• Energy Research
• Closed Access close
• Restricted close
• other engineering and technologies close
• DE close
• IT close
• ES close

Abstract To achieve the EU climate and energy objectives, a transition towards a future sustainable energy system is needed. The integration of the huge potential for industrial waste heat recovery into smart energy system represents a main opportunity to accomplish these goals. To successfully implement this strategy, all the several stakeholders' conflicting objectives should be considered. In this paper an evolutionary multi-objective optimization model is developed to perform a sustainability evaluation of an energy system involving an industrial facility as the waste heat source and the neighbourhood as district heating network end users. An Italian case study of heat recovery from a steel casting facility shows how the model allows to properly select the district heating network set of users to fully exploit the available waste energy. Design directions such as the thermal energy storage capacity can be also provided. Moreover, the model enables the analysis of the trade-off between the stakeholders’ different perspectives, allowing to identify possible win-win solutions for both the industrial sector and the citizenship.

The electrical resistance of Ni 50 Ti 30 Hf 20 and Ni 50 Ti 40.5 Hf 9.5 alloys during Stress Assisted Two Way Memory Effect was investigated with the aim to deduce the relationship between electrical resistance and deformation across the transformation range. Results show an almost linear relationship although a crossing point between increasing and decreasing deformation may compromise the use of these alloys actuators.

The passivation of iron and steel (DIN 1623) was studied by integral and depth selective conversion electron Mossbauer spectroscopy and Auger electron spectroscopy. Thickness and phase composition of the passive layer formed in sulphate solution and in a phosphate buffer were determined in dependence on the anodic potential and the duration of the passivating procedure. The experimental results lead to the conclusion that not the whole oxidic layer is responsible for the passivity but only a very thin intermediate layer formed between the cubic substrate and the rhombic oxide (γ-FeOOH) cover.

Abstract AP1000® Generation III+ reactor bases its safety concept on passive systems, differently from the previous Generation II reactors. This fact has led the approximations and methodologies previously used for modeling active safety systems to be reviewed and adapted to simulate the physics of passive systems. Diverse studies about the AP1000 containment have demonstrated the difficulty to correctly model the occurring phenomenology. In this paper, an integral AP1000 3D containment GOTHIC model is presented, including the Passive Containment Cooling System (PCCS). The model includes the compartments inside and outside the metallic containment liner that influence the thermal–hydraulic behavior. The model is tested against a Large Break Loss of Coolant Accident (LBLOCA) to assess its thermal–hydraulic performance, assuming a PCS tank malfunction, what is a conservative hypothesis. The pressure and temperature evolution predicted by the 3D containment model is analyzed and compared with a single node Lumped Parameters model, allowing to evaluate some preliminary benefits of 3D modeling for containment safety analysis. The 3D containment model allows to predict the thermal evolution in each containment compartment capturing the heterogeneity of this phenomenon, with higher resolution than the lumped parameters models traditionally used in this kind of analyses. It allows to observe the thermohydraulic conditions locally at any time during the transient.

Abstract Breastshot water wheels are gravity hydraulic machines employed in low head sites. The scope of this work is to test the performance of a breastshot water wheel with two geometric inflow configurations: a sluice gate at different openings and two vertical overflow weirs. With the sluice gate, the maximum efficiency of the plant is 75%, constant over a wide range of flow rates, while the efficiency with the weir is increasing in the same flow rate range. Therefore, the wheel with the weir can exploit higher water volumes, and also it performs better at high power input. In practical applications, the inflow configuration can be effectively controlled to optimize the operative working conditions of breastshot water wheels, depending on the external hydraulic ones. The experimental results are also discussed in dimensionless terms, in order to support engineers in the design of similar breastshot water wheels.

Abstract Hybrid energy storage is a multi-modal approach to store and supply different forms of energy (electricity, heat, cold) simultaneously. This is an important sector coupling approach and enables large scale flexibility for a deep decarbonization of energy systems. Two different proposed energy storages – power-to-heat-to-X energy storage (PHXES) and pumped thermal energy storage (PTES) – are investigated in detail in this work towards their potential towards a hybrid deployment. The techno-economic analysis includes thermodynamic flowsheet simulations and unified cost estimations based on the used equipment. It is shown that the main input data set (e.g. working fluid selection, turbomachinery efficiency, pinch temperatures) has a strong influence on storage roundtrip efficiency in the thermodynamic simulations, but also on storage costs. Cost decrease and performance increase can be conflicting development targets, and it is not clear if future energy systems rather require technologies with the highest storage efficiencies or if low cost is an important prerequisite. PHXES and three variants of PTES are implemented into a simplified energy system model of the city of Hamburg that comprises the electric load and heat demand of the district heating system. Two scenarios (fossil benchmark and 80% decarbonization) are used to select the technologies and their capacities that allow the most cost-effective energy supply solution by a linear-programming optimization procedure. Large scale renewable power generation and hybrid energy storage play the major roles in the decarbonization scenario. PHXES with a storage capacity of 69 GWh, hot water storage (3.6 GWh) and a battery system (430 MWh) are part of the cost-optimal solution. A cost sensitivity analysis shows that a total cost reduction of 60–80% is required for PTES to become competitive in this model scenario.

Abstract The elemental dissolution of Cu-Zn alloys was investigated as a function of Zn content ranging from 0 to 45 wt%. Atomic emission spectroelectrochemistry (AESEC) was utilized to directly monitor Cu2+ and Zn2+ release and oxide growth as function of time during potentiodynamic experiments. It was determined that Cu dissolution undergoes a simultaneous mechanism of Cu2O formation and Cu2+ release. The addition of Zn in Cu-Zn alloy does not measurably change the dissolution mechanism of Cu2+ and the rate of aqueous Cu2+ was only dependent on the potential. Zn dissolution was however blocked by the formation of a Cu(0) film which shifted the Zn dissolution in the anodic direction.

Previous work carried out for the last eight years resulted in the proposal of a complete system of dimensionless groups in order to represent the performance of different kinematic Stirling engine configurations. When looking for experimental support for the proposed model, some differences between the performances of several prototypes were observed. In this paper an equation is introduced to be applied to all known kinematic engines and to their whole range of performance. The coefficients appearing in this equation can be computed from temperature and geometrical dimensionless ratios and from experimental measurements at the maximum indicated power operating point. The meaning of those coefficients is interpreted and their usefulness to provide an engine performance overview is shown. The quasi-static simulation and the characteristic Mach number at the maximum indicated power operating point appear to be interesting criteria in order to evaluate the performance of prototypes.