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This paper discusses key design and development issues in utilizing coal and other solid fuels in gas turbines. These fuels may be burned in raw form or processed to produce liquids or gases in more or less refined forms. The use of such fuels in gas turbines requires resolution of technology issues which are of little or no consequence for conventional natural gas and refined oil fuels. For coal, these issues are primarily related to the solid form in which coal is naturally found and its high ash and contaminant levels. Biomass presents another set of issues similar to those of coal. Among the key areas discussed are effects of ash and contaminant level on deposition, corrosion, and erosion of turbine hot parts, with particular emphasis on deposition effects.

Progress in science often follows or parallels the development of new techniques. The optical microscope helped convert medicine and biology from a speculative activity in old times to today's sophisticated scientific disciplines. The telescope changed the study and interpretation of heavens from mythology to science. X-ray diffraction enabled the flourishing of solid state physics and materials science. The technique object of this review, Ambient Pressure Photoelectron Spectroscopy or APPES for short, has also the potential of producing dramatic changes in the study of liquid and solid surfaces, particularly in areas such as atmospheric, environment and catalysis sciences. APPES adds an important missing element to the host of techniques that give fundamental information, i.e., spectroscopy and microscopy, about surfaces in the presence of gases and vapors, as encountered in industrial catalysis and atmospheric environments. APPES brings electron spectroscopy into the realm of techniques that can be used in practical environments. Decades of surface science in ultra high vacuum (UHV) has shown the power of electron spectroscopy in its various manifestations. Their unique property is the extremely short elastic mean free path of electrons as they travel through condensed matter, of the order of a few atomic distances in the energy rangemore » from a few eV to a few thousand eV. As a consequence of this the information obtained by analyzing electrons emitted or scattered from a surface refers to the top first few atomic layers, which is what surface science is all about. Low energy electron diffraction (LEED), Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), Ultraviolet photoelectron spectroscopy (UPS), and other such techniques have been used for decades and provided some of the most fundamental knowledge about surface crystallography, composition and electronic structure available today. Unfortunately the high interaction cross section of electrons with matter also prevents them from traveling long distances unscattered in gas environments. Above the millibar pressure range this distance is reduced to less that a millimeter, effectively preventing its use in the most relevant environments, usually between millibars and atmospheric pressures. There is therefore a large gap of several orders of magnitude where information about surfaces is scarce because these powerful electron spectroscopies cannot operate. One characteristic of surfaces in ambient pressure environments is that they are covered by dense layers of molecules, even when their binding energy is weak. Water for example is known to form layers several molecules thick at room temperature in humid environments. Metals readily form oxide films several layers thick in oxygen atmospheres. Dense layers of adsorbed molecules can also be produced in ultra high vacuum, often by the simple and expedient method of cooling the sample to cryogenic temperatures. A large amount of data has been obtained in the past in UHV by surface scientists using this method. While this has provided valuable information it begs the question of whether the structures formed in this manner represent equilibrium structures or metastable ones, kinetically trapped due to high activation energies that cannot be overcome at low temperature. From a thermodynamic point of view is interesting to consider the entropic contribution to the Gibbs free energy, which we can call 'the pressure factor', equal to kT.logP. This factor amounts to a sizeable 0.3 eV difference at room temperature between UHV (<10{sup -8} Pascal) and atmospheric pressures. Such change if free energy can definitely result in changes in surface structure and stability. Entire areas of the phase diagram are out of reach due to the pressure gap. Even when cooling is not necessary, many surface treatments and most chemical reactions necessitate the presence of gases at pressures ranging from millibar to bars. What is the structure and chemical nature of the species formed on the surface in equilibrium with such gases? As we shall illustrate in this review, APPES provides a much needed electron spectroscopy to analyze surface electronic structure and composition in equilibrium with gases.« less

This report was prepared as part of the documentation of Annex 10 (Photoproduction of Hydrogen) of the IEA Hydrogen Agreement. Subtask A of this Annex concerned photo-electrochemical hydrogen production, with an emphasis on direct water splitting. However, studies of non oxygen-evolving systems were also included in view of their interesting potential for combined hydrogen production and waste degradation. Annex 10 was operative from 1 March 1995 until 1 October 1998. One of the collaborative projects involved scientists from the Universities of Geneva and Bern, and the Federal Institute of Technology in Laussane, Switzerland. A device consisting of a photoelectrochemical cell (PEC) with a WO{sub 3} photoanode connected in series with a so-called Grazel cell (a dye sensitized liquid junction photovoltaic cell) was developed and studied in this project. Part of these studies concerned the combination of hydrogen production with degradation of organic pollutants, as described in Chapter 3 of this report. For completeness, a review of the state of the art of organic waste treatment is included in Chapter 2. Most of the work at the University of Geneva, under the supervision of Prof. J. Augustynski, was focused on the development and testing of efficient WO{sub 3} photoanodes for the photoelectrochemical degradation of organic waste solutions. Two types of WO{sub 3} anodes were developed: non transparent bulk photoanodes and non-particle-based transparent film photoanodes. Both types were tested for degradation and proved to be very efficient in dilute solutions. For instance, a solar-to-chemical energy conversion efficiency of 9% was obtained by operating the device in a 0.01M solution of methanol (as compared to about 4% obtained for direct water splitting with the same device). These organic compounds are oxidized to CO{sub 2} by the photocurrent produced by the photoanode. The advantages of this procedure over conventional electrolytic degradation are that much (an order of magnitude) less energy is required and that sunlight can be used directly. In the case of photoproduction of hydrogen, as compared to water splitting, feeding the anodic compartment of the PEC with an organic pollutant, instead of the usual supporting electrolyte, will bring about a substantial increase of the photocurrent at a given illumination. Thus, the replacement of the photo-oxidation of water by the photodegradation of organic waste will be accompanied by a gain in solar-to-chemical conversion efficiency and hence by a decrease in the cost of the photoproduced hydrogen. Taking into account the benefits and possible revenues obtainable by the waste degradation, this would seem to be a promising approach to the photoproduction of hydrogen. Hydrogen sulfide (H{sub 2}S) is another waste effluent requiring extensive treatment, especially in petroleum refineries. The so-called Claus process is normally used to convert the H{sub 2}S to elemental sulfur. A sulfur recovery process developed at the Florida Solar Energy Center is described briefly in Chapter 4 by Dr. C. Linkous as a typical example of the photoproduction of hydrogen in a non oxygen-evolving system. The encouraging results obtained in these investigations of photoelectrochemical hydrogen production combined with organic waste degradation, have prompted a decision to continue the work under the new IEA Hydrogen Agreement Annex 14, Photoelectrolytic Hydrogen Production.

AbstractA natural laboratory is a place supporting the conditions for hypothesis testing under non-anthropogenic settings. Located at the southern end of the Magellanic sub-Antarctic ecoregion in southwestern South America, the Cape Horn Biosphere Reserve (CHBR) has one of the most extreme rainfall gradients in the world. Subject to oceanic climate conditions, it is also characterized by moderate thermal fluctuations throughout the year. This makes it a unique natural laboratory for studying the effects of extreme rainfall variations on forest bird communities. Here, we monitor the bird species richness in the different forest types present in the CHBR. We found that species richness decreased with increasing precipitation, in which an increase of 100 mm in average annual precipitation showed about 1% decrease in species richness. Similar patterns were found among different forest types within the CHBR. These results provide a baseline to investigate the interactions between physical and biotic factors in a subpolar region that climatically contrasts with boreal forests, which is subject to continental climatic conditions. This research highlights the importance of ecological and ornithological long-term studies in the CHBR, which can contribute both to a higher resolution of the heterogeneity of climate changes in different regions of the world, and to orient conservation policies in the Magellanic sub-Antarctic ecoregion in the face of growing development pressures.

This report addresses the Asia-Pacific Economic Cooperation (APEC) organization’s desire to minimize the learning time required to understand the implications of smart-grid concepts so APEC members can advance their thinking in a timely manner and advance strategies regarding smart approaches that can help meet their environmental-sustainability and energy-efficiency policy goals. As significant investments are needed to grow and maintain the electricity infrastructure, consideration needs to be given to how information and communications technologies can be applied to electricity infrastructure decisions that not only meet traditional needs for basic service and reliability, but also provide the flexibility for a changing the mix of generation sources with sensitivity to environmental and societal impacts.

The costs for carbon dioxide (CO2) capture and storage (CCS) in geologic formations is estimated to be $6–75/t CO2 .I n the absence of a mandate to reduce greenhouse gas emissions or some other significant incentive for CCS deployment, this cost effectively limits CCS technology deployment to small niche markets and stymies the potential for further technological development through learning by doing until these disincentives for the free venting of CO2 are in place. By far, the largest current fraction of these costs is capture (including compression and dehydration), commonly estimated at $25–60/t CO2 for power plant applications, followed by CO2 transport and storage, estimated at $0–15/t CO2. Of the storage costs, only a small fraction of the cost will go to accurate geological characterization. These one time costs are probably on the order of $0.1/t CO2 or less as these costs are spread out over the many millions of tons likely to be injected into a field over many decades. Geologic assessments include information central to capacity prediction, risk estimation for the target intervals and development facilities engineering. Since assessment costs are roughly two orders of magnitude smaller than capture costs, and assessment products carry other tangible societal benefits, such as improved accuracy in fossil fuel and ground water reserves estimates, government or joint private–public funding of major assessment initiatives should underpin early policy choices regarding CO2 storage deployment and should serve as a point of entry for policy makers and regulators. Early assessment is also likely to improve the knowledge base upon which the first commercial CCS deployments will rest. 2005 Elsevier Ltd. All rights reserved.

The Lancet Countdown : le suivi des progrès en matière de santé et de changement climatique est une collaboration de recherche internationale et multidisciplinaire entre des établissements universitaires et des praticiens du monde entier. Il fait suite aux travaux de la Commission Lancet de 2015, qui a conclu que la réponse au changement climatique pourrait être « la plus grande opportunité de santé mondiale du XXIe siècle ». Le compte à rebours du Lancet vise à suivre les impacts sur la santé des risques climatiques ; la résilience et l'adaptation en matière de santé ; les co-bénéfices pour la santé de l'atténuation du changement climatique ; l'économie et la finance ; et l'engagement politique et plus large. Ces domaines d'intervention forment les cinq groupes de travail thématiques du Lancet Countdown et représentent différents aspects de l'association complexe entre la santé et le changement climatique. Ces groupes thématiques fourniront des indicateurs pour une vue d'ensemble mondiale de la santé et du changement climatique ; des études de cas nationales mettant en évidence les pays qui ouvrent la voie ou vont à l'encontre de la tendance ; et un engagement avec un éventail de parties prenantes. Le compte à rebours du Lancet vise finalement à rendre compte chaque année d'une série d'indicateurs dans ces cinq groupes de travail. Ce document décrit les indicateurs potentiels et les domaines d'indicateurs à suivre par la collaboration, avec des suggestions sur les méthodologies et les ensembles de données disponibles pour atteindre cet objectif. Les domaines d'indicateurs proposés doivent être affinés et marquent le début d'un processus de consultation en cours - de novembre 2016 au début de 2017 - pour développer ces domaines, identifier les domaines clés non couverts actuellement et modifier les indicateurs si nécessaire. Cette collaboration cherchera activement à s'engager dans les processus de suivi existants, tels que les objectifs de développement durable des Nations Unies et les profils de pays de l'OMS en matière de climat et de santé. Les indicateurs évolueront également au fil du temps grâce à une collaboration continue avec des experts et un éventail de parties prenantes, et dépendront de l'émergence de nouvelles preuves et connaissances. Au cours de ses travaux, le Lancet Countdown adoptera un processus collaboratif et itératif, qui vise à compléter les initiatives existantes, à accueillir l'engagement avec de nouveaux partenaires et à être ouvert au développement de nouveaux projets de recherche sur la santé et le changement climatique. The Lancet Countdown: tracking progress on health and climate change es una colaboración de investigación internacional y multidisciplinaria entre instituciones académicas y profesionales de todo el mundo. Sigue el trabajo de la Comisión Lancet de 2015, que concluyó que la respuesta al cambio climático podría ser "la mayor oportunidad de salud global del siglo XXI". The Lancet Countdown tiene como objetivo realizar un seguimiento de los impactos en la salud de los peligros climáticos; la resiliencia y la adaptación a la salud; los beneficios colaterales para la salud de la mitigación del cambio climático; la economía y las finanzas; y el compromiso político y más amplio. Estas áreas de enfoque forman los cinco grupos de trabajo temáticos de The Lancet Countdown y representan diferentes aspectos de la compleja asociación entre la salud y el cambio climático. Estos grupos temáticos proporcionarán indicadores para una visión global de la salud y el cambio climático; estudios de casos nacionales que destacan a los países que lideran el camino o van en contra de la tendencia; y el compromiso con una variedad de partes interesadas. En última instancia, The Lancet Countdown tiene como objetivo informar anualmente sobre una serie de indicadores en estos cinco grupos de trabajo. Este documento describe los posibles indicadores y dominios de indicadores a ser rastreados por la colaboración, con sugerencias sobre las metodologías y conjuntos de datos disponibles para lograr este fin. Los dominios de indicadores propuestos requieren un mayor refinamiento y marcan el comienzo de un proceso de consulta continuo, desde noviembre de 2016 hasta principios de 2017, para desarrollar estos dominios, identificar áreas clave que actualmente no están cubiertas y cambiar los indicadores cuando sea necesario. Esta colaboración buscará activamente involucrarse con los procesos de monitoreo existentes, como los Objetivos de Desarrollo Sostenible de la ONU y LOS perfiles climáticos y de salud de los países de la OMS. Los indicadores también evolucionarán con el tiempo a través de la colaboración continua con expertos y una variedad de partes interesadas, y dependerán de la aparición de nuevas pruebas y conocimientos. Durante el transcurso de su trabajo, The Lancet Countdown adoptará un proceso colaborativo e iterativo, que tiene como objetivo complementar las iniciativas existentes, dar la bienvenida al compromiso con nuevos socios y estar abierto al desarrollo de nuevos proyectos de investigación sobre salud y cambio climático. The Lancet Countdown: tracking progress on health and climate change is an international, multidisciplinary research collaboration between academic institutions and practitioners across the world. It follows on from the work of the 2015 Lancet Commission, which concluded that the response to climate change could be "the greatest global health opportunity of the 21st century". The Lancet Countdown aims to track the health impacts of climate hazards; health resilience and adaptation; health co-benefits of climate change mitigation; economics and finance; and political and broader engagement. These focus areas form the five thematic working groups of the Lancet Countdown and represent different aspects of the complex association between health and climate change. These thematic groups will provide indicators for a global overview of health and climate change; national case studies highlighting countries leading the way or going against the trend; and engagement with a range of stakeholders. The Lancet Countdown ultimately aims to report annually on a series of indicators across these five working groups. This paper outlines the potential indicators and indicator domains to be tracked by the collaboration, with suggestions on the methodologies and datasets available to achieve this end. The proposed indicator domains require further refinement, and mark the beginning of an ongoing consultation process-from November, 2016 to early 2017-to develop these domains, identify key areas not currently covered, and change indicators where necessary. This collaboration will actively seek to engage with existing monitoring processes, such as the UN Sustainable Development Goals and WHO's climate and health country profiles. The indicators will also evolve over time through ongoing collaboration with experts and a range of stakeholders, and be dependent on the emergence of new evidence and knowledge. During the course of its work, the Lancet Countdown will adopt a collaborative and iterative process, which aims to complement existing initiatives, welcome engagement with new partners, and be open to developing new research projects on health and climate change. العد التنازلي لمجلة لانسيت: تتبع التقدم المحرز في مجال الصحة وتغير المناخ هو تعاون بحثي دولي متعدد التخصصات بين المؤسسات الأكاديمية والممارسين في جميع أنحاء العالم. ويتبع ذلك عمل لجنة لانسيت لعام 2015، التي خلصت إلى أن الاستجابة لتغير المناخ يمكن أن تكون "أعظم فرصة صحية عالمية في القرن الحادي والعشرين". يهدف العد التنازلي لمجلة لانسيت إلى تتبع الآثار الصحية للمخاطر المناخية ؛ والمرونة الصحية والتكيف ؛ والفوائد الصحية المشتركة للتخفيف من آثار تغير المناخ ؛ والاقتصاد والتمويل ؛ والمشاركة السياسية والأوسع نطاقًا. تشكل مجالات التركيز هذه مجموعات العمل المواضيعية الخمسة للعد التنازلي لمجلة لانسيت وتمثل جوانب مختلفة من الارتباط المعقد بين الصحة وتغير المناخ. وستوفر هذه المجموعات المواضيعية مؤشرات لإلقاء نظرة عامة عالمية على الصحة وتغير المناخ ؛ ودراسات حالة وطنية تسلط الضوء على البلدان التي تقود الطريق أو تسير عكس الاتجاه ؛ والمشاركة مع مجموعة من أصحاب المصلحة. يهدف العد التنازلي لمجلة لانسيت في نهاية المطاف إلى تقديم تقرير سنوي عن سلسلة من المؤشرات عبر مجموعات العمل الخمس هذه. تحدد هذه الورقة المؤشرات المحتملة ومجالات المؤشرات التي سيتم تتبعها من خلال التعاون، مع اقتراحات حول المنهجيات ومجموعات البيانات المتاحة لتحقيق هذه الغاية. تتطلب مجالات المؤشرات المقترحة مزيدًا من التنقيح، وتمثل بداية عملية تشاور مستمرة - من نوفمبر 2016 إلى أوائل 2017 - لتطوير هذه المجالات، وتحديد المجالات الرئيسية غير المشمولة حاليًا، وتغيير المؤشرات عند الضرورة. سيسعى هذا التعاون بنشاط إلى المشاركة في عمليات الرصد القائمة، مثل أهداف الأمم المتحدة للتنمية المستدامة والملامح القطرية للمناخ والصحة لمنظمة الصحة العالمية. ستتطور المؤشرات أيضًا بمرور الوقت من خلال التعاون المستمر مع الخبراء ومجموعة من أصحاب المصلحة، وستعتمد على ظهور أدلة ومعارف جديدة. خلال عملها، سيعتمد العد التنازلي لمجلة لانسيت عملية تعاونية وتكرارية، تهدف إلى استكمال المبادرات الحالية، والترحيب بالمشاركة مع شركاء جدد، والانفتاح على تطوير مشاريع بحثية جديدة حول الصحة وتغير المناخ.