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Abstract Additional experimental data concerning the kinetics of Ni-Mo codeposition were obtained by investigating cathodic polarization using a rotating disc electrode. The Ni-Mo alloys were deposited from an ammonium citrate bath. The alloy deposition was controlled by activation in the case of low values of the cathode potential and by diffusion in the case of higher values. The hydrogen discharge was found to be diffusion controlled. The inductive influence of nickel results in depolarization of the reduction of molybdenum which cannot be deposited separately. An increase in the disc rotation speed caused an increase in the maximum cathode efficiency and in the molybdenum content of the alloy.

According to the renewable energy directive 2009/28/EC, the European Union Member States should increase by 2020 the use of renewable energy to 20% of gross final energy consumption and to reach a mandatory share of 10% renewable energy in the transport sector. This study aims to quantify the impact of 2020 bioenergy targets on the land use in the EU, based on the projections of the National Renewable Action Plans in four scenarios: Scenario 1. Bioenergy targets according to NREAPs; Scenario 2. Bioenergy targets according to NREAPs, no second generation biofuels; Scenario 3. Bioenergy targets according to NREAPs, reduced import of biofuels and bioliquids; Scenario 4. Bioenergy targets according to NREAPs, high imports of biofuels and bioliquids. This study also considers the credit for co-products generated from biofuel production. The analysis reveals that the land used in the EU for bioenergy would range between 13.5 Mha and 25.2 Mha in 2020. This represent between 12.2% and 22.5% of the total arable land used and 7.3% and 13.5% of the Utilised Agricultural Area (UAA). In the NREAPS scenario, about 17.4 Mha would be used for bioenergy production, representing 15.7% of arable land and 9.4% of UAA. The increased demand from biofuels would lead to an increased generation of co-products, replacing conventional fodder for animal feed. Considering the co-products, the land used for bioenergy would range between 8.8 Mha and 15.0 Mha in 2020 in the various scenarios. This represent between 7.9% and 13.3% of the total arable land used in the EU and 4.7% and 8.0% of the UAA. In the NREAPS scenario, when co-products are considered, about 10.3 Mha would be used for biofuels, bioliquids and bioenergy production, representing 9.3% of arable land and 5.6% of agricultural land. This study further provides detailed data on the impact on land use in each Member State.

AbstractAn arc‐furnace model consisting of non‐linear, time‐varying resistance, realized by the Alternative Transients Program (ATP), is presented in this paper. It is shown that the model is appropriate for flicker investigation in electrical networks supplying arc furnaces, constituting a valid alternative to the linear arc modelling realized by amplitude modulation of voltage generators. Block diagram of the procedure for ATP modelling of the nonlinear, time‐varying arc resistance, dynamic voltage‐current characteristic of the furnace electric arc, voltage and current arc waveforms and characteristic curves of an arc furnace, obtained by ATP simulation, are presented, referring to circuit parameters taken from an actual plant and to a sinusoidal law for arc‐length time variation. Aflickermeter ATP simulation is realized to derive equivalent voltage‐variation values in agreement with the actual flicker measurements.

Abstract The central role of occupants for achieving energy savings in residential buildings is increasingly recognised. Simulation programmes able to take into account occupant behaviour are considered to be powerful tools for bridging the gap between the predicted and the actual energy consumption for new buildings. Nevertheless, the majority of residential buildings that will constitute the housing stock in 2050 have already been built today, therefore occupant behaviour and building simulation tools need to be fully exploited for supporting the renovation of existing housing stock. The aim of this paper is to explore the role of occupant behaviour modelling in supporting decision-makers dealing with the design of renovation strategies for residential buildings. An Italian multi-family public housing building is assumed as case study to estimate the influence of three dimensions linked with occupant behaviour – management of the thermostat, management of the heating system, variation of building characteristics – on energy heating consumption. The results show that, while the occupant behaviour influences the heating loads up to 1/3 in case of high level of building retrofit, the less the building is renovated, the higher is the behavioural impact in absolute terms of energy reduction. Therefore, in order to be effective, renovation strategies are required to design appropriate informative instruments at an early stage to support behaviour changes towards responsible energy consumption.

The main objective of this paper is to illustrate the current state of the art of the newborn smart gas grid concept. We provide a detailed discussion of the envisaged features of the smart gas grid, giving attention to both the related academic literature and to the ongoing world-wide projects. In doing so, we also discuss the potentialities of rethinking the smart grid paradigm from the perspective of a whole energy system, that both encompasses the electrical and the gas grid, and identify some critical key aspects that must be handled while developing the new smart energy paradigm.

Abstract In this work, we intend to solve the equations governing two laminar isothermal or non-isothermal coaxial plane jets with variable density in an ambient fluid at rest in order to study the initial conditions influence (i.e. the nozzles ejection conditions) on the jet characteristic parameters. A finite difference method is developed to solve the dimensionless Navier–Stokes and energy equations resulting from some assumptions. The discussion about the results relates primarily to the concentration core length according to the nozzles thicknesses ratios. The influences of the gas velocity and temperature resulting from the external nozzle are also examined. This made it possible to deduce correlations of practical use between these parameters in order to apply them in engineering processes.

Abstract This paper aims to present a feasibility study of the innovative plant for methanol synthesis from carbon dioxide-sequestered by fossil fuel power plant and hydrogen, which is produced by water electrolyzer employing the over-production on the electrical grid. The thermo-economic analysis is performed in the framework of the MefCO2 H2020 EU project and it is referred to the German economic scenario, properly taking into account the real market costs and cost functions for different components of the plant. Three different plant capacities for methanol production (4000 10,000 and 50,000 ton/year) have been investigated, assuming an average cost for electrical energy to feed electrolysers and analyzing the influence of the most significant parameters (oxygen selling option, methanol selling price and electrolysers’ capital cost) on the profitability of the plant. The analysis has been performed in W-ECoMP, software for the thermo-economic analysis and plant optimization developed by the University of Genoa.

Abstract In recent years living walls have increasingly spread, thus becoming a diffuse architectural envelope cladding technology. Consequently, a more precise understanding of their thermal behavior and impact on the building energy balance are needed. One of the most important effects provided by the use of living walls is the shading of the building envelope, with clear benefits during the cooling period. Furthermore, many features characterize the thermal behavior of living walls, namely plant species, leaf area index (LAI), evapotranspiration, emissivity and air cavity type. All these particular characteristics have been accounted in the mathematical model developed in the frame of the presented research, whose aim is to provide a tool for the prediction of the thermal behavior of living walls. Two kinds of living walls, one with grass and closed air cavity and the other one with vertical garden and open air cavity were considered. The results achieved by means of the developed model show a good agreement with the measurements also supported by model efficiency indexes such as Nash–Sutcliffe efficiency index (NSEC). Values of around 0.7 were obtained for the NSEC index for both the investigated living walls.

Abstract This paper presents experimental and numerical investigation of mistuned forced responses of an integrally bladed disk with full set of underplatform dampers (UPDs). This research aims at providing: 1. An experimental benchmark for nonlinear dynamics of a mistuned bladed disks with UPDs. 2. A numerical model that can account for features of a mistuned forced response level. Accordingly, a detailed experimental campaign is conducted on a static test rig called Octopus. This rig is specifically designed to investigate the dynamics of a full-scale integrally bladed disk (blisk) with UPDs in a noncontact manner so that the dynamic response of the system is not modified. The effect of mistuning on experimental forced response levels is assessed and a linearized model is proposed to predict the modulation of frequency response functions (FRFs) due to the frequency splitting. In the development of the model, the mistuning pattern identified from the linear blisk without UPDs is used and it is assumed that adding the dampers does not change the structural mistuning of the blisk. In this study, the fundamental mistuning model identification (FMM ID) was employed to identify the mistuning pattern of the blisk. It is shown that the proposed model successfully predicts the modulation of linear mistuned FRFs. The linearized model is also able to predict the modulation of nonlinear mistuned FRFs in stick condition (when nonlinear friction damping is negligible) with a good accuracy validating this assumption that adding the dampers does not change the mistuning pattern.

Abstract An international workshop was held in Richland, Washington, United States of America, in October, 1980 to discuss progress on development of the acid digestion process for treating combustible nuclear waste. The workshop was attended by participants from nine member countries of the Nuclear Energy Agency of the Organization for Economic Cooperation and Development (OECD/NEA). The status of the acid digestion development programs of various countries is discussed in this paper. The acid digestion process has been developed and demonstrated on an engineering scale in several countries and appears to be especially applicable to treatment of combustible wastes containing high levels of transuranic contamination, where there is potential for recovering the transuranic radionuclides. Because the process takes place at a relatively low temperature, the plutonium contained in the residue is in a form that can be readily recovered using standard leaching techniques. The process is adaptable to a wide variety of combustible wastes, such as cellulosics, plastics, rubber materials, and ion exchange resin. While the process has been developed and demonstrated on an engineering scale primarily for transuranic contaminated wastes, the process is also adaptable to beta-gamma wastes such as reactor ion exchange resins.