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Abstract Techniques for evaluating water management are critical to diagnose the performance of polymer electrolyte membrane fuel cells (PEMFCs). Acoustic emission as a function of polarisation (AEfP) has been recently introduced as a non-invasive, non-destructive method to analyse the water generation and removal inside a PEMFC during polarisation. AEfP was shown to provide unique insight into water management within a conventional PEMFC and correlating it to cell performance. Here, AEfP is used to characterise the performance of fractal PEMFCs by evaluating the hydration conditions inside them. This is achieved by probing the water dynamics inside two different fractal flow-field based PEMFCs, namely 1-way and 2-way fractal PEMFCs, and measuring the corresponding acoustic activity generated from them. AEfP is performed on the fractal PEMFCs under relatively humid (70% RH) and fully humidified (100% RH) reactant relative humidity (RH) conditions. Flooding in the 2-way fractal PEMFC, as opposed to the 1-way fractal PEMFC, is demonstrated under different operating conditions by the relatively higher acoustic activity it generates. Corroborating evidence of flooding in the 2-way fractal flow-field under different conditions is provided by its polarisation curves, impedance tests and galvanostatic (current hold) measurements.

In this work, we investigated the impact of temperature on two-phase transport in low temperature (LT)-polymer electrolyte membrane (PEM) electrolyzer anode flow channels via in operando neutron imaging and observed a decrease in mass transport overpotential with increasing temperature. We observed an increase in anode oxygen gas content with increasing temperature, which was counter-intu.itive to the trends in mass transport overpotential. We attributed this counterintuitive decrease in mass transport overpotential to the enhanced reactant distribution in the flow channels as a result of the temperature increase, determined via a one-dimensional analytical model. We further determined that gas accumulation and fluid property changes are competing, temperature-dependent contributors to mass transport overpotential; however, liquid water viscosity changes led to the dominate enhancement of reactant water distributions in the anode. We present this temperature-dependent mass transport overpotential as a great opportunity for further increasing the voltage efficiency of PEM electrolyzers.

Abstract The technology landscape around distributed generation continues to evolve in response to increasing demand for high-efficiency, low-emission, low-cost power generation. While emerging distributed power technologies, such as solid oxide fuel cells (SOFCs), continue to advance, they still face challenges due to their high capital costs, and shorter lifetimes that typically arise from electrochemical stack performance degradation at high operating temperatures (>750 °C). Recent advancements in protonic ceramic fuel cells (PCFCs) offer the potential to mitigate drawbacks of their higher temperature SOFC counterparts by enabling lower operating temperatures (550 °C–600 °C) with acceptable power densities. The present work leverages the recent progress in protonic ceramic cell and stack technology development to generate viable system configurations and evaluate the energetic performance potential of PCFC-based systems for stationary power generation. Process system engineering of two water-neutral system concepts, which provide 25 kW of electric power and process hot water, are presented and evaluated through sensitivity studies. Stack design parameters are altered and used to gauge the effect on system performance characteristics, including fuel cell stack and balance-of-plant sizing requirements, and electric and cogeneration efficiencies. The study finds that the potentially high per-pass fuel utilization capability of PCFC stacks could enable unprecedented electric efficiencies approaching 70% without hybridization with other prime movers.

Thermally integrated pumped-thermal electricity storage (TI-PTES) offers the opportunity to store electricity as thermal exergy at a large scale, and existing studies are primarily focused on TI-PTES systems based on high-temperature thermal energy storage. This paper presents a thermo-economic analysis of a “cold TI-PTES” system which converts electricity into cold energy using a vapor compression refrigeration (VCR) unit and stores it at sub-ambient temperatures during the charging process, and generates electricity by using an organic Rankine cycle (ORC) working between the sub-ambient temperature and an external low-grade heat source during the discharging process. The effects of key parameters, i.e., mass flowrate and temperature of the storage medium, ORC evaporation temperature, component efficiencies, and pinch-point temperature differences, on the system performance are evaluated based on a whole-system thermo-economic model. The results reveal that the roundtrip efficiency and levelized cost of storage (LCOS) of the system increases while the electrical energy storage capacity decreases as the temperatures of the two cold storage tanks approach each other. When the temperature of the cold storage tank 1 rises from 1 °C to 8 °C while the cold storage tank 2 remains as 13 °C, there is an increase of 25% and 20% in the roundtrip efficiency and LCOS respectively while the energy storage capacity decreases by 69%. A roundtrip efficiency of 0.74 and LCOS of 0.32 $/kWh are achieved with a heat source temperature of 85 °C, using a mass flowrate and temperature of the cold storage medium of 50 kg/s and 1 °C. Furthermore, any change in cold storage medium mass flowrate changes both electrical energy storage capacity and power output by the same proportions. With a continuous high-flowrate external heat source, the LCOS can be as low as 0.17 $/kWh. By providing sufficient heat from an external heat source, the proposed system possesses a high potential for medium-to-large scale energy storage with a unique hybrid ...

Abstract Comparative pyrolysis behaviors of typical hardwood ( Fagus sylvatica ) and softwood ( Cunninghamia lanceolata ) were investigated based on thermogravimetric analysis over a wide heating rate range from 5 K/min to 60 K/min. The Flynn-Wall-Ozawa model-free method was applied to estimate the various activation energy values at different conversion rates, and the Coats-Redfern model-fitting method was used to predict the possible reaction mechanism. Two pyrolysis regions were established by the trend of activation energy, divided by the threshold of conversion rate (0.4 for hardwood and 0.2 for softwood) but with the same distinguished temperature at about 580 K. For the region under the conversion rate threshold, the activation energy of hardwood increased gradually while softwood decreased. Furthermore, the activation energy remained the same for both hardwood and softwood in the region over the conversion rate threshold. However, softwood behaved greater activation energy than hardwood during the whole pyrolysis process. The pyrolysis differences of hardwood and softwood could be attributed to the chemical component, molecular structure, component proportion and various extractives. The same reaction mechanism of hardwood and softwood was verified by applying the Coats-Redfern approach. By checking activation energies obtained according to different models with those obtained through the Flynn-Wall-Ozawa method, the best model was based on diffusion mechanism when the conversion rate was less than its threshold, otherwise based on reaction order (2nd to 3rd).

Abstract Interest in solar chimney power plant (SCPP) has seen resurgence due to the continuously increasing awareness on environmental concerns, particularly greenhouse gas emissions from fossil fuels, since the 21st century. Although remarkable advances in the understanding of SCPP have been achieved through extensive theoretical, experimental, and numerical studies with different focuses on various aspects of the SCPP technology, no industrial scale SCPP has been built. In response to these new scientific advances and challenges for commercialization, seven questions, including parameter influences, turbine design, flow and heat transfer characteristics, similarity analysis, and hybrid systems, are presented in this work. In addition, answers and current understanding are included to provide succinct links to latest knowledge and identify areas that require further research.

Abstract Increasing electricity production by solar and wind energy is projected to impact the stability of electricity grids and consequently may limit the growth of renewable electricity generation. This issue can be ameliorated in part by increasing the flexibility of baseload power plants. A thermodynamic analysis of thermal energy storage (TES) coupled with a nuclear-powered Rankine cycle as one approach of increasing baseload flexibility is presented. During periods of excess capacity, the high-pressure steam supply is used to charge the TES. When electricity generation above the baseload capacity is required, the TES is discharged to generate steam for expansion in the low-pressure turbine. Pressure, temperature, and enthalpy state points within the cycle are presented over a range of charge and discharge rates. The capacity factor over a charge/discharge cycle is up to 9.8% higher than that of the same plant operated with steam bypass. This benefit increases with increasing charge and discharge power. With TES, the thermal-to-electrical efficiency is stable over a wide range of discharge rates. The results support future development of TES systems for baseload thermal power plants in a power grid in which renewable energy is prioritized.