• Energy Research
• Embargo close
• GB close
• ES close
• CN close
• US close
• CA close

This thesis explores Germany’s *Energiewende* (‘energy transition’) and the role of citizen/community energy democracy initiatives at municipal and state levels in shaping developments that underpin this society-wide transformation - examining how grassroots agitation, in particular, has prompted meaningful action and policy change on the part of government at multiple levels. Using Berlin and Hamburg - Germany’s largest urban centers and leading city-states in the country’s federal system - as case studies, the research examines how citizens’ initiatives in both cities have campaigned for the remunicipalization of local energy networks to expedite, democratize, and incorporate social justice goals into each region’s Energiewende. Finally, this study pivots to consider the progress of the transition nationally in recent years, investigating how major events like the Covid-19 pandemic, watershed federal elections in 2021, war in Ukraine, and the resultant energy crisis have affected the evolution and direction of the Energiewende, and the important contributions of citizen/community energy initiatives to the national response here. The analytical framework draws on over 100 interviews conducted with relevant stakeholders and experts involved in the transition, representing different perspectives (e.g. on remunicipalization and the Energiewende itself) and diverse levels of government (e.g. from the district to federal level). This extensive body of original research is complemented by a wide array of other relevant source material that has likewise been consulted to inform this work and further evaluate the impacts of bottom-up energy democracy initiatives on the broader transition in Germany’s regions - and, by extension, nationally - as they continue to affect the pace and trajectory of the now-famous Energiewende. Ultimately, this study contributes an in-depth, ground-level analysis to the literature of key elements that have driven energy system change in Germany, shining a fresh light on the complex and interrelated nexus of sustained grassroots action, policy responses, and shifting sociopolitical realities that form the context in which the Energiewende has been (re)launched, reformed, and reimagined over the decades.

This thesis explores Germany’s *Energiewende* (‘energy transition’) and the role of citizen/community energy democracy initiatives at municipal and state levels in shaping developments that underpin this society-wide transformation - examining how grassroots agitation, in particular, has prompted meaningful action and policy change on the part of government at multiple levels. Using Berlin and Hamburg - Germany’s largest urban centers and leading city-states in the country’s federal system - as case studies, the research examines how citizens’ initiatives in both cities have campaigned for the remunicipalization of local energy networks to expedite, democratize, and incorporate social justice goals into each region’s Energiewende. Finally, this study pivots to consider the progress of the transition nationally in recent years, investigating how major events like the Covid-19 pandemic, watershed federal elections in 2021, war in Ukraine, and the resultant energy crisis have affected the evolution and direction of the Energiewende, and the important contributions of citizen/community energy initiatives to the national response here. The analytical framework draws on over 100 interviews conducted with relevant stakeholders and experts involved in the transition, representing different perspectives (e.g. on remunicipalization and the Energiewende itself) and diverse levels of government (e.g. from the district to federal level). This extensive body of original research is complemented by a wide array of other relevant source material that has likewise been consulted to inform this work and further evaluate the impacts of bottom-up energy democracy initiatives on the broader transition in Germany’s regions - and, by extension, nationally - as they continue to affect the pace and trajectory of the now-famous Energiewende. Ultimately, this study contributes an in-depth, ground-level analysis to the literature of key elements that have driven energy system change in Germany, shining a fresh light on the complex and interrelated nexus of sustained grassroots action, policy responses, and shifting sociopolitical realities that form the context in which the Energiewende has been (re)launched, reformed, and reimagined over the decades.

Integrating environmental, social and governance (ESG) variables into the assessment of a mining project is essential to ensure the short and long term acceptance by the various stakeholders involved and the lack of doing so can put the sustainability of a project at risk. Thus, a holistic approach has been proposed which combines profitability and sustainability analysis with social and environmental considerations for any decisions made on processing operation selection or mine expansion. The potential economic implications of these factors would be used for determining the operational strategy. This study is based on an actual quarry case study and statistical data taken from Spain. Quantitative variables related to ESG aspects have been integrated into a block model, and optimisations were performed based on different plant types and waste disposal strategies. Results demonstrate a strong interdependence between profitability and sustainability. It is observed that strategies related to operating costs impact the environmental and social impacts. A green index is also incorporated to evaluate and compare the different scenarios, determining that the most relevant strategies in adding value to mining projects include investment in new technologies, environmental solutions, and economic and social benefits. Objectius de Desenvolupament Sostenible::9 - Indústria, Innovació i Infraestructura Objectius de Desenvolupament Sostenible::8 - Treball Decent i Creixement Econòmic Objectius de Desenvolupament Sostenible::12 - Producció i Consum Responsables Peer Reviewed

Integrating environmental, social and governance (ESG) variables into the assessment of a mining project is essential to ensure the short and long term acceptance by the various stakeholders involved and the lack of doing so can put the sustainability of a project at risk. Thus, a holistic approach has been proposed which combines profitability and sustainability analysis with social and environmental considerations for any decisions made on processing operation selection or mine expansion. The potential economic implications of these factors would be used for determining the operational strategy. This study is based on an actual quarry case study and statistical data taken from Spain. Quantitative variables related to ESG aspects have been integrated into a block model, and optimisations were performed based on different plant types and waste disposal strategies. Results demonstrate a strong interdependence between profitability and sustainability. It is observed that strategies related to operating costs impact the environmental and social impacts. A green index is also incorporated to evaluate and compare the different scenarios, determining that the most relevant strategies in adding value to mining projects include investment in new technologies, environmental solutions, and economic and social benefits. Objectius de Desenvolupament Sostenible::9 - Indústria, Innovació i Infraestructura Objectius de Desenvolupament Sostenible::8 - Treball Decent i Creixement Econòmic Objectius de Desenvolupament Sostenible::12 - Producció i Consum Responsables Peer Reviewed

Organic solar cells utilize an energy-level offset to generate free charge carriers. Although a very small energy-level offset increases the open-circuit voltage, it remains unclear how exactly charge generation is affected. Here we investigate organic solar cell blends with highest occupied molecular orbital energy-level offsets (∆EHOMO) between the donor and acceptor that range from 0 to 300 meV. We demonstrate that exciton quenching at a negligible ∆EHOMO takes place on timescales that approach the exciton lifetime of the pristine materials, which drastically limits the external quantum efficiency. We quantitatively describe this finding via the Boltzmann stationary-state equilibrium between charge-transfer states and excitons and further reveal a long exciton lifetime to be decisive in maintaining an efficient charge generation at a negligible ∆EHOMO. Moreover, the Boltzmann equilibrium quantitatively describes the major reduction in non-radiative voltage losses at a very small ∆EHOMO. Ultimately, highly luminescent near-infrared emitters with very long exciton lifetimes are suggested to enable highly efficient organic solar cells. Donor–acceptor systems with low energy-level offset enable high power efficiency in organic solar cells yet it is unclear what drives charge generation. Classen et al. show that long exciton lifetimes enable efficient exciton splitting and thus generation of free charges while also suppressing voltage losses.

Organic solar cells utilize an energy-level offset to generate free charge carriers. Although a very small energy-level offset increases the open-circuit voltage, it remains unclear how exactly charge generation is affected. Here we investigate organic solar cell blends with highest occupied molecular orbital energy-level offsets (∆EHOMO) between the donor and acceptor that range from 0 to 300 meV. We demonstrate that exciton quenching at a negligible ∆EHOMO takes place on timescales that approach the exciton lifetime of the pristine materials, which drastically limits the external quantum efficiency. We quantitatively describe this finding via the Boltzmann stationary-state equilibrium between charge-transfer states and excitons and further reveal a long exciton lifetime to be decisive in maintaining an efficient charge generation at a negligible ∆EHOMO. Moreover, the Boltzmann equilibrium quantitatively describes the major reduction in non-radiative voltage losses at a very small ∆EHOMO. Ultimately, highly luminescent near-infrared emitters with very long exciton lifetimes are suggested to enable highly efficient organic solar cells. Donor–acceptor systems with low energy-level offset enable high power efficiency in organic solar cells yet it is unclear what drives charge generation. Classen et al. show that long exciton lifetimes enable efficient exciton splitting and thus generation of free charges while also suppressing voltage losses.

In recent decades, many societal changes have unfolded, including population ageing, reconfigurations of household structures, labour market transformation, and a secular deceleration of economic growth. These shifts pose considerable challenges to preexisting welfare states, particularly to the efficacy of countries’ pension systems. This dissertation examines the context and trajectory of pension reforms in Mexico, the United Kingdom, and the United States. Its contribution is to ascertain the viability and political feasibility of reforms that enhance the financial sustainability of their pension systems, while maintaining adequate income and coverage levels. The dissertation builds on political economy approaches and on the institutionalist literature, which highlight how the role of interest groups and structure of institutions and political systems shape policy outcomes. The frameworks of blame avoidance and credit-claiming are also considered, to provide a comprehensive analysis of the complex dynamics surrounding pension systems and reform efforts. This dissertation uses a mixed-methods approach – including public opinion surveys of 3,000+ individuals, semi-structured elite interviews, historical document analyses, and specialized fiscal and actuarial projections of selected pension reforms in the three selected countries. It addresses three core research questions: 1) What is the current context for pension reform in Mexico, the United Kingdom, and the United States given their histories? 2) Is the necessary (for achieving specific minimum levels of sustainability, adequacy, and coverage) pension reform politically feasible? 3) How do the characteristics of each reform affect its political feasibility? Corollary: The modification of which channel (benefits, contributions, retirement age) is perceived as more politically feasible for diverse stakeholders? The methodology chosen provides a timely picture of the context surrounding potential pension reforms in the three case studies. In Mexico, credit-claiming and the interests of private stakeholders explain the success of recent pension reforms, and partisan politics are the key determinants for future fiscal changes. For the United Kingdom, the institutionalist literature helps explain the reasons for the relatively easier reform avenues; the most politically feasible reforms are those in the private sector, while the housing market is of key importance for pensions. In the United States, the institutionalist literature and the framework of blame avoidance also help explain the current legislative gridlock and the reasons why no major reform has been enacted for decades. For Mexico and the United Kingdom there exist politically feasible reforms, notably a modification of the retirement age channel, that can increase the system’s sustainability while maintaining income adequacy and coverage; whereas based on the current context of extreme polarisation and legislative gridlock, there do not seem to exist politically feasible pension reforms that preserve the structure of Social Security in the United States. The dissertation brings the lens of political feasibility to bear on a previously technical literature on the structure of the pension systems in the three countries, and thus on the feasibility of reform to deliver financial sustainability, adequacy of retirement incomes, and adequate coverage of the old age population. It identifies the feasible routes for reform in Mexico and the United Kingdom, but concludes that the political economy context the United States has reached rules out feasible reforms of its current pension structures.