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The global restoration agenda can help solve the biodiversity extinction crisis by regenerating biodiversity-rich ecosystems, maximising conservation benefits using natural regeneration. Yet, conservation is rarely the core objective of restoration, and biodiversity is often neglected in restoration projects targeted towards carbon sequestration or enhancing ecosystem services for improved local livelihoods. Here, we synthesise evidence to show that promoting biodiversity in restoration planning and delivery is integral to delivering other long-term restoration aims, such as carbon sequestration, timber production, enhanced local farm yields, reduced soil erosion, recovered hydrological services and improved human health. For each of these restoration goals, biodiversity must be a keystone objective to the entire process. Biodiversity integration requires improved evidence and action, delivered via a socio-ecological process operating at landscape scales and backed by supportive regulations and finance. Conceiving restoration and biodiversity conservation as synergistic, mutually reinforcing partners is critical for humanity's bids to tackle the global crises of climate change, land degradation and biodiversity extinction.

From the British debate on the depletion of coal in 1865 to the First World Power Conference held in London in 1924, scientists, engineers, industrialists, and politicians produced new interpretations of the past, present, and future in terms of the mobilisation of energy resources. This thesis identifies an emerging ‘energy developmentalism’, which called for maximising energy use to maintain or improve a nation’s place in international competition. Energy developmentalism was not a marginal worldview confined to ‘energeticists’, but a coherent set of claims, measurements, and arguments that informed energy governance on an international scale. Rather than focusing on a single resource, energy developmentalism applied a unified schema to all energy sources, including those like solar and tidal energy that were still mostly theoretical. Drawing on sources from across Europe, while staying grounded in political changes in Britain and France, makes it possible to understand how a general formula for transforming raw materials with maximum efficiency was applied differently depending on specific political contexts. This period saw the articulation of problems like the depletion of resources, the difference between renewable and nonrenewable energy, the intermittency of renewables, the overreliance on a single source of energy, and the centrality of energy to modern economies – problems that are often associated with later periods. Scientific measurements of efficiency, horsepower, and kilowatts became operators in political debates centred on questions of national standing and progress. Even as oil became increasingly important in the world economy, the delegates at the First World Power Conference transformed a vision of a renewable energy future into one of a general expansion of energy consumption as the basis of progress. In so doing, they downplayed the continued importance of fossil fuels and equated ‘conservation’ with the fullest possible use of all energy sources, renewable or not.

Traditionally, critical infrastructures demand for high dependability, being the services they provide essential to human beings and the society at large. However, more recent attention to cautious usage of energy resources is changing this vision and calls for solutions accounting for appropriate multi-requirements combinations when developing a critical infrastructure. In such a context, analysis supports able to assist the designer in envisioning a satisfactory trade-off among the multi-requirements for the system at hand are highly helpful. In this paper, the focus is on the railway sector and the contribution is a stochastic model-based analysis framework to quantitatively assess trade-offs between dependability indicators and electrical energy consumption incurred by the rail switch heating system.Moving from a preliminary study that concentrated on energy consumption only, the analysis framework has been extended to become a solid support to devise appropriate tuning of the heating policy that guarantees satisfactory trade-offs between dependability and energy consumption. An evaluation campaign in a variety of climate scenarios demonstrates the feasibility and utility of the developed framework.

Climate change has been widely recognised as one of the most urgent and growing threats to natural and cultural heritage in the twenty-first century, and the indelible impact of humanity has led to the definition of a new geological epoch, the Anthropocene. Indigenous peoples are disproportionately affected by natural and human-induced changes to the environment. Their vulnerability is exacerbated by centuries of cultural and territorial disenfranchisement within settler-colonial nations. This dissertation aims at understanding Indigenous perceptions of heritage in the face of climate change and its intersection with the impacts of settler- colonialism. It analyses how these on-the-ground perceptions can, in turn, inform heritage organisations and contribute to safeguarding the many facets of tangible and intangible Indigenous heritage for future generations in the Anthropocene. This is accomplished through a comparative, transnational case study of two communities each from the Dehcho First Nations in the Northwest Territories, Canada, and the Aymara and Quechua peoples in northern Chile. I use a multi-method approach consisting of semi-structured interviews, oral histories and participant observation. The data is complemented by environmental and heritage legislation and grey literature at multiple organisational scales for both case studies. Three lines of enquiry are explored through an applied comparative thematic analysis: i) the perceptions of climate change and associated land loss/change among Indigenous groups and how this impacts each group’s notions of challenges to its cultural identity; ii) the intersection of the effects of post- colonialism, ongoing industrial activities and climate change on the intergenerational transmission of ancestral knowledge and notions of place attachment; and iii) how international, national and regional political and sociocultural rhetoric on environmental and heritage conservation affect local, grassroots considerations for safeguarding heritage. The similarities and contrasts of the Dehcho First Nations, Aymara and Quechua experiences of climate change across the North-South divide are related from the grassroots to arrive at redefining heritage practices in the Anthropocene. The results demonstrate that decolonising heritage is not only necessary, but that this decolonisation depends on building and actively engaging in intercultural empathy through the global threat of climate change. In order to understand how Indigenous practices, places, and items are valorised—attributed value—as heritage in the face of climate change, one must empathise with the cultural loss that exists in the temporal and cognitive spaces between Indigenous individuals’ moments of nostalgic reference and today.

Power system controls are vulnerable to cyber-attacks that can seriously affect and even inhibit their operation. Such attacks may affect large portions of the power system, make repair difficult and cause huge societal impact, so pressure to ensure cyber-security of control and communication systems is now strong worldwide. Several cyber-security frameworks were developed, but it is rather difficult to anticipate adoption costs and benefits, and this hampers their generalised adoption. T his paper focuses on the outcome of two case studies (concerning the Italian power generation and the Polish transmission systems. The socio-economic impact of failures and the costs of standard adoption are estimated on an objective basis. It is up to public authorities to decide whether to require the adoption of security standards to operators in the electric system. The nature of public good of security underlines the necessity of public support for this operation, but we discuss the extent and the management of this support.

The luminescent solar concentrator has the potential of widespread use as a generator of electricity from sunlight well-suited for use in the urban environment owing to its adaptability in shape and coloration. The device performance is heavily dependent on the ability to transport light long distances to the edges. A common organic luminophore used in the device is based on a perylene core. In this work, we describe an overlooked effect of UV illumination on the appearance and efficiency of these devices. An additional absorption peak appears upon polymerization under intense UV in nitrogen atmosphere which significantly reduces the edge emissions from the device. The additional absorbance peak disappears after exposure to air, indicating the presence of a radical anion being formed during the UV light exposure. This suggests newly-produced LSC devices should be allowed to stand a period of time under ambient conditions before their performance characteristics are determined, which could have implications in potential future commercialization of the technology.

Silicon carbide/silicon rich carbide multilayers, aimed at the formation of silicon nanodots for photovoltaic applications, have been studied. The electrical properties have been investigated at the nano-scale by conductive Atomic Force Microscopy (c-AFM) and at macro-scale by temperature dependent conductivity measurements. The mixture is composed of highly conductive Si nanoclusters and moderately conductive SiC nanoclusters in a disordered matrix. The conduction mechanism takes place via band states induced by the disorder at the interface between nanodot clusters. Structural properties have been extracted by optical spectroscopy analyses. The results contribute to the understanding of the microscopical electronic mechanisms of the composite material, which is a candidate for third generation photovoltaics.

The hydration of CO2 suffers from kinetic inefficiencies that make its natural trapping impractically sluggish. However, CO2-fixing carbonic anhydrases (CAs) remarkably accelerate its equilibration by 6 orders of magnitude and are, therefore, "ideal" catalysts. Notably, CA has been detected in ureolytic bacteria, suggesting its potential involvement in microbially induced carbonate precipitation (MICP), yet the dynamics of the urease (Ur) and CA genes remain poorly understood. Here, through the use of the ureolytic bacteriumSporosarcina pasteurii, we investigate the differing role of Ur and CA in ureolysis, CO2 hydration, and CaCO3 precipitation with increasing CO2(g) concentrations. We show that Ur gene up-regulation coincides with an increase in [HCO3-] following the hydration of CO2 to HCO3- by CA. Hence, CA physiologically promotes buffering, which enhances solubility trapping and affects the phase of the CaCO3 mineral formed. Understanding the role of CO2 hydration on the performance of ureolysis and CaCO3 precipitation provides essential new insights, required for the development of next-generation biocatalyzed CO2 trapping technologies.

Achievement of sustainable development in light of ongoing climate change and biodiversity pressures benefits from the deployment of innovations that foster engagement and uptake across all levels, mobilises finance flows commencement to the scale of the challenge, and enables the dissemination of transition solutions that support the low carbon economy. This research investigates the relationship between the legal architecture of market mechanisms under international law and the role of private actors, and how this contributes to sustainable development. Through an exploration of how market mechanisms under the climate change and biodiversity regimes have achieved environmentally sound outcomes, been advanced in sectoral approaches, and facilitated via bilateral and multilateral trade and investment relationships, important insights are identified regarding the composition of effective law and governance architectural approaches. Leveraging experiences derived from treaty practice viewed through an interactional account of international law, this assessment elucidates the important role played by alignment of legal regimes, robust transparency measures, and complementary schemes such as stakeholder-endorsed certifications in buttressing the established measures to ensure sustainable development outcomes and contributes to understanding the role of private actors in the operationalisation of environmental agreements. Research findings suggest it is the interaction of norms across the international legal architecture, informed by relationships within and across relevant treaty systems and the general corpus of international law, and actualised through engagement with private actors as a component of market mechanisms that provides the opportunity for congruence of practice, forging of shared understandings, and normative internalisation and ownership among communities of practice that stimulates both innovative solutions and ambitious action.