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Abstract An orange and an apple juice each containing 250–385 ppm tin were under suspicion of having caused an outbreak of food poisoning in Kuwait in 1967 but did not cause any toxic signs when fed to pigeons, cats and dogs. One cat out of 11 vomited when fed an orange juice containing 540 ppm tin derived from the container, and with juices containing 1370 ppm tin, 20–30% of the cats vomited but none of the dogs was affected. Fruit juices containing 2000 ppm tin caused vomiting in up to 40% of the cats. Modification of orange juices with a high tin content by addition of nitrate or ethanol or by adjustment of the pH from 3 to 6 did not affect the incidence of vomiting. No toxic signs were produced in rats given fruit juices containing added tin salts up to a level of 995 ppm or in rats and cats given aqueous solutions of tin salts (up to 1200 ppm tin) in citric acid. Solid foods containing tin derived from the containers up to the highest level obtainable (470 ppm) had no toxic effect when fed to dogs and cats. Five human volunteers showed no toxic signs after drinking fruit juices containing 498, 540 or 730 ppm tin derived from the containers, but all five had some gastro-intestinal disturbance after drinking a fruit juice containing 1370 ppm tin. A repeat experiment with the latter juice had no effect in four of the volunteers and only mild symptoms in the fifth. In rats and cats, there was no evidence of tin absorption 24 hr after ingestion of fruit juices containing high levels of tin. No tin was recovered from the urine and in the rats 99% was recovered from the faeces. Only minute amounts of tin could be found in the body, apart from the alimentary tract, of a rat that had been given orange juice with a high tin content ad lib. instead of drinking water for 7 days. It is concluded that toxic signs follow the drinking of tin-containing fruit juices by man and cats only with tin levels of approximately 1400 ppm and above, that there is no evidence from these experiments that toxicity is due to the absorption of tin and that the most likely cause is local irritation of the mucous membrane of the alimentary tract.

The importance of fluorinated products in pharmaceutical and medicinal chemistry has necessitated the development of synthetic fluorination methods, of which direct C–H fluorination is among the most powerful. Despite the challenges and limitations associated with the direct fluorination of unactivated C–H bonds, appreciable advancements in manipulating the selectivity and reactivity have been made, especially via transition metal catalysis and photochemistry. Where transition metal catalysis provides one strategy for C–H bond activation, transition-metal-free photochemical C–H fluorination can provide a complementary selectivity via a radical mechanism that proceeds under milder conditions than thermal radical activation methods. One exciting development in C–F bond formation is the use of small-molecule photosensitizers, allowing the reactions i) to proceed under mild conditions, ii) to be user-friendly, iii) to be cost-effective and iv) to be more amenable to scalability than typical photoredox-catalyzed methods. In this review, we highlight photosensitized C–H fluorination as a recent strategy for the direct and remote activation of C–H (especially C(sp3)–H) bonds. To guide the readers, we present the developing mechanistic understandings of these reactions and exemplify concepts to assist the future planning of reactions.

For zero‐defect wave soldering of double‐sided and multilayer printed circuit boards, the copper through‐hole‐plating must be impervious to gas generated in the laminate for the period of a few seconds while the solder is molten. The kinetics of the gas evolution during soldering have been related quantitatively to the integrity of the plated copper. This in turn is related to the quality of the electroless copper (evaluated using the backlighting test), the nature and distribution of the catalyst (evaluated using X‐ray photoelectron spectroscopy) and the methods and effectiveness of the hole‐wall preparation (evaluated using scanning electron microscopy). The relevance of laboratory measurements has been confirmed on a wide range of industrial production plating lines.

Intra-day price spreads are of interest to electricity traders, storage and electric vehicle operators. This paper formulates dynamic density functions, based upon skewed-t and similar representations, to model and forecast the German electricity price spreads between different hours of the day, as revealed in the day-ahead auctions. The four specifications of the density functions are dynamic and conditional upon exogenous drivers, thereby permitting the location, scale and shape parameters of the densities to respond hourly to such factors as weather and demand forecasts. The best fitting and forecasting specifications for each spread are selected based on the Pinball Loss function, following the closed-form analytical solutions of the cumulative distribution functions.

The industrial sector accounts for 17% of end-use energy in the UK, and 54% globally. Therefore, there is substantial scope for simulating and assessing potential energy retrofit options for industrial buildings. Building Energy Modelling (BEM) applied to industrial buildings poses a complex but important opportunity for reducing global energy demand, due to years of renovation and expansion. Large and complex industrial buildings make modelling existing geometry for BEM difficult and time consuming. This paper presents a potential solution for quickly capturing and processing as-built geometry of a factory to be utilized in BEM. Laser scans were captured from the interior of an industrial facility to produce a Point Cloud. The existing capabilities of a Point Cloud processing software were assessed to identify the potential development opportunities to automate the conversion of Point Clouds to building geometry for BEM applications. In conclusion, scope exists for increasing the speed of 3D geometry creation of an existing industrial building for application in BEM and subsequent thermal simulation.

Abstract Two office layouts with high and low levels of thermal control were compared, respectively traditional cellular and contemporary open plan offices. The traditional Norwegian practice provided every user with control over a window, blinds, door, and the ability to adjust heating and cooling. Occupants were expected to control their thermal environment to find their own comfort, while air conditioning was operating in the background to ensure the indoor air quality. In contrast, in the British open plan office, limited thermal control was provided through openable windows and blinds only for occupants seated around the perimeter of the building. Centrally operated displacement ventilation was the main thermal control system. Users’ perception of thermal environment was recorded through survey questionnaires, empirical building performance through environmental measurements and thermal control through semi-structured interviews. The Norwegian office had 35% higher user satisfaction and 20% higher user comfort compared to the British open plan office. However, the energy consumption in the British practice was within the benchmark and much lower than the Norwegian office. Overall, a balance between thermal comfort and energy efficiency is required, as either extreme poses difficulties for the other.

Abstract In the next 25 years an unprecedented number of new marine artificial structures, over 75,000 offshore wind turbines alone, are planned to meet global net zero targets. Structures are required to last for multiple decades in the hostile marine environment; where the largest cost across their whole lifecycle is on operations and maintenance dependent on accessibility in calm seas. However, the role of climate change on accessibility, and thus operational cost, has not been resolved. Here we provide the first study of future accessibility; evaluated from global climate model driven wave modelling, using the high emission scenario (RCP8.5). We found that climate change drives significant regional variation in accessibility, with the northern hemisphere benefiting from a 6% increase in operating windows whilst accessibility in parts of the southern hemisphere is reduced by 6-9%. These findings will help offshore developers and stakeholders incorporate adaptions to climate change as part of strategic planning practices.