiling point ranges in distilled biocrudes.

Abstract The accumulation of waste biomass and plastic and the inefficient combustion of low-quality coal is a major cause of energy loss and air pollution in rural China. This paper reports for the first time an experimental and multi-perspective analysis on an industrial scale co-pyrolysis of waste biomass and plastic. The results show that the resulting biochar product had a low calorific value of ≥21.0 MJ/kg, which meets the national standard for commercial solid fuel (GB/T 31862–2015). The calorific value of the produced gas was over 10 MJ/m3 and met the requirements of the national standard for residential heating and cooking (GB/T 13612–2006). The products of the co-pyrolysis can replace 1100 t of standard coal per annum, and reduce carbon dioxide emissions, sulfur dioxide emissions, smoke, and other contaminants at the rate of 1720 t, 5–6 t, and 320 kg, respectively, as well as reducing smoke pollution. In addition, through the recycling of 750 t of plastic waste per annum for use in the co-pyrolysis, this method can reduce the white pollution of 50–66.7 km2 of farmland in the local area. The present study can guide the optimization of such systems and lead to adequate flexibility in the co-pyrolysis of different wastes to generate economic and socioenvironmental benefits.

The enhanced oil recovery technique of low-salinity (LS) water flooding is a topic of substantial interest in the petroleum industry. Studies have shown that LS brine injection can increase oil production relative to conventional high-salinity (HS) brine injection, but contradictory results have also been reported and an understanding of the underlying mechanisms remains elusive. We have recently developed a steady-state pore network model to simulate oil recovery by LS brine injection in uniformly wetted pore structures (Watson et al., Transp. Porous Med. 118, 201-223, 2017). We extend this approach here to investigate the low-salinity effect (LSE) in heterogeneously wetted media. We couple a model of capillary force-driven fluid displacement to a novel tracer algorithm and track the salinity front in the pore network as oil and HS brine are displaced by injected LS brine. The wettability of the pore structure is modified in regions where water salinity falls below a critical threshold, and simulations show that this can have significant consequences for oil recovery. For networks that contain spanning clusters of both water-wet and oil-wet (OW) pores prior to flooding, our results demonstrate that the OW pores contain the only viable source of incremental oil recovery by LS brine injection. Moreover, we show that a LS-induced increase in microscopic sweep efficiency in the OW pore fraction is a necessary, but not sufficient, condition to guarantee additional oil production. Simulations suggest that the fraction of OW pores in the network, the average network connectivity and the initial HS brine saturation are key factors that can determine the extent of any improvement in oil recovery in heterogeneously wetted networks following LS brine injection. This study highlights that the mechanisms of the LSE can be markedly different in uniformly wetted and non-uniformly wetted porous media.