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Ammonia increases buffer capacity of methanogenic medium in mesophilic anaerobic reactor thus increasing the stability of anaerobic digestion process. Optimal ammonia concentration ensures sufficient buffer capacity while not inhibiting the process. It was found out in this paper that this optimum depends on the quality of anaerobic sludge under investigation. The optimal concentrations for methanogens were 2.1, 2.6 and 3.1 g/L of ammonia nitrogen in dependence on inoculum origin. High ammonia nitrogen concentration (4.0 g/L) inhibited methane production, while low ammonia nitrogen concentration (0.5 g/L) caused low methane yield, loss of biomass (as VSS) and loss of the aceticlastic methanogenic activity. It was found out that negative effect of low ammonia nitrogen concentration on biomass is caused not only by low buffer capacity but also by insufficiency of nitrogen as nutrient. It was also found out that anaerobic sludge with higher ammonia nitrogen concentration (4.2 g/L) tolerates even concentration of volatile fatty acids (160 mmol/L) which causes inhibition of the process with low ammonia nitrogen concentration (0.2 g/L).

Given the significant amount of installed generation-capacity based on wind power, and also due to current economic downturn, the subsidies and incentives that have been widely used by wind-power producers to recover their investment costs have decreased and are even expected to disappear in the near future. In these conditions, wind-power producers need to develop offering strategies to make their investments profitable counting solely on the market. This paper proposes a multi-stage risk-constrained stochastic complementarity model to derive the optimal offering strategy of a wind-power producer that participates in both the day-ahead and the balancing markets. Uncertainties concerning wind-power productions, market prices, demands' bids, and rivals' offers are efficiently modeled using a set of scenarios. The conditional-value-at-risk metric is used to model the profit risk associated with the offering decisions. The proposed model is recast as a tractable mixed-integer linear programming program solvable using available branch-and-cut algorithms. Results of a case study are reported and discussed to show the effectiveness and applicability of the proposed approach.

This paper describes anaerobic thermophilic sludge digestion (55 °C) in a continuously stirred tank reactor (CSTR) on a pilot-plant scale (150 L). The experimental protocol was defined to examine the effect of the increase in the organic loading rate on the efficiency of the digester and to report on its steady-state performance. The reactor was subjected to a programme of steady-state operation over a range of solids retention times (SRTs) of 75, 40, 27, 20 and 15 days and organic loading rates (OLR) in the range 0.4–2.2 kg VS/(m3 day). The digester was fed with raw sludge (containing approximately 35 kg/m3 volatile solids (VS)) once daily during the 75-day SRT period, twice daily during the 40-day SRT period and three times a day during the 27-, 20- and 15-day SRT periods. The reactor was initially operated with an organic loading rate of 0.4 kg VS/(m3 day) and an SRT of 75 days. The volatile solids removal efficiency in the reactor was found to be 73%, while the volumetric methane production rate produced in the digester reached 0.02 m3/(m3 day). Over a 338-day operating period, an OLR of 2.2 kg VS/(m3 day) was achieved with 49.1% VS removal efficiency in the pilot sludge digester, at which time the volumetric methane production rate content of biogas produced in the digester reached 0.4 m3/(m3 day). The chemical oxygen demand (COD) mass balance obtained indicated that COD used for methane generation increased when the SRT was decreased or when the influent organic loading rate was increased. This implies that the amount of COD used in the anabolism route decreased with SRT due the microbial population becoming adapted to new operational conditions and more COD being used to generate methane.

One of the major goals of engine designers is the reduction of fuel consumption and pollutant emissions while keeping or even improving engine performance. In recent years, different technical issues have been investigated and incorporated into internal combustion engines in order to fulfill these requirements. Most are related to the combustion process since it is responsible for both fuel consumption and pollutant emissions. Additionally, the most critical operating points for an engine are both the starting and the warming up periods (the time the engine takes to reach its nominal temperature, generally between 80°C and 90°C), since at these points fuel consumption and pollutant emissions are larger than at any other points. Thus, reducing the warm-up period can be crucial to fulfill new demands and regulations. This period depends strongly on the engine cooling system and the different strategies used to control and regulate coolant flow and temperature. In the present work, the influences of different engine cooling system configurations on the warm-up period of a Diesel engine are studied. The first part of the work focuses on the modeling of a baseline engine cooling system and the tests performed to adjust and validate the model. Once the model was validated, different modifications of the engine coolant system were simulated. From the modelled results, the most favourable condition was selected in order to check on the test bench the reduction achieved in engine warm-up time and to quantify the benefits obtained in terms of engine fuel consumption and pollutant emissions under the New European Driving Cycle (NEDC). The results show that one of the selected configurations reduced the warm-up period by approximately 159 s when compared with the baseline configuration. As a consequence, important reductions in fuel consumption and pollutant emissions (HC and CO) were obtained.

Abstract CIEMAT is promoting experiences on heliostats for replacement of damaged facets on CESA-1 field, design of new modules for Phoebus-like plants and innovative high-risk options for the future. Glass-metal facets, stretched membranes, glass fiber and holographic concentrators are being considered in a number of developments.

Abstract Thermal energy storage (TES) systems are growing to a relevant role in solar cooling applications. Hence, high energy density is a desirable property of the TES system. Phase change materials (PCM) helps to increase this characteristic. A high temperature pilot plant able to test different types of TES systems and materials was designed and built at the University of Lleida (Spain). This pilot plant is composed mainly of three parts: heating system, cooling system, and different storage tanks. Two identical storage tanks based on the shell-and-tubes heat exchanger, one of them including 196 squared fins in the bundle of the tubes and the other without, were experimentally tested. Hydroquinone was selected as the storage material, having a latent heat of 205 kJ/kg and a phase change temperature between 168 and 173 °C. The aim of this paper is to test experimentally, and compare the average effectiveness of the TES systems analyzed using PCM for solar cooling and refrigeration applications. It was found out that for the same tank configurations (shell-and-tubes) even changing drastically the dimensions of the tank or the number and the diameter of the tubes, the average effectiveness curve proposed in the literature fits well with the results showed here.

This work studied outdoor pilot scale production of Nannochloropsis gaditana in tubular photobioreactors. The growth and biomass composition of the strain were studied under different culture strategies: continuous-mode (varying nutrient supply and dilution rate) and two-stage cultures aiming lipid enhancement. Besides, parameters such as irradiance, specific nitrate input and dilution rate were used to obtain models predicting growth, lipid and fatty acids production rates. The range of optimum dilution rate was 0.31-0.351/day with maximum biomass, lipid and fatty acids productivities of 590, 110 and 66.8 mg/l day, respectively. Nitrate limitation led to an increase in lipid and fatty acids contents (from 20.5% to 38.0% and from 16.9% to 23.5%, respectively). Two-stage culture strategy provided similar fatty acids productivities (56.4 mg/l day) but the neutral lipids content was doubled.

This study classifies Mediterranean marine protected areas (MPAs) according to the combined result of pressure level and protection. Six major marine environment pressures were considered: pressures from fish farms, fishing, marine litter, pressures from marinas, pollution from maritime transport, and climate change. MPA protection was assessed through legal protection and management effort. Most MPA area in the Mediterranean is under relatively high pressure level and afforded low protection. Inshore areas show higher pressure levels. Five marine ecoregions, nine countries and nineteen MPA designation categories have over 50% of their MPA area under major concern. The mean number of cumulative pressures occurring in priority MPAs ranges between three and four, although the mean combined intensity of those pressures is low. However, these figures are most likely underestimated, especially for the southern Mediterranean. The most concerning pressures to MPAs regarding extent and intensity were: climate change, fishing and pollution from maritime transport.