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  • Authors: Ding, Yang; Wang, Chunhua; Pei, Lang; Mao, Qinan; +7 Authors

    Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions, Mn4+ ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode (W-LED), plant cultivation LED, and temperature thermometer. Up to now, Mn4+ has been widely introduced into the lattices of various inorganic hosts for brightly red-emitting phosphors. However, how to correlate the structure-activity relationship between host framework, luminescence property, and photoelectric device is urgently demanded. In this review, we thoroughly summarize the recent advances of Mn4+ doped phosphors. Meanwhile, several strategies like co-doping and defect passivation for improving Mn4+ emission are also discussed. Most importantly, the relationship between the protocols for tailoring the structures of Mn4+ doped phosphors, increased luminescence performance, and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated. Finally, the challenges and perspectives of Mn4+ doped phosphors for practical applications are anticipated. We cordially anticipate that this review can deliver a deep comprehension of not only Mn4+ luminescence mechanism but also the crystal structure tailoring strategy of phosphors, so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.

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  • Authors: Ding, Yang; Wang, Chunhua; Pei, Lang; Mao, Qinan; +7 Authors

    Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions, Mn4+ ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode (W-LED), plant cultivation LED, and temperature thermometer. Up to now, Mn4+ has been widely introduced into the lattices of various inorganic hosts for brightly red-emitting phosphors. However, how to correlate the structure-activity relationship between host framework, luminescence property, and photoelectric device is urgently demanded. In this review, we thoroughly summarize the recent advances of Mn4+ doped phosphors. Meanwhile, several strategies like co-doping and defect passivation for improving Mn4+ emission are also discussed. Most importantly, the relationship between the protocols for tailoring the structures of Mn4+ doped phosphors, increased luminescence performance, and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated. Finally, the challenges and perspectives of Mn4+ doped phosphors for practical applications are anticipated. We cordially anticipate that this review can deliver a deep comprehension of not only Mn4+ luminescence mechanism but also the crystal structure tailoring strategy of phosphors, so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.

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  • Authors: Dieter Sell; M. M. W. Etschmann; Jens Schrader;

    Fourteen yeast strains were screened for production of 2-phenylethanol from L-phenylalanine with molasses as carbon source. Up to 1 g 2-phenylethanol l-1 was obtained. Using oleyl alcohol as a second phase for in situ product removal to enhance the production of 2-phenylethanol increased the yield to about 3 g 2-phenylethanol l-1 at 35 degrees C. The most productive strains were Kluyveromyces marxianus CBS 600 and CBS 397.

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  • Authors: Dieter Sell; M. M. W. Etschmann; Jens Schrader;

    Fourteen yeast strains were screened for production of 2-phenylethanol from L-phenylalanine with molasses as carbon source. Up to 1 g 2-phenylethanol l-1 was obtained. Using oleyl alcohol as a second phase for in situ product removal to enhance the production of 2-phenylethanol increased the yield to about 3 g 2-phenylethanol l-1 at 35 degrees C. The most productive strains were Kluyveromyces marxianus CBS 600 and CBS 397.

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  • Authors: Tröger, N.; Richter, D.; Stahl, R.;

    The project between tthe Deutsche Biomasseforschungszentrum (DBFZ) and the Karlsruhe Institute of Technology (KIT) focuses on the pr rovision of alternative fuels by thermochemical conversion. Biogenic residues and wastes which are not used yet or which could be utilised more efficiently are studied. The selection of possible feedstock was supported by a techhnical potential analysis including the competition to th he food industry. The technical suitability of raw materials for the fast pyrolysis (FP) process was of special in nterest. As a possible feedstock following types of biomass were studied: corn stover, corn cobs, biogenic floating re efuse (river Rhine and Baltic Sea), scrap wood, bark, rape s straw, sunflower straw, draff, diverse residues of flour production and hay. A process development unit (PDU) with a biomass feeding rate of 10 kg/h and a twin screw m mixer reactor was used for all experiments. It was found that different types of biomass form different char, condensate e and gas yields due to varying ash levels and lignocellulosic composition. Elemental formulas for feedstock, char, organic condensate and gas were estimated independent on t the feedstock due to similar elemental compositions. Pyrolysis gas analysis during the experiments gave information on the mass yields. A CO/CO2-ratio of 1 (i.e. wood) corresponds to organic condensate yields of about 50 wt.-%%, whereas a ratio of 0.3-0.7 (straw) corresponds to 18-32 wt. .-% respectively. Proceedings of the 20th European Biomass Conference and Exhibition, 18-22 June 2012, Milan, Italy, pp. 973-977

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  • Authors: Tröger, N.; Richter, D.; Stahl, R.;

    The project between tthe Deutsche Biomasseforschungszentrum (DBFZ) and the Karlsruhe Institute of Technology (KIT) focuses on the pr rovision of alternative fuels by thermochemical conversion. Biogenic residues and wastes which are not used yet or which could be utilised more efficiently are studied. The selection of possible feedstock was supported by a techhnical potential analysis including the competition to th he food industry. The technical suitability of raw materials for the fast pyrolysis (FP) process was of special in nterest. As a possible feedstock following types of biomass were studied: corn stover, corn cobs, biogenic floating re efuse (river Rhine and Baltic Sea), scrap wood, bark, rape s straw, sunflower straw, draff, diverse residues of flour production and hay. A process development unit (PDU) with a biomass feeding rate of 10 kg/h and a twin screw m mixer reactor was used for all experiments. It was found that different types of biomass form different char, condensate e and gas yields due to varying ash levels and lignocellulosic composition. Elemental formulas for feedstock, char, organic condensate and gas were estimated independent on t the feedstock due to similar elemental compositions. Pyrolysis gas analysis during the experiments gave information on the mass yields. A CO/CO2-ratio of 1 (i.e. wood) corresponds to organic condensate yields of about 50 wt.-%%, whereas a ratio of 0.3-0.7 (straw) corresponds to 18-32 wt. .-% respectively. Proceedings of the 20th European Biomass Conference and Exhibition, 18-22 June 2012, Milan, Italy, pp. 973-977

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Aaboud, M; Aad, G; Abbott, B; Abdallah, J; +196 Authors

    With the increase in energy of the Large Hadron Collider to a centre-of-mass energy of 13 TeV for Run 2, events with dense environments, such as in the cores of high-energy jets, became a focus for new physics searches as well as measurements of the Standard Model. These environments are characterized by charged-particle separations of the order of the tracking detectors sensor granularity. Basic track quantities are compared between 3.2 fb$^{-1}$ of data collected by the ATLAS experiment and simulation of proton-proton collisions producing high-transverse-momentum jets at a centre-of-mass energy of 13 TeV. The impact of charged-particle separations and multiplicities on the track reconstruction performance is discussed. The efficiency in the cores of jets with transverse momenta between 200 GeV and 1600 GeV is quantified using a novel, data-driven, method. The method uses the energy loss, dE/dx, to identify pixel clusters originating from two charged particles. Of the charged particles creating these clusters, the measured fraction that fail to be reconstructed is $0.061 \pm 0.006 \textrm{(stat.)} \pm 0.014 \textrm{(syst.)}$ and $0.093 \pm 0.017 \textrm{(stat.)}\pm 0.021 \textrm{(syst.)}$ for jet transverse momenta of 200-400 GeV and 1400-1600 GeV, respectively. The European physical journal / C 77(10), 673 (2017). doi:10.1140/epjc/s10052-017-5225-7 Published by Springer, Berlin

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    https://dx.doi.org/10.48550/ar...
    Article . 2017
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      PubMed Central
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      HAL-UPMC
      Article . 2017
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      HAL Clermont Université
      Article . 2017
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      HAL AMU
      Article . 2017
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      HAL-CEA
      Article . 2017
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      CERN Document Server
      Other literature type . 2017
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      https://dx.doi.org/10.48550/ar...
      Article . 2017
      License: arXiv Non-Exclusive Distribution
      Data sources: Datacite
      addClaim

      This Research product is the result of merged Research products in OpenAIRE.

      You have already added works in your ORCID record related to the merged Research product.
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    Authors: Aaboud, M; Aad, G; Abbott, B; Abdallah, J; +196 Authors

    With the increase in energy of the Large Hadron Collider to a centre-of-mass energy of 13 TeV for Run 2, events with dense environments, such as in the cores of high-energy jets, became a focus for new physics searches as well as measurements of the Standard Model. These environments are characterized by charged-particle separations of the order of the tracking detectors sensor granularity. Basic track quantities are compared between 3.2 fb$^{-1}$ of data collected by the ATLAS experiment and simulation of proton-proton collisions producing high-transverse-momentum jets at a centre-of-mass energy of 13 TeV. The impact of charged-particle separations and multiplicities on the track reconstruction performance is discussed. The efficiency in the cores of jets with transverse momenta between 200 GeV and 1600 GeV is quantified using a novel, data-driven, method. The method uses the energy loss, dE/dx, to identify pixel clusters originating from two charged particles. Of the charged particles creating these clusters, the measured fraction that fail to be reconstructed is $0.061 \pm 0.006 \textrm{(stat.)} \pm 0.014 \textrm{(syst.)}$ and $0.093 \pm 0.017 \textrm{(stat.)}\pm 0.021 \textrm{(syst.)}$ for jet transverse momenta of 200-400 GeV and 1400-1600 GeV, respectively. The European physical journal / C 77(10), 673 (2017). doi:10.1140/epjc/s10052-017-5225-7 Published by Springer, Berlin

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    CORE
    Article . 2017
    License: CC BY
    Data sources: CORE
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    PubMed Central
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    HAL-UPMC
    Article . 2017
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    HAL Clermont Université
    Article . 2017
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    HAL AMU
    Article . 2017
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    HAL-CEA
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      https://dx.doi.org/10.48550/ar...
      Article . 2017
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    Authors: Carriel-Schmitt, Caroline; Boscagli, Chiara; Rapp, Michael; Raffelt, Klaus; +1 Authors

    Bio-oil composition can differ depending on the biomass feedstock. Such information is essential if upgrading to a liquid fuel or to platform chemicals is intended. Furthermore, water and inorganic elements have to be taken into account for the catalyst selection. In this work, two bio-oils from wheat straw and beech wood were characterized by different techniques. Both were composed by a light and a heavy phase separately analyzed. The water content of the fractions differed over a wide range between 14.4 and 56.7 wt.% and therefore also the HHV (between 28.5 and 9.2 MJ/Kg). Both phases showed very low content of sulfur (<0.4 wt.%), which can have influence the lifetime of the catalyst. The 1H-NMR integration showed higher values in the regions of alkanes, carboxylic acid or keto-groups, and hetero-(aromatics) for both heavy phases, while light phases showed higher values in the water, O-H exchanging and carbohydrates region. So the heavy phases seem to be a good basis if phenols and its derivatives are expected and the light phases if alcohols are of interest. These results show that the bio-oils composition is essential for upgrading reactions, impacting on the products as well as on the choice of the catalyst. Proceedings of the 25th European Biomass Conference and Exhibition, 12-15 June 2017, Stockholm, Sweden, pp. 1143-1147

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    https://dx.doi.org/10.5071/25t...
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    Authors: Carriel-Schmitt, Caroline; Boscagli, Chiara; Rapp, Michael; Raffelt, Klaus; +1 Authors

    Bio-oil composition can differ depending on the biomass feedstock. Such information is essential if upgrading to a liquid fuel or to platform chemicals is intended. Furthermore, water and inorganic elements have to be taken into account for the catalyst selection. In this work, two bio-oils from wheat straw and beech wood were characterized by different techniques. Both were composed by a light and a heavy phase separately analyzed. The water content of the fractions differed over a wide range between 14.4 and 56.7 wt.% and therefore also the HHV (between 28.5 and 9.2 MJ/Kg). Both phases showed very low content of sulfur (<0.4 wt.%), which can have influence the lifetime of the catalyst. The 1H-NMR integration showed higher values in the regions of alkanes, carboxylic acid or keto-groups, and hetero-(aromatics) for both heavy phases, while light phases showed higher values in the water, O-H exchanging and carbohydrates region. So the heavy phases seem to be a good basis if phenols and its derivatives are expected and the light phases if alcohols are of interest. These results show that the bio-oils composition is essential for upgrading reactions, impacting on the products as well as on the choice of the catalyst. Proceedings of the 25th European Biomass Conference and Exhibition, 12-15 June 2017, Stockholm, Sweden, pp. 1143-1147

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao KITopen (Karlsruhe I...arrow_drop_down
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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    Authors: Pari, Luigi; Alfano, Vincenzo; Magagnini, Gianmaria; Grassi, Gianpaolo;

    This work, carried out at Research Centre for Industrial Crops of CREA in Rovigo, aimed at assessing the performance of a modified combine header and seed losses during late harvest of 5 hemp varieties. The renewed interest in Italy for hemp cultivation is aimed at seed production unlike the traditional cultivation aimed at fibre. However, it must face the lack of monoecious varieties suitable for Italian environment. In the case of dioecious varieties, traditionally cultivated in Italy for fibre production, the high crop height makes it difficult the mechanical harvesting with conventional combines. Similarly, the uneven height recorded in the case of imported varieties for seed production, requires adjusting continuously the height of the combine header. So, modified combine headers capable of be moved upwards and downwards by a lift have been developed. The aim is to avoid the risk of possible clogging of threshing apparatus introducing big pieces of stalks. Moreover, in this way, the stalks can be harvested separately in order to increase the income for farmers. In view of valorise the whole plant, as multipurpose crop, the right harvest time should be a trade-off between seed yield and fibre quality. Early harvesting guaranties a good fibre quality but causes also the harvest of seed not completely ripened. On the contrary delaying the harvest reduces the seed yield due to seed loss for dehiscence. In addition to losses for dehiscence prior to harvest, the trials aimed at distinguishing the loss incurred during harvest attributable both to crop disturbance by combine header and to the setting of the combine’s threshing and separation elements. Proceedings of the 28th European Biomass Conference and Exhibition, 6-9 July 2020, Virtual, pp. 197-200

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    Authors: Pari, Luigi; Alfano, Vincenzo; Magagnini, Gianmaria; Grassi, Gianpaolo;

    This work, carried out at Research Centre for Industrial Crops of CREA in Rovigo, aimed at assessing the performance of a modified combine header and seed losses during late harvest of 5 hemp varieties. The renewed interest in Italy for hemp cultivation is aimed at seed production unlike the traditional cultivation aimed at fibre. However, it must face the lack of monoecious varieties suitable for Italian environment. In the case of dioecious varieties, traditionally cultivated in Italy for fibre production, the high crop height makes it difficult the mechanical harvesting with conventional combines. Similarly, the uneven height recorded in the case of imported varieties for seed production, requires adjusting continuously the height of the combine header. So, modified combine headers capable of be moved upwards and downwards by a lift have been developed. The aim is to avoid the risk of possible clogging of threshing apparatus introducing big pieces of stalks. Moreover, in this way, the stalks can be harvested separately in order to increase the income for farmers. In view of valorise the whole plant, as multipurpose crop, the right harvest time should be a trade-off between seed yield and fibre quality. Early harvesting guaranties a good fibre quality but causes also the harvest of seed not completely ripened. On the contrary delaying the harvest reduces the seed yield due to seed loss for dehiscence. In addition to losses for dehiscence prior to harvest, the trials aimed at distinguishing the loss incurred during harvest attributable both to crop disturbance by combine header and to the setting of the combine’s threshing and separation elements. Proceedings of the 28th European Biomass Conference and Exhibition, 6-9 July 2020, Virtual, pp. 197-200

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    Authors: Wester, William; GammeV Collaboration;

    Proc. of Patras Workshop on Axions, WIMPs and WISPs, 68 - 71; DESY-PROC-2011-04; ISSN 1435-8077 Contribution to Proceedings

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    Authors: Wester, William; GammeV Collaboration;

    Proc. of Patras Workshop on Axions, WIMPs and WISPs, 68 - 71; DESY-PROC-2011-04; ISSN 1435-8077 Contribution to Proceedings

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  • Authors: Andreas, Marcus; Wagner, Felix;

    Ecovillages are arguably seen as "pioneers of change." Yet, thus far, little light has been shed on their potential to effect change beyond their own borders. This issue of RCC Perspectives presents a much needed overview of research on ecovillages, looking at the history and philosophy of utopias and presenting case studies and ongoing research from across the globe. It addresses whether ecovillages can serve as models for a cultural transformation, and shows how researchers and activists could and are collaborating in the quest for utopia, all the while inviting readers to explore what it means to live "the good life."

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  • Authors: Andreas, Marcus; Wagner, Felix;

    Ecovillages are arguably seen as "pioneers of change." Yet, thus far, little light has been shed on their potential to effect change beyond their own borders. This issue of RCC Perspectives presents a much needed overview of research on ecovillages, looking at the history and philosophy of utopias and presenting case studies and ongoing research from across the globe. It addresses whether ecovillages can serve as models for a cultural transformation, and shows how researchers and activists could and are collaborating in the quest for utopia, all the while inviting readers to explore what it means to live "the good life."

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    Authors: Dubey, Satya P.; Hrushikesh A. Abhyankar; Marchante, Veronica; Brighton, James L.; +1 Authors

    {"references": ["S. Jacobsen, H.-G. Fritz, P.Deg\u00e9e, P.Dubois, and R.J\u00e9r\u00f4me, \"Continuous\nreactive extrusion polymerisation of L-lactide \u2015 an engineering view,\"\nMacromol. Symp., vol. 153, no. 1, pp. 261\u2013273, 2000.", "K. Madhavan Nampoothiri, N. R. Nair, and R. P. John, \"An overview of\nthe recent developments in polylactide (PLA) research,\" Bioresour.\nTechnol., vol. 101, no. 22, pp. 8493\u20138501, Nov. 2010.", "P. Dubois, C. Jacobs, R. Jerome, and P. Teyssie, \"Macromolecular\nengineering of polylactones and polylactides. 4. Mechanism and kinetics\nof lactide homopolymerization by aluminum isopropoxide,\"\nMacromolecules, vol. 24, no. 9, pp. 2266\u20132270, Apr. 1991.", "D. R. Witzke, R. Narayan, and J. J. Kolstad, \"Reversible Kinetics and\nThermodynamics of the Homopolymerization of l-Lactide with 2-\nEthylhexanoic Acid Tin(II) Salt,\" Macromolecules, vol. 30, no. 23, pp.\n7075\u20137085, Nov. 1997.", "N. E. Kamber, W. Jeong, R. M. Waymouth, R. C. Pratt, B. G. G.\nLohmeijer, and J. L. Hedrick, \"Organocatalytic ring-opening\npolymerization,\" Chem. Rev., vol. 107, no. 12, pp. 5813\u20135840, 2007.", "W. Jeong, J. L. Hedrick, and R. M. Waymouth, \"Organic Spirocyclic\nInitiators for the Ring-Expansion Polymerization of \u03b2-Lactones,\" J. Am.\nChem. Soc., vol. 129, no. 27, pp. 8414\u20138415, Jul. 2007.", "M. Myers, E. F. Connor, T. Glauser, A. M\u00f6ck, G. Nyce, and J. L.\nHedrick, \"Phosphines: Nucleophilic organic catalysts for the controlled\nring-opening polymerization of lactides,\" J. Polym. Sci. Part Polym.\nChem., vol. 40, no. 7, pp. 844\u2013851, Apr. 2002.", "I. Ba\u015faran and A. Oral, \"Synthesis and Characterization of Poly(L-Lactic\nacid)/Clay Nanocomposite via Metal-Free Process,\" Polym.-Plast.\nTechnol. Eng., vol. 52, no. 12, pp. 1271\u20131276, 2013.", "\"InnoREX.\" (Online). Available: http://www.innorex.eu/about.php.\n[10] S. Jing, W. Peng, Z. Tong, and Z. Baoxiu, \"Microwave-irradiated ringopening\npolymerization of D,L-lactide under atmosphere,\" J. Appl.\nPolym. Sci., vol. 100, no. 3, pp. 2244\u20132247, May 2006.\n[11] P. Albert, H. Warth, R. M\u00fclhaupt, and R. Janda, \"Comparison of thermal\nand microwave-activated polymerization of \u03b5-caprolactone with titanium\ntetrabutylate as catalyst,\" Macromol. Chem. Phys., vol. 197, no. 5, pp.\n1633\u20131641, May 1996.\n[12] A. S\u00f6derg\u00e5rd and M. Stolt, \"Industrial Production of High Molecular\nWeight Poly(Lactic Acid),\" in Poly(Lactic Acid), R. Auras, L.-T. Lim,\nS. E. M. Selke, and H. Tsuji, Eds. John Wiley & Sons, Inc., 2010, pp.\n27\u201341.\n[13] R. Mehta, V. Kumar, and S. N. Upadhyay, \"Mathematical Modeling of\nthe Poly(lactic acid) Ring\u2013Opening Polymerization Kinetics,\" Polym.-\nPlast. Technol. Eng., vol. 46, no. 3, pp. 257\u2013264, 2007.\n[14] I. Banu, J.-P. Puaux, G. Bozga, and I. Nagy, \"Modeling of L-lactide\nPolymerization by Reactive Extrusion,\" Macromol. Symp., vol. 289, no.\n1, pp. 108\u2013118, 2010.\n[15] Y. Yu, G. Storti, and M. Morbidelli, \"Ring-Opening Polymerization of\nl,l-Lactide: Kinetic and Modeling Study,\" Macromolecules, vol. 42, no.\n21, pp. 8187\u20138197, Nov. 2009.\n[16] \"Compounding and extrusion - Fraunhofer ICT.\" (Online). Available:\nhttp://www.ict.fraunhofer.de/en/comp/pe/ce.html.\n[17] Y. Yu, G. Storti, and M. Morbidelli, \"Kinetics of Ring-Opening\nPolymerization of l,l-Lactide,\" Ind. Eng. Chem. Res., vol. 50, no. 13, pp.\n7927\u20137940, Jul. 2011.\n[18] L. J. Liu, C. Zhang, L. Q. Liao, X. L. Wang, and R. X. Zhuo,\n\"Microwave-assisted Polymerization of D, L-Lactide with Stannous\nOctanoate as Catalyst,\" Chin. Chem. Lett., vol. 12, no. 8, pp. 663\u2013664,\n2001.\n[19] M. Vukomanovi\u0107, M. Mitri\u0107, S. D. \u0160kapin, E. \u017dagar, J. Plavec, N.\nIgnjatovi\u0107, and D. Uskokovi\u0107, \"Influence of ultrasonic processing on the\nmacromolecular properties of poly (d,l-lactide-co-glycolide) alone and in\nits biocomposite with hydroxyapatite,\" Ultrason. Sonochem., vol. 17, no.\n5, pp. 902\u2013908, Jun. 2010.\n[20] C. Zhang, L. Liao, and L. Liu, \"Rapid Ring-Opening Polymerization of\nD,L-Lactide by Microwaves,\" Macromol. Rapid Commun., vol. 25, no.\n15, pp. 1402\u20131405, Aug. 2004.\n[21] \"Ludovic - Twin screw extrusion - SCConsultants.\" (Online). Available:\nhttp://www.scconsultants.com/en/ludovic-twin-screw-simulationsoftware.\nhtml..\n[22] \"Purac home.\" (Online). Available: http://www.purac.com/.\n[23] \"NatureWorks LLC Home Page.\" (Online). Available:\nhttp://www.natureworksllc.com/."]} PLA emerged as a promising polymer because of its property as a compostable, biodegradable thermoplastic made from renewable sources. PLA can be polymerized from monomers (Lactide or Lactic acid) obtained by fermentation processes from renewable sources such as corn starch or sugarcane. For PLA synthesis, ring opening polymerization (ROP) of Lactide monomer is one of the preferred methods. In the literature, the technique mainly developed for ROP of PLA is based on metal/bimetallic catalyst (Sn, Zn and Al) or other organic catalysts in suitable solvent. However, the PLA synthesized using such catalysts may contain trace elements of the catalyst which may cause toxicity. This work estimated the usefulness and drawbacks of using different catalysts as well as effect of alternative energies and future aspects for PLA production.

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    Authors: Dubey, Satya P.; Hrushikesh A. Abhyankar; Marchante, Veronica; Brighton, James L.; +1 Authors

    {"references": ["S. Jacobsen, H.-G. Fritz, P.Deg\u00e9e, P.Dubois, and R.J\u00e9r\u00f4me, \"Continuous\nreactive extrusion polymerisation of L-lactide \u2015 an engineering view,\"\nMacromol. Symp., vol. 153, no. 1, pp. 261\u2013273, 2000.", "K. Madhavan Nampoothiri, N. R. Nair, and R. P. John, \"An overview of\nthe recent developments in polylactide (PLA) research,\" Bioresour.\nTechnol., vol. 101, no. 22, pp. 8493\u20138501, Nov. 2010.", "P. Dubois, C. Jacobs, R. Jerome, and P. Teyssie, \"Macromolecular\nengineering of polylactones and polylactides. 4. Mechanism and kinetics\nof lactide homopolymerization by aluminum isopropoxide,\"\nMacromolecules, vol. 24, no. 9, pp. 2266\u20132270, Apr. 1991.", "D. R. Witzke, R. Narayan, and J. J. Kolstad, \"Reversible Kinetics and\nThermodynamics of the Homopolymerization of l-Lactide with 2-\nEthylhexanoic Acid Tin(II) Salt,\" Macromolecules, vol. 30, no. 23, pp.\n7075\u20137085, Nov. 1997.", "N. E. Kamber, W. Jeong, R. M. Waymouth, R. C. Pratt, B. G. G.\nLohmeijer, and J. L. Hedrick, \"Organocatalytic ring-opening\npolymerization,\" Chem. Rev., vol. 107, no. 12, pp. 5813\u20135840, 2007.", "W. Jeong, J. L. Hedrick, and R. M. Waymouth, \"Organic Spirocyclic\nInitiators for the Ring-Expansion Polymerization of \u03b2-Lactones,\" J. Am.\nChem. Soc., vol. 129, no. 27, pp. 8414\u20138415, Jul. 2007.", "M. Myers, E. F. Connor, T. Glauser, A. M\u00f6ck, G. Nyce, and J. L.\nHedrick, \"Phosphines: Nucleophilic organic catalysts for the controlled\nring-opening polymerization of lactides,\" J. Polym. Sci. Part Polym.\nChem., vol. 40, no. 7, pp. 844\u2013851, Apr. 2002.", "I. Ba\u015faran and A. Oral, \"Synthesis and Characterization of Poly(L-Lactic\nacid)/Clay Nanocomposite via Metal-Free Process,\" Polym.-Plast.\nTechnol. Eng., vol. 52, no. 12, pp. 1271\u20131276, 2013.", "\"InnoREX.\" (Online). Available: http://www.innorex.eu/about.php.\n[10] S. Jing, W. Peng, Z. Tong, and Z. Baoxiu, \"Microwave-irradiated ringopening\npolymerization of D,L-lactide under atmosphere,\" J. Appl.\nPolym. Sci., vol. 100, no. 3, pp. 2244\u20132247, May 2006.\n[11] P. Albert, H. Warth, R. M\u00fclhaupt, and R. Janda, \"Comparison of thermal\nand microwave-activated polymerization of \u03b5-caprolactone with titanium\ntetrabutylate as catalyst,\" Macromol. Chem. Phys., vol. 197, no. 5, pp.\n1633\u20131641, May 1996.\n[12] A. S\u00f6derg\u00e5rd and M. Stolt, \"Industrial Production of High Molecular\nWeight Poly(Lactic Acid),\" in Poly(Lactic Acid), R. Auras, L.-T. Lim,\nS. E. M. Selke, and H. Tsuji, Eds. John Wiley & Sons, Inc., 2010, pp.\n27\u201341.\n[13] R. Mehta, V. Kumar, and S. N. Upadhyay, \"Mathematical Modeling of\nthe Poly(lactic acid) Ring\u2013Opening Polymerization Kinetics,\" Polym.-\nPlast. Technol. Eng., vol. 46, no. 3, pp. 257\u2013264, 2007.\n[14] I. Banu, J.-P. Puaux, G. Bozga, and I. Nagy, \"Modeling of L-lactide\nPolymerization by Reactive Extrusion,\" Macromol. Symp., vol. 289, no.\n1, pp. 108\u2013118, 2010.\n[15] Y. Yu, G. Storti, and M. Morbidelli, \"Ring-Opening Polymerization of\nl,l-Lactide: Kinetic and Modeling Study,\" Macromolecules, vol. 42, no.\n21, pp. 8187\u20138197, Nov. 2009.\n[16] \"Compounding and extrusion - Fraunhofer ICT.\" (Online). Available:\nhttp://www.ict.fraunhofer.de/en/comp/pe/ce.html.\n[17] Y. Yu, G. Storti, and M. Morbidelli, \"Kinetics of Ring-Opening\nPolymerization of l,l-Lactide,\" Ind. Eng. Chem. Res., vol. 50, no. 13, pp.\n7927\u20137940, Jul. 2011.\n[18] L. J. Liu, C. Zhang, L. Q. Liao, X. L. Wang, and R. X. Zhuo,\n\"Microwave-assisted Polymerization of D, L-Lactide with Stannous\nOctanoate as Catalyst,\" Chin. Chem. Lett., vol. 12, no. 8, pp. 663\u2013664,\n2001.\n[19] M. Vukomanovi\u0107, M. Mitri\u0107, S. D. \u0160kapin, E. \u017dagar, J. Plavec, N.\nIgnjatovi\u0107, and D. Uskokovi\u0107, \"Influence of ultrasonic processing on the\nmacromolecular properties of poly (d,l-lactide-co-glycolide) alone and in\nits biocomposite with hydroxyapatite,\" Ultrason. Sonochem., vol. 17, no.\n5, pp. 902\u2013908, Jun. 2010.\n[20] C. Zhang, L. Liao, and L. Liu, \"Rapid Ring-Opening Polymerization of\nD,L-Lactide by Microwaves,\" Macromol. Rapid Commun., vol. 25, no.\n15, pp. 1402\u20131405, Aug. 2004.\n[21] \"Ludovic - Twin screw extrusion - SCConsultants.\" (Online). Available:\nhttp://www.scconsultants.com/en/ludovic-twin-screw-simulationsoftware.\nhtml..\n[22] \"Purac home.\" (Online). Available: http://www.purac.com/.\n[23] \"NatureWorks LLC Home Page.\" (Online). Available:\nhttp://www.natureworksllc.com/."]} PLA emerged as a promising polymer because of its property as a compostable, biodegradable thermoplastic made from renewable sources. PLA can be polymerized from monomers (Lactide or Lactic acid) obtained by fermentation processes from renewable sources such as corn starch or sugarcane. For PLA synthesis, ring opening polymerization (ROP) of Lactide monomer is one of the preferred methods. In the literature, the technique mainly developed for ROP of PLA is based on metal/bimetallic catalyst (Sn, Zn and Al) or other organic catalysts in suitable solvent. However, the PLA synthesized using such catalysts may contain trace elements of the catalyst which may cause toxicity. This work estimated the usefulness and drawbacks of using different catalysts as well as effect of alternative energies and future aspects for PLA production.

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    Authors: Opiyo, Francis, E.O.; Wasonga, Oliver, V.; Schilling, Janpeter; Mureithi, Stephen, M.;

    The theory of “resource scarcity” dominates the debate on “ecoviolence” in pastoral areas, where conflicts among communities have traditionally been linked to competition over scarce resources and invariably drought because of its role in resource depletion. However, the notion that climate change and resultant resource scarcity directly prompt violent conflict has been challenged by the notion that conflict actually coincide with periods of resource abundance. These contesting views point to nondeterministic linkage between resource availability and conflicts and, therefore, the complexity of pastoral conflicts. This is the scenario hypothesized for the vast pastoral areas of Kenya where violent conflict has become a chronic characteristic. While focusing on drought-induced conflicts over grazing resources, this paper takes cognizance of other factors that trigger and perpetuate violent conflicts in arid north-western Kenya. We present an insight on the nature, causes, dynamics and mitigation strategies of conflicts between the Turkana and Pokot pastoralists based on research study focusing on the linkages between resource availability and conflict. The findings suggest that violent conflicts in pastoral areas result from a myriad of socio-cultural, economic and political factors that reinforce one another by limiting availability of, depleting and reducing access to natural resource base. Competition for scarce natural resources triggered by frequent droughts and exacerbated by weak local institutions, proliferation of small firearms, political incitements, unclear property right regimes and cattle-raiding, was considered central to the violent conflicts observed in the area. The authors conclude that developing integrated policies and strengthening local governance institutions that are rooted in traditional practices for managing resources and inter-community conflicts is integral to the solution.

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    Authors: Opiyo, Francis, E.O.; Wasonga, Oliver, V.; Schilling, Janpeter; Mureithi, Stephen, M.;

    The theory of “resource scarcity” dominates the debate on “ecoviolence” in pastoral areas, where conflicts among communities have traditionally been linked to competition over scarce resources and invariably drought because of its role in resource depletion. However, the notion that climate change and resultant resource scarcity directly prompt violent conflict has been challenged by the notion that conflict actually coincide with periods of resource abundance. These contesting views point to nondeterministic linkage between resource availability and conflicts and, therefore, the complexity of pastoral conflicts. This is the scenario hypothesized for the vast pastoral areas of Kenya where violent conflict has become a chronic characteristic. While focusing on drought-induced conflicts over grazing resources, this paper takes cognizance of other factors that trigger and perpetuate violent conflicts in arid north-western Kenya. We present an insight on the nature, causes, dynamics and mitigation strategies of conflicts between the Turkana and Pokot pastoralists based on research study focusing on the linkages between resource availability and conflict. The findings suggest that violent conflicts in pastoral areas result from a myriad of socio-cultural, economic and political factors that reinforce one another by limiting availability of, depleting and reducing access to natural resource base. Competition for scarce natural resources triggered by frequent droughts and exacerbated by weak local institutions, proliferation of small firearms, political incitements, unclear property right regimes and cattle-raiding, was considered central to the violent conflicts observed in the area. The authors conclude that developing integrated policies and strengthening local governance institutions that are rooted in traditional practices for managing resources and inter-community conflicts is integral to the solution.

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  • Authors: Ding, Yang; Wang, Chunhua; Pei, Lang; Mao, Qinan; +7 Authors

    Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions, Mn4+ ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode (W-LED), plant cultivation LED, and temperature thermometer. Up to now, Mn4+ has been widely introduced into the lattices of various inorganic hosts for brightly red-emitting phosphors. However, how to correlate the structure-activity relationship between host framework, luminescence property, and photoelectric device is urgently demanded. In this review, we thoroughly summarize the recent advances of Mn4+ doped phosphors. Meanwhile, several strategies like co-doping and defect passivation for improving Mn4+ emission are also discussed. Most importantly, the relationship between the protocols for tailoring the structures of Mn4+ doped phosphors, increased luminescence performance, and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated. Finally, the challenges and perspectives of Mn4+ doped phosphors for practical applications are anticipated. We cordially anticipate that this review can deliver a deep comprehension of not only Mn4+ luminescence mechanism but also the crystal structure tailoring strategy of phosphors, so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.

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  • Authors: Ding, Yang; Wang, Chunhua; Pei, Lang; Mao, Qinan; +7 Authors

    Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions, Mn4+ ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode (W-LED), plant cultivation LED, and temperature thermometer. Up to now, Mn4+ has been widely introduced into the lattices of various inorganic hosts for brightly red-emitting phosphors. However, how to correlate the structure-activity relationship between host framework, luminescence property, and photoelectric device is urgently demanded. In this review, we thoroughly summarize the recent advances of Mn4+ doped phosphors. Meanwhile, several strategies like co-doping and defect passivation for improving Mn4+ emission are also discussed. Most importantly, the relationship between the protocols for tailoring the structures of Mn4+ doped phosphors, increased luminescence performance, and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated. Finally, the challenges and perspectives of Mn4+ doped phosphors for practical applications are anticipated. We cordially anticipate that this review can deliver a deep comprehension of not only Mn4+ luminescence mechanism but also the crystal structure tailoring strategy of phosphors, so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.

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  • Authors: Dieter Sell; M. M. W. Etschmann; Jens Schrader;

    Fourteen yeast strains were screened for production of 2-phenylethanol from L-phenylalanine with molasses as carbon source. Up to 1 g 2-phenylethanol l-1 was obtained. Using oleyl alcohol as a second phase for in situ product removal to enhance the production of 2-phenylethanol increased the yield to about 3 g 2-phenylethanol l-1 at 35 degrees C. The most productive strains were Kluyveromyces marxianus CBS 600 and CBS 397.

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  • Authors: Dieter Sell; M. M. W. Etschmann; Jens Schrader;

    Fourteen yeast strains were screened for production of 2-phenylethanol from L-phenylalanine with molasses as carbon source. Up to 1 g 2-phenylethanol l-1 was obtained. Using oleyl alcohol as a second phase for in situ product removal to enhance the production of 2-phenylethanol increased the yield to about 3 g 2-phenylethanol l-1 at 35 degrees C. The most productive strains were Kluyveromyces marxianus CBS 600 and CBS 397.

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  • Authors: Tröger, N.; Richter, D.; Stahl, R.;

    The project between tthe Deutsche Biomasseforschungszentrum (DBFZ) and the Karlsruhe Institute of Technology (KIT) focuses on the pr rovision of alternative fuels by thermochemical conversion. Biogenic residues and wastes which are not used yet or which could be utilised more efficiently are studied. The selection of possible feedstock was supported by a techhnical potential analysis including the competition to th he food industry. The technical suitability of raw materials for the fast pyrolysis (FP) process was of special in nterest. As a possible feedstock following types of biomass were studied: corn stover, corn cobs, biogenic floating re efuse (river Rhine and Baltic Sea), scrap wood, bark, rape s straw, sunflower straw, draff, diverse residues of flour production and hay. A process development unit (PDU) with a biomass feeding rate of 10 kg/h and a twin screw m mixer reactor was used for all experiments. It was found that different types of biomass form different char, condensate e and gas yields due to varying ash levels and lignocellulosic composition. Elemental formulas for feedstock, char, organic condensate and gas were estimated independent on t the feedstock due to similar elemental compositions. Pyrolysis gas analysis during the experiments gave information on the mass yields. A CO/CO2-ratio of 1 (i.e. wood) corresponds to organic condensate yields of about 50 wt.-%%, whereas a ratio of 0.3-0.7 (straw) corresponds to 18-32 wt. .-% respectively. Proceedings of the 20th European Biomass Conference and Exhibition, 18-22 June 2012, Milan, Italy, pp. 973-977

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  • Authors: Tröger, N.; Richter, D.; Stahl, R.;

    The project between tthe Deutsche Biomasseforschungszentrum (DBFZ) and the Karlsruhe Institute of Technology (KIT) focuses on the pr rovision of alternative fuels by thermochemical conversion. Biogenic residues and wastes which are not used yet or which could be utilised more efficiently are studied. The selection of possible feedstock was supported by a techhnical potential analysis including the competition to th he food industry. The technical suitability of raw materials for the fast pyrolysis (FP) process was of special in nterest. As a possible feedstock following types of biomass were studied: corn stover, corn cobs, biogenic floating re efuse (river Rhine and Baltic Sea), scrap wood, bark, rape s straw, sunflower straw, draff, diverse residues of flour production and hay. A process development unit (PDU) with a biomass feeding rate of 10 kg/h and a twin screw m mixer reactor was used for all experiments. It was found that different types of biomass form different char, condensate e and gas yields due to varying ash levels and lignocellulosic composition. Elemental formulas for feedstock, char, organic condensate and gas were estimated independent on t the feedstock due to similar elemental compositions. Pyrolysis gas analysis during the experiments gave information on the mass yields. A CO/CO2-ratio of 1 (i.e. wood) corresponds to organic condensate yields of about 50 wt.-%%, whereas a ratio of 0.3-0.7 (straw) corresponds to 18-32 wt. .-% respectively. Proceedings of the 20th European Biomass Conference and Exhibition, 18-22 June 2012, Milan, Italy, pp. 973-977

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    Authors: Aaboud, M; Aad, G; Abbott, B; Abdallah, J; +196 Authors

    With the increase in energy of the Large Hadron Collider to a centre-of-mass energy of 13 TeV for Run 2, events with dense environments, such as in the cores of high-energy jets, became a focus for new physics searches as well as measurements of the Standard Model. These environments are characterized by charged-particle separations of the order of the tracking detectors sensor granularity. Basic track quantities are compared between 3.2 fb$^{-1}$ of data collected by the ATLAS experiment and simulation of proton-proton collisions producing high-transverse-momentum jets at a centre-of-mass energy of 13 TeV. The impact of charged-particle separations and multiplicities on the track reconstruction performance is discussed. The efficiency in the cores of jets with transverse momenta between 200 GeV and 1600 GeV is quantified using a novel, data-driven, method. The method uses the energy loss, dE/dx, to identify pixel clusters originating from two charged particles. Of the charged particles creating these clusters, the measured fraction that fail to be reconstructed is $0.061 \pm 0.006 \textrm{(stat.)} \pm 0.014 \textrm{(syst.)}$ and $0.093 \pm 0.017 \textrm{(stat.)}\pm 0.021 \textrm{(syst.)}$ for jet transverse momenta of 200-400 GeV and 1400-1600 GeV, respectively. The European physical journal / C 77(10), 673 (2017). doi:10.1140/epjc/s10052-017-5225-7 Published by Springer, Berlin

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      https://dx.doi.org/10.48550/ar...
      Article . 2017
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Aaboud, M; Aad, G; Abbott, B; Abdallah, J; +196 Authors

    With the increase in energy of the Large Hadron Collider to a centre-of-mass energy of 13 TeV for Run 2, events with dense environments, such as in the cores of high-energy jets, became a focus for new physics searches as well as measurements of the Standard Model. These environments are characterized by charged-particle separations of the order of the tracking detectors sensor granularity. Basic track quantities are compared between 3.2 fb$^{-1}$ of data collected by the ATLAS experiment and simulation of proton-proton collisions producing high-transverse-momentum jets at a centre-of-mass energy of 13 TeV. The impact of charged-particle separations and multiplicities on the track reconstruction performance is discussed. The efficiency in the cores of jets with transverse momenta between 200 GeV and 1600 GeV is quantified using a novel, data-driven, method. The method uses the energy loss, dE/dx, to identify pixel clusters originating from two charged particles. Of the charged particles creating these clusters, the measured fraction that fail to be reconstructed is $0.061 \pm 0.006 \textrm{(stat.)} \pm 0.014 \textrm{(syst.)}$ and $0.093 \pm 0.017 \textrm{(stat.)}\pm 0.021 \textrm{(syst.)}$ for jet transverse momenta of 200-400 GeV and 1400-1600 GeV, respectively. The European physical journal / C 77(10), 673 (2017). doi:10.1140/epjc/s10052-017-5225-7 Published by Springer, Berlin

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    CORE
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    https://dx.doi.org/10.48550/ar...
    Article . 2017
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      CORE
      Article . 2017
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      Data sources: CORE
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      PubMed Central
      Other literature type . 2017
      Data sources: PubMed Central
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      HAL-UPMC
      Article . 2017
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      HAL Clermont Université
      Article . 2017
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      HAL AMU
      Article . 2017
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      HAL-CEA
      Article . 2017
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      CERN Document Server
      Other literature type . 2017
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      https://dx.doi.org/10.48550/ar...
      Article . 2017
      License: arXiv Non-Exclusive Distribution
      Data sources: Datacite
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Carriel-Schmitt, Caroline; Boscagli, Chiara; Rapp, Michael; Raffelt, Klaus; +1 Authors

    Bio-oil composition can differ depending on the biomass feedstock. Such information is essential if upgrading to a liquid fuel or to platform chemicals is intended. Furthermore, water and inorganic elements have to be taken into account for the catalyst selection. In this work, two bio-oils from wheat straw and beech wood were characterized by different techniques. Both were composed by a light and a heavy phase separately analyzed. The water content of the fractions differed over a wide range between 14.4 and 56.7 wt.% and therefore also the HHV (between 28.5 and 9.2 MJ/Kg). Both phases showed very low content of sulfur (<0.4 wt.%), which can have influence the lifetime of the catalyst. The 1H-NMR integration showed higher values in the regions of alkanes, carboxylic acid or keto-groups, and hetero-(aromatics) for both heavy phases, while light phases showed higher values in the water, O-H exchanging and carbohydrates region. So the heavy phases seem to be a good basis if phenols and its derivatives are expected and the light phases if alcohols are of interest. These results show that the bio-oils composition is essential for upgrading reactions, impacting on the products as well as on the choice of the catalyst. Proceedings of the 25th European Biomass Conference and Exhibition, 12-15 June 2017, Stockholm, Sweden, pp. 1143-1147

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao KITopen (Karlsruhe I...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    https://dx.doi.org/10.5071/25t...
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      https://dx.doi.org/10.5071/25t...
      Conference object . 2017
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Carriel-Schmitt, Caroline; Boscagli, Chiara; Rapp, Michael; Raffelt, Klaus; +1 Authors

    Bio-oil composition can differ depending on the biomass feedstock. Such information is essential if upgrading to a liquid fuel or to platform chemicals is intended. Furthermore, water and inorganic elements have to be taken into account for the catalyst selection. In this work, two bio-oils from wheat straw and beech wood were characterized by different techniques. Both were composed by a light and a heavy phase separately analyzed. The water content of the fractions differed over a wide range between 14.4 and 56.7 wt.% and therefore also the HHV (between 28.5 and 9.2 MJ/Kg). Both phases showed very low content of sulfur (<0.4 wt.%), which can have influence the lifetime of the catalyst. The 1H-NMR integration showed higher values in the regions of alkanes, carboxylic acid or keto-groups, and hetero-(aromatics) for both heavy phases, while light phases showed higher values in the water, O-H exchanging and carbohydrates region. So the heavy phases seem to be a good basis if phenols and its derivatives are expected and the light phases if alcohols are of interest. These results show that the bio-oils composition is essential for upgrading reactions, impacting on the products as well as on the choice of the catalyst. Proceedings of the 25th European Biomass Conference and Exhibition, 12-15 June 2017, Stockholm, Sweden, pp. 1143-1147

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao KITopen (Karlsruhe I...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    https://dx.doi.org/10.5071/25t...
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao KITopen (Karlsruhe I...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      https://dx.doi.org/10.5071/25t...
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Pari, Luigi; Alfano, Vincenzo; Magagnini, Gianmaria; Grassi, Gianpaolo;

    This work, carried out at Research Centre for Industrial Crops of CREA in Rovigo, aimed at assessing the performance of a modified combine header and seed losses during late harvest of 5 hemp varieties. The renewed interest in Italy for hemp cultivation is aimed at seed production unlike the traditional cultivation aimed at fibre. However, it must face the lack of monoecious varieties suitable for Italian environment. In the case of dioecious varieties, traditionally cultivated in Italy for fibre production, the high crop height makes it difficult the mechanical harvesting with conventional combines. Similarly, the uneven height recorded in the case of imported varieties for seed production, requires adjusting continuously the height of the combine header. So, modified combine headers capable of be moved upwards and downwards by a lift have been developed. The aim is to avoid the risk of possible clogging of threshing apparatus introducing big pieces of stalks. Moreover, in this way, the stalks can be harvested separately in order to increase the income for farmers. In view of valorise the whole plant, as multipurpose crop, the right harvest time should be a trade-off between seed yield and fibre quality. Early harvesting guaranties a good fibre quality but causes also the harvest of seed not completely ripened. On the contrary delaying the harvest reduces the seed yield due to seed loss for dehiscence. In addition to losses for dehiscence prior to harvest, the trials aimed at distinguishing the loss incurred during harvest attributable both to crop disturbance by combine header and to the setting of the combine’s threshing and separation elements. Proceedings of the 28th European Biomass Conference and Exhibition, 6-9 July 2020, Virtual, pp. 197-200

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ ZENODOarrow_drop_down
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    ZENODO
    Article . 2020
    License: CC BY
    Data sources: Datacite
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    ZENODO
    Other literature type . 2020
    License: CC BY
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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    Article . 2020
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    https://dx.doi.org/10.5071/28t...
    Conference object . 2020
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      Article . 2020
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    Authors: Pari, Luigi; Alfano, Vincenzo; Magagnini, Gianmaria; Grassi, Gianpaolo;

    This work, carried out at Research Centre for Industrial Crops of CREA in Rovigo, aimed at assessing the performance of a modified combine header and seed losses during late harvest of 5 hemp varieties. The renewed interest in Italy for hemp cultivation is aimed at seed production unlike the traditional cultivation aimed at fibre. However, it must face the lack of monoecious varieties suitable for Italian environment. In the case of dioecious varieties, traditionally cultivated in Italy for fibre production, the high crop height makes it difficult the mechanical harvesting with conventional combines. Similarly, the uneven height recorded in the case of imported varieties for seed production, requires adjusting continuously the height of the combine header. So, modified combine headers capable of be moved upwards and downwards by a lift have been developed. The aim is to avoid the risk of possible clogging of threshing apparatus introducing big pieces of stalks. Moreover, in this way, the stalks can be harvested separately in order to increase the income for farmers. In view of valorise the whole plant, as multipurpose crop, the right harvest time should be a trade-off between seed yield and fibre quality. Early harvesting guaranties a good fibre quality but causes also the harvest of seed not completely ripened. On the contrary delaying the harvest reduces the seed yield due to seed loss for dehiscence. In addition to losses for dehiscence prior to harvest, the trials aimed at distinguishing the loss incurred during harvest attributable both to crop disturbance by combine header and to the setting of the combine’s threshing and separation elements. Proceedings of the 28th European Biomass Conference and Exhibition, 6-9 July 2020, Virtual, pp. 197-200

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    Authors: Wester, William; GammeV Collaboration;

    Proc. of Patras Workshop on Axions, WIMPs and WISPs, 68 - 71; DESY-PROC-2011-04; ISSN 1435-8077 Contribution to Proceedings

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    Authors: Wester, William; GammeV Collaboration;

    Proc. of Patras Workshop on Axions, WIMPs and WISPs, 68 - 71; DESY-PROC-2011-04; ISSN 1435-8077 Contribution to Proceedings

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  • Authors: Andreas, Marcus; Wagner, Felix;

    Ecovillages are arguably seen as "pioneers of change." Yet, thus far, little light has been shed on their potential to effect change beyond their own borders. This issue of RCC Perspectives presents a much needed overview of research on ecovillages, looking at the history and philosophy of utopias and presenting case studies and ongoing research from across the globe. It addresses whether ecovillages can serve as models for a cultural transformation, and shows how researchers and activists could and are collaborating in the quest for utopia, all the while inviting readers to explore what it means to live "the good life."

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  • Authors: Andreas, Marcus; Wagner, Felix;

    Ecovillages are arguably seen as "pioneers of change." Yet, thus far, little light has been shed on their potential to effect change beyond their own borders. This issue of RCC Perspectives presents a much needed overview of research on ecovillages, looking at the history and philosophy of utopias and presenting case studies and ongoing research from across the globe. It addresses whether ecovillages can serve as models for a cultural transformation, and shows how researchers and activists could and are collaborating in the quest for utopia, all the while inviting readers to explore what it means to live "the good life."

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    Authors: Dubey, Satya P.; Hrushikesh A. Abhyankar; Marchante, Veronica; Brighton, James L.; +1 Authors

    {"references": ["S. Jacobsen, H.-G. Fritz, P.Deg\u00e9e, P.Dubois, and R.J\u00e9r\u00f4me, \"Continuous\nreactive extrusion polymerisation of L-lactide \u2015 an engineering view,\"\nMacromol. Symp., vol. 153, no. 1, pp. 261\u2013273, 2000.", "K. Madhavan Nampoothiri, N. R. Nair, and R. P. John, \"An overview of\nthe recent developments in polylactide (PLA) research,\" Bioresour.\nTechnol., vol. 101, no. 22, pp. 8493\u20138501, Nov. 2010.", "P. Dubois, C. Jacobs, R. Jerome, and P. Teyssie, \"Macromolecular\nengineering of polylactones and polylactides. 4. Mechanism and kinetics\nof lactide homopolymerization by aluminum isopropoxide,\"\nMacromolecules, vol. 24, no. 9, pp. 2266\u20132270, Apr. 1991.", "D. R. Witzke, R. Narayan, and J. J. Kolstad, \"Reversible Kinetics and\nThermodynamics of the Homopolymerization of l-Lactide with 2-\nEthylhexanoic Acid Tin(II) Salt,\" Macromolecules, vol. 30, no. 23, pp.\n7075\u20137085, Nov. 1997.", "N. E. Kamber, W. Jeong, R. M. Waymouth, R. C. Pratt, B. G. G.\nLohmeijer, and J. L. Hedrick, \"Organocatalytic ring-opening\npolymerization,\" Chem. Rev., vol. 107, no. 12, pp. 5813\u20135840, 2007.", "W. Jeong, J. L. Hedrick, and R. M. Waymouth, \"Organic Spirocyclic\nInitiators for the Ring-Expansion Polymerization of \u03b2-Lactones,\" J. Am.\nChem. Soc., vol. 129, no. 27, pp. 8414\u20138415, Jul. 2007.", "M. Myers, E. F. Connor, T. Glauser, A. M\u00f6ck, G. Nyce, and J. L.\nHedrick, \"Phosphines: Nucleophilic organic catalysts for the controlled\nring-opening polymerization of lactides,\" J. Polym. Sci. Part Polym.\nChem., vol. 40, no. 7, pp. 844\u2013851, Apr. 2002.", "I. Ba\u015faran and A. Oral, \"Synthesis and Characterization of Poly(L-Lactic\nacid)/Clay Nanocomposite via Metal-Free Process,\" Polym.-Plast.\nTechnol. Eng., vol. 52, no. 12, pp. 1271\u20131276, 2013.", "\"InnoREX.\" (Online). Available: http://www.innorex.eu/about.php.\n[10] S. Jing, W. Peng, Z. Tong, and Z. Baoxiu, \"Microwave-irradiated ringopening\npolymerization of D,L-lactide under atmosphere,\" J. Appl.\nPolym. Sci., vol. 100, no. 3, pp. 2244\u20132247, May 2006.\n[11] P. Albert, H. Warth, R. M\u00fclhaupt, and R. Janda, \"Comparison of thermal\nand microwave-activated polymerization of \u03b5-caprolactone with titanium\ntetrabutylate as catalyst,\" Macromol. Chem. Phys., vol. 197, no. 5, pp.\n1633\u20131641, May 1996.\n[12] A. S\u00f6derg\u00e5rd and M. Stolt, \"Industrial Production of High Molecular\nWeight Poly(Lactic Acid),\" in Poly(Lactic Acid), R. Auras, L.-T. Lim,\nS. E. M. Selke, and H. Tsuji, Eds. John Wiley & Sons, Inc., 2010, pp.\n27\u201341.\n[13] R. Mehta, V. Kumar, and S. N. Upadhyay, \"Mathematical Modeling of\nthe Poly(lactic acid) Ring\u2013Opening Polymerization Kinetics,\" Polym.-\nPlast. Technol. Eng., vol. 46, no. 3, pp. 257\u2013264, 2007.\n[14] I. Banu, J.-P. Puaux, G. Bozga, and I. Nagy, \"Modeling of L-lactide\nPolymerization by Reactive Extrusion,\" Macromol. Symp., vol. 289, no.\n1, pp. 108\u2013118, 2010.\n[15] Y. Yu, G. Storti, and M. Morbidelli, \"Ring-Opening Polymerization of\nl,l-Lactide: Kinetic and Modeling Study,\" Macromolecules, vol. 42, no.\n21, pp. 8187\u20138197, Nov. 2009.\n[16] \"Compounding and extrusion - Fraunhofer ICT.\" (Online). Available:\nhttp://www.ict.fraunhofer.de/en/comp/pe/ce.html.\n[17] Y. Yu, G. Storti, and M. Morbidelli, \"Kinetics of Ring-Opening\nPolymerization of l,l-Lactide,\" Ind. Eng. Chem. Res., vol. 50, no. 13, pp.\n7927\u20137940, Jul. 2011.\n[18] L. J. Liu, C. Zhang, L. Q. Liao, X. L. Wang, and R. X. Zhuo,\n\"Microwave-assisted Polymerization of D, L-Lactide with Stannous\nOctanoate as Catalyst,\" Chin. Chem. Lett., vol. 12, no. 8, pp. 663\u2013664,\n2001.\n[19] M. Vukomanovi\u0107, M. Mitri\u0107, S. D. \u0160kapin, E. \u017dagar, J. Plavec, N.\nIgnjatovi\u0107, and D. Uskokovi\u0107, \"Influence of ultrasonic processing on the\nmacromolecular properties of poly (d,l-lactide-co-glycolide) alone and in\nits biocomposite with hydroxyapatite,\" Ultrason. Sonochem., vol. 17, no.\n5, pp. 902\u2013908, Jun. 2010.\n[20] C. Zhang, L. Liao, and L. Liu, \"Rapid Ring-Opening Polymerization of\nD,L-Lactide by Microwaves,\" Macromol. Rapid Commun., vol. 25, no.\n15, pp. 1402\u20131405, Aug. 2004.\n[21] \"Ludovic - Twin screw extrusion - SCConsultants.\" (Online). Available:\nhttp://www.scconsultants.com/en/ludovic-twin-screw-simulationsoftware.\nhtml..\n[22] \"Purac home.\" (Online). Available: http://www.purac.com/.\n[23] \"NatureWorks LLC Home Page.\" (Online). Available:\nhttp://www.natureworksllc.com/."]} PLA emerged as a promising polymer because of its property as a compostable, biodegradable thermoplastic made from renewable sources. PLA can be polymerized from monomers (Lactide or Lactic acid) obtained by fermentation processes from renewable sources such as corn starch or sugarcane. For PLA synthesis, ring opening polymerization (ROP) of Lactide monomer is one of the preferred methods. In the literature, the technique mainly developed for ROP of PLA is based on metal/bimetallic catalyst (Sn, Zn and Al) or other organic catalysts in suitable solvent. However, the PLA synthesized using such catalysts may contain trace elements of the catalyst which may cause toxicity. This work estimated the usefulness and drawbacks of using different catalysts as well as effect of alternative energies and future aspects for PLA production.

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    Authors: Dubey, Satya P.; Hrushikesh A. Abhyankar; Marchante, Veronica; Brighton, James L.; +1 Authors

    {"references": ["S. Jacobsen, H.-G. Fritz, P.Deg\u00e9e, P.Dubois, and R.J\u00e9r\u00f4me, \"Continuous\nreactive extrusion polymerisation of L-lactide \u2015 an engineering view,\"\nMacromol. Symp., vol. 153, no. 1, pp. 261\u2013273, 2000.", "K. Madhavan Nampoothiri, N. R. Nair, and R. P. John, \"An overview of\nthe recent developments in polylactide (PLA) research,\" Bioresour.\nTechnol., vol. 101, no. 22, pp. 8493\u20138501, Nov. 2010.", "P. Dubois, C. Jacobs, R. Jerome, and P. Teyssie, \"Macromolecular\nengineering of polylactones and polylactides. 4. Mechanism and kinetics\nof lactide homopolymerization by aluminum isopropoxide,\"\nMacromolecules, vol. 24, no. 9, pp. 2266\u20132270, Apr. 1991.", "D. R. Witzke, R. Narayan, and J. J. Kolstad, \"Reversible Kinetics and\nThermodynamics of the Homopolymerization of l-Lactide with 2-\nEthylhexanoic Acid Tin(II) Salt,\" Macromolecules, vol. 30, no. 23, pp.\n7075\u20137085, Nov. 1997.", "N. E. Kamber, W. Jeong, R. M. Waymouth, R. C. Pratt, B. G. G.\nLohmeijer, and J. L. Hedrick, \"Organocatalytic ring-opening\npolymerization,\" Chem. Rev., vol. 107, no. 12, pp. 5813\u20135840, 2007.", "W. Jeong, J. L. Hedrick, and R. M. Waymouth, \"Organic Spirocyclic\nInitiators for the Ring-Expansion Polymerization of \u03b2-Lactones,\" J. Am.\nChem. Soc., vol. 129, no. 27, pp. 8414\u20138415, Jul. 2007.", "M. Myers, E. F. Connor, T. Glauser, A. M\u00f6ck, G. Nyce, and J. L.\nHedrick, \"Phosphines: Nucleophilic organic catalysts for the controlled\nring-opening polymerization of lactides,\" J. Polym. Sci. Part Polym.\nChem., vol. 40, no. 7, pp. 844\u2013851, Apr. 2002.", "I. Ba\u015faran and A. Oral, \"Synthesis and Characterization of Poly(L-Lactic\nacid)/Clay Nanocomposite via Metal-Free Process,\" Polym.-Plast.\nTechnol. Eng., vol. 52, no. 12, pp. 1271\u20131276, 2013.", "\"InnoREX.\" (Online). Available: http://www.innorex.eu/about.php.\n[10] S. Jing, W. Peng, Z. Tong, and Z. Baoxiu, \"Microwave-irradiated ringopening\npolymerization of D,L-lactide under atmosphere,\" J. Appl.\nPolym. Sci., vol. 100, no. 3, pp. 2244\u20132247, May 2006.\n[11] P. Albert, H. Warth, R. M\u00fclhaupt, and R. Janda, \"Comparison of thermal\nand microwave-activated polymerization of \u03b5-caprolactone with titanium\ntetrabutylate as catalyst,\" Macromol. Chem. Phys., vol. 197, no. 5, pp.\n1633\u20131641, May 1996.\n[12] A. S\u00f6derg\u00e5rd and M. Stolt, \"Industrial Production of High Molecular\nWeight Poly(Lactic Acid),\" in Poly(Lactic Acid), R. Auras, L.-T. Lim,\nS. E. M. Selke, and H. Tsuji, Eds. John Wiley & Sons, Inc., 2010, pp.\n27\u201341.\n[13] R. Mehta, V. Kumar, and S. N. Upadhyay, \"Mathematical Modeling of\nthe Poly(lactic acid) Ring\u2013Opening Polymerization Kinetics,\" Polym.-\nPlast. Technol. Eng., vol. 46, no. 3, pp. 257\u2013264, 2007.\n[14] I. Banu, J.-P. Puaux, G. Bozga, and I. Nagy, \"Modeling of L-lactide\nPolymerization by Reactive Extrusion,\" Macromol. Symp., vol. 289, no.\n1, pp. 108\u2013118, 2010.\n[15] Y. Yu, G. Storti, and M. Morbidelli, \"Ring-Opening Polymerization of\nl,l-Lactide: Kinetic and Modeling Study,\" Macromolecules, vol. 42, no.\n21, pp. 8187\u20138197, Nov. 2009.\n[16] \"Compounding and extrusion - Fraunhofer ICT.\" (Online). Available:\nhttp://www.ict.fraunhofer.de/en/comp/pe/ce.html.\n[17] Y. Yu, G. Storti, and M. Morbidelli, \"Kinetics of Ring-Opening\nPolymerization of l,l-Lactide,\" Ind. Eng. Chem. Res., vol. 50, no. 13, pp.\n7927\u20137940, Jul. 2011.\n[18] L. J. Liu, C. Zhang, L. Q. Liao, X. L. Wang, and R. X. Zhuo,\n\"Microwave-assisted Polymerization of D, L-Lactide with Stannous\nOctanoate as Catalyst,\" Chin. Chem. Lett., vol. 12, no. 8, pp. 663\u2013664,\n2001.\n[19] M. Vukomanovi\u0107, M. Mitri\u0107, S. D. \u0160kapin, E. \u017dagar, J. Plavec, N.\nIgnjatovi\u0107, and D. Uskokovi\u0107, \"Influence of ultrasonic processing on the\nmacromolecular properties of poly (d,l-lactide-co-glycolide) alone and in\nits biocomposite with hydroxyapatite,\" Ultrason. Sonochem., vol. 17, no.\n5, pp. 902\u2013908, Jun. 2010.\n[20] C. Zhang, L. Liao, and L. Liu, \"Rapid Ring-Opening Polymerization of\nD,L-Lactide by Microwaves,\" Macromol. Rapid Commun., vol. 25, no.\n15, pp. 1402\u20131405, Aug. 2004.\n[21] \"Ludovic - Twin screw extrusion - SCConsultants.\" (Online). Available:\nhttp://www.scconsultants.com/en/ludovic-twin-screw-simulationsoftware.\nhtml..\n[22] \"Purac home.\" (Online). Available: http://www.purac.com/.\n[23] \"NatureWorks LLC Home Page.\" (Online). Available:\nhttp://www.natureworksllc.com/."]} PLA emerged as a promising polymer because of its property as a compostable, biodegradable thermoplastic made from renewable sources. PLA can be polymerized from monomers (Lactide or Lactic acid) obtained by fermentation processes from renewable sources such as corn starch or sugarcane. For PLA synthesis, ring opening polymerization (ROP) of Lactide monomer is one of the preferred methods. In the literature, the technique mainly developed for ROP of PLA is based on metal/bimetallic catalyst (Sn, Zn and Al) or other organic catalysts in suitable solvent. However, the PLA synthesized using such catalysts may contain trace elements of the catalyst which may cause toxicity. This work estimated the usefulness and drawbacks of using different catalysts as well as effect of alternative energies and future aspects for PLA production.

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    Authors: Opiyo, Francis, E.O.; Wasonga, Oliver, V.; Schilling, Janpeter; Mureithi, Stephen, M.;

    The theory of “resource scarcity” dominates the debate on “ecoviolence” in pastoral areas, where conflicts among communities have traditionally been linked to competition over scarce resources and invariably drought because of its role in resource depletion. However, the notion that climate change and resultant resource scarcity directly prompt violent conflict has been challenged by the notion that conflict actually coincide with periods of resource abundance. These contesting views point to nondeterministic linkage between resource availability and conflicts and, therefore, the complexity of pastoral conflicts. This is the scenario hypothesized for the vast pastoral areas of Kenya where violent conflict has become a chronic characteristic. While focusing on drought-induced conflicts over grazing resources, this paper takes cognizance of other factors that trigger and perpetuate violent conflicts in arid north-western Kenya. We present an insight on the nature, causes, dynamics and mitigation strategies of conflicts between the Turkana and Pokot pastoralists based on research study focusing on the linkages between resource availability and conflict. The findings suggest that violent conflicts in pastoral areas result from a myriad of socio-cultural, economic and political factors that reinforce one another by limiting availability of, depleting and reducing access to natural resource base. Competition for scarce natural resources triggered by frequent droughts and exacerbated by weak local institutions, proliferation of small firearms, political incitements, unclear property right regimes and cattle-raiding, was considered central to the violent conflicts observed in the area. The authors conclude that developing integrated policies and strengthening local governance institutions that are rooted in traditional practices for managing resources and inter-community conflicts is integral to the solution.

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    Authors: Opiyo, Francis, E.O.; Wasonga, Oliver, V.; Schilling, Janpeter; Mureithi, Stephen, M.;

    The theory of “resource scarcity” dominates the debate on “ecoviolence” in pastoral areas, where conflicts among communities have traditionally been linked to competition over scarce resources and invariably drought because of its role in resource depletion. However, the notion that climate change and resultant resource scarcity directly prompt violent conflict has been challenged by the notion that conflict actually coincide with periods of resource abundance. These contesting views point to nondeterministic linkage between resource availability and conflicts and, therefore, the complexity of pastoral conflicts. This is the scenario hypothesized for the vast pastoral areas of Kenya where violent conflict has become a chronic characteristic. While focusing on drought-induced conflicts over grazing resources, this paper takes cognizance of other factors that trigger and perpetuate violent conflicts in arid north-western Kenya. We present an insight on the nature, causes, dynamics and mitigation strategies of conflicts between the Turkana and Pokot pastoralists based on research study focusing on the linkages between resource availability and conflict. The findings suggest that violent conflicts in pastoral areas result from a myriad of socio-cultural, economic and political factors that reinforce one another by limiting availability of, depleting and reducing access to natural resource base. Competition for scarce natural resources triggered by frequent droughts and exacerbated by weak local institutions, proliferation of small firearms, political incitements, unclear property right regimes and cattle-raiding, was considered central to the violent conflicts observed in the area. The authors conclude that developing integrated policies and strengthening local governance institutions that are rooted in traditional practices for managing resources and inter-community conflicts is integral to the solution.

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