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Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

The design and assessment of net-zero buildings commonly focus exclusively on the operational phase, ignoring the embodied environmental impacts over the building life cycle. An analysis is presented on the consequences of integrating embodied impacts into the assessment of the environmental advantageousness of net-zero concepts. Fundamental issues needing consideration in the design process - based on the evaluation of primary energy use and related greenhouse gas emissions - are examined by comparing three net-zero building design and assessment cases: (1) no embodied impacts included, net balance limited to the operation stage only; (2) embodied impacts included but evaluated separately from the operation stage; and (3) embodied impacts included with the operation stage in a life cycle approach. A review of recent developments in research, standardization activities and design practice and the presentation of a case study of a residential building in Norway highlight the critical importance of performance indicator definitions and system boundaries. A practical checklist is presented to guide the process of incorporating embodied impacts across the building life cycle phases in net-zero design. Its implications are considered on overall environmental impact assessment of buildings. Research and development challenges, as well as recommendations for designers and other stakeholders, are identified.

Thermoacoustic technology emerges as a sustainable and low-carbon method for energy conversion, leveraging environmentally friendly working mediums and independence from electricity. This study presents the development of a multimode heat-driven thermoacoustic system designed to utilize medium/low-grade heat sources for room-temperature cooling and heating. We constructed both a simulation model and an experimental prototype for a single-unit direct-coupled thermoacoustic system, exploring its performance in heating-only, cooling-only, and hybrid heating and cooling modes. Internal characteristic analysis including an examination of internal exergy loss and a distribution analysis of key parameters was first conducted in the hybrid cooling and heating mode. The results indicated a positive-focused traveling-wave-dominant acoustic field within the thermoacoustic core unit, enhancing energy conversion efficiency. The output system performance was subsequently tested under different working conditions in the heating-only and cooling-only modes. A maximum output heating power of 2.3 kW and a maximum COPh of 1.41 were observed in the heating-only mode. Meanwhile, a cooling power of 748 W and a COPc of 0.4 were obtained in the typical cooling condition at 7 °C when operating in cooling-only mode. These findings underscore the promising potential of thermoacoustic systems for efficiently utilizing medium/low-grade heat sources for cooling and/or heating applications in the future.

AbstractThe potential impacts of future climate scenarios on water balance and flow regime are presented and discussed for a temporary river system in southern Italy. Different climate projections for the future (2030–2059) and the recent conditions (1980–2009) were investigated. A hydrological model (Soil and Water Assessment Tool) was used to simulate water balance at the basin scale and streamflow in a number of river sections under various climate change scenarios, based on different combinations of global and regional models (global circulation models and regional climate models). The impact on water balance components was quantified at the basin and subbasin levels as deviation from the baseline (1980–2009), and the flow regime alteration under changing climate was estimated using a number of hydrological indicators. An increase in mean temperature for all months between 0.5–2.4 °C and a reduction in precipitation (by 4–7%) was predicted for the future. As a consequence, a decline of blue water (7–18%) and total water yield (11–28%) was estimated. Although the river type classification remains unvaried, the flow regime distinctly moves towards drier conditions and the divergence from the current status increases in future scenarios, especially for those reaches classified as I‐D (ie, intermittent‐dry) and E (ephemeral). Hydrological indicators showed a decrease in both high flow and low flow magnitudes for various time durations, an extension of the dry season and an exacerbation of extreme low flow conditions. A reduction of snowfall in the mountainous part of the basin and an increase in potential evapotranspiration was also estimated (4–4.4%). Finally, the paper analyses the implications of the climate change for river ecosystems and for River Basin Management Planning. The defined quantitative estimates of water balance alteration could support the identification of priorities that should be addressed in upcoming years to set water‐saving actions.

In this paper, we address the problem of determining the optimal day-ahead generation profile for a wind power producer by exploiting wind speed forecasts provided by a meteorological service. In the considered framework, the wind power producer is called to take part in the responsibility of system operation by providing day-ahead generation profiles and undergoing penalties in case of deviations from the schedule. Penalties are applied only if the delivered hourly energy deviates from the schedule more than a given relative tolerance. The optimal solution is obtained analytically by formulating and solving a stochastic optimization problem aiming at maximizing the expected profit. The proposed approach consists in exploiting wind speed forecasts to classify the next day into one of several predetermined classes, and then selecting the optimal solution derived for each class. The performance of the bidding strategy is demonstrated using real data from an Italian wind plant and weather forecasts provided by a commercial meteorological service.

<div class="section abstract"><div class="htmlview paragraph">The introduction of new light-duty vehicle emission limits to comply under real driving conditions (RDE) is pushing the diesel engine manufacturers to identify and improve the technologies and strategies for further emission reduction. The latest technology advancements on the after-treatment systems have permitted to achieve very low emission conformity factors over the RDE, and therefore, the biggest challenge of the diesel engine development is maintaining its competitiveness in the trade-off “CO₂-system cost” in comparison to other propulsion systems. In this regard, diesel engines can continue to play an important role, in the short-medium term, to enable cost-effective compliance of CO₂-fleet emission targets, either in conventional or hybrid propulsion systems configuration. This is especially true for large-size cars, SUVs and light commercial vehicles.</div><div class="htmlview paragraph">In this framework, a comprehensive approach covering the whole powertrain is of primary importance in order to simultaneously meet the performance, efficiency, noise and emission targets, and therefore, further development of the combustion system design and injection system represent important levers for additional improvements. For this purpose, a dedicated 0.5 dm³ single-cylinder engine has been developed and equipped with, a state-of-the-art Euro 6 combustion system, and an advanced common rail fuel injection system (FIS) offering higher flexibility in terms of injection strategy and higher quantity accuracy. Three injector nozzles with different hydraulic flow rates (HF) have been selected and employed for the overall combustion process optimization.</div><div class="htmlview paragraph">The optimization has been performed by means of an extensive DoE-based test campaign in which the engine and FIS operating parameters have been parametrized with the aim to carry out a proper combination in terms of HF and injection strategy. The results at partial load conditions evidence significant advantages in applying an advanced injection pattern, while the HF reduction can significantly improve the smoke emission and combustion noise without fuel consumption penalties. Therefore, a proper combination and optimization of the HF and injection strategy can provide low noise and engine-out smoke while maintaining the rated power performance targets.</div></div>

The aim of the paper is to study the influence of the power transformer on signal transmission in the case of a power line communication (PLC) system in a overhead Medium Voltage (MV) power network. A model of the PLC system was carried out by means of the Simulink® software. A distributed parameter MV overhead line, two power transformers, the signal coupling interface of a ST7540 FSK powerline transceiver were included in the model. The performances of the complete PLC communication system are evaluated for different line lengths by means of the attenuation computed as ratio between the received and transmitted voltage signals. © 2011 IEEE.