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We report on surface channeling experiments of singly charged ions on single crystal surfaces of Pt(1 1 0) and Pd(1 1 0). Using a time-of-flight system installed in forward direction we analyze the energy distribution of the scattered projectiles. By variation of the primary energy and the angle of incidence we investigate effects of the perpendicular energy on the channeling features. The perpendicular energy is defined as E-perpendicular to = E(0)sin(2)psi with psi the angle of incidence. In combination with precise azimuthal rotations of the crystal, we are sensitive to axial channeling and obtain information about the limits of axial surface channeling. From a comparison with detailed trajectory calculations we find that axial channeling effects are most pronounced for a perpendicular energy between 5 and 20 eV. As a result, we obtain an exemplary channeling map for the interaction of nitrogen ions with the (1 x 2) reconstructed Pt(1 1 0) surface identifying different channeling regimes. (c) 2004 Elsevier B.V. All rights reserved.

Solar Energy Materials and Solar Cells, 116 + (2013) 176-181. doi:10.1016/j.solmat.2013.04.019

With the concept of climate services rapidly climbing research and research-funding agendas worldwide, the time is ripe for a debate about the objectives, scope and content of such services.

Since 2007, a range of new modeling approaches and tools have been developed for sustainability impact assessment (SIA), but a lack of universal acceptance of SIA tools in applied policy making is observed. The current article gives an overview of experiences from several European and international projects, critically reviews the selected SIA tools and then discusses a number of reasons for the observed disconnect of the tools with the potential users. Largely based on the experiences of the presented SIA tools focusing land use policy advice, a decision tree is designed, which may facilitate an adequate, region and developmental phase specific selection of tool-box components for the development of SIA tools in future. Elements to ensure end-user participation are also integrated in the decision tree in order to increase the likelihood of the tool in applied land use policy advice. In addition, the Challenges in SIA tool development and use are further discussed.

In this study we examine the determination accuracy of both the mean radiant temperature (Tmrt) and the Universal Thermal Climate Index (UTCI) within the scope of numerical weather prediction (NWP), and global (GCM) and regional (RCM) climate model simulations. First, Tmrt is determined and the so-called UTCI-Fiala model is then used for the calculation of UTCI. Taking into account the uncertainties of NWP model (among others the HIgh Resolution Limited Area Model HIRLAM) output (temperature, downwelling short-wave and long-wave radiation) stated in the literature, we simulate and discuss the uncertainties of Tmrt and UTCI at three stations in different climatic regions of Europe. The results show that highest negative (positive) differences to reference cases (under assumed clear-sky conditions) of up to -21°C (9°C) for Tmrt and up to -6°C (3.5°C) for UTCI occur in summer (winter) due to cloudiness. In a second step, the uncertainties of RCM simulations are analyzed: three RCMs, namely ALADIN (Aire Limitée Adaptation dynamique Développement InterNational), RegCM (REGional Climate Model) and REMO (REgional MOdel) are nested into GCMs and used for the prediction of temperature and radiation fluxes in order to estimate Tmrt and UTCI. The inter-comparison of RCM output for the three selected locations shows that biases between 0.0 and ±17.7°C (between 0.0 and ±13.3°C) for Tmrt (UTCI), and RMSE between ±0.5 and ±17.8°C (between ±0.8 and ±13.4°C) for Tmrt (UTCI) may be expected. In general the study shows that uncertainties of UTCI, due to uncertainties arising from calculations of radiation fluxes (based on NWP models) required for the prediction of Tmrt, are well below ±2°C for clear-sky cases. However, significant higher uncertainties in UTCI of up to ±6°C are found, especially when prediction of cloudiness is wrong.

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The Vietnamese Mekong Delta (VMD) is one of the world’s most vulnerable deltas to climate change and sea level rise. Adequate understandings of future hydrological changes are crucial for effective water management and risk-proofing, however, this knowledge body is currently very limited. This study quantifies the responses of the VMD’s river flow regime to multiple stimuli, namely future upstream inflow variation, local climate change, and sea level rise. The one-dimensional hydrodynamic model MIKE 11 was used to simulate discharges and water levels across the delta. We developed four scenarios to represent changes in the upstream discharges, precipitation changes and sea level rise, covering the 2036–2065 period. We downscaled climate data and applied three bias-correction methods for five General Circulation Models (GCM), and two Representative Concentration Pathways (RCPs). The climate change projections show similar trends of increasing wet season precipitation and decreasing dry season precipitation. However, cross-scenario variations are sometimes large, depending on the individual GCMs, the RCPs and specific locations. The hydraulic simulation results indicate that, under discharge changes between −20% and +10%, combined with in-delta precipitation variations during the dry season, river discharges at the four representative stations could reduce substantially from −2.5% to −100.2%. During the wet season, the calculated river discharges show increase between 7.3% and 46.7% under four considered scenarios. Substantial changes in the VMD’s river flow regime could have potentially serious implications for water management, especially saltwater intrusion, and therefore calling for timely adaptation measures.

A full understanding of the elementary processes taking place in dye-sensitised solar cells requires an accurate description of the electronic structure of the dyes, the semiconductor surface, the electrolyte and their interactions. This review describes how electronic structure calculations have contributed to the field since its first steps and what methodologies have been adopted to study the charge transfer processes at the interface. Not all properties are equally predictable with electronic structure methods, and this work highlights the main success areas (e.g. the rationalization of the optical properties of the dyes), the recent developments (e.g. the improved description of the dye–semiconductor interaction) and the key challenges for the future (e.g. the calculation of charge recombination rate).