• Energy Research
• Swiss National Science Foundation close
• LT close

To attain commercial viability, perovskite solar cells (PSCs) have to be reasonably priced, highly efficient, and stable for a long period of time. Although a new record of a certified power conversion efficiency (PCE) value over 25% was achieved, PSC performance is limited by the lack of hole-transporting materials (HTMs), which extract positive charges from the light-absorbing perovskite layer and carry them to the electrode. Here, we report spirobifluorene-based HTMs with finely tuned energy levels, high glass-transition temperature, and excellent charge mobility and conductivity enabled by molecularly engineered enamine arms. HTMs are synthesized using simple condensation chemistry, which does not require costly catalysts, inert reaction conditions, and time-consuming product purification procedures. Enamine-derived HTMs allow the fabrication of PSCs reaching a maximum PCE of 19.2% and stability comparable to spiro-OMeTAD. This work demonstrates that simple enamine condensation reactions could be used as a universal path to obtain HTMs for highly efficient and stable PSCs.

A measurement of the underlying activity in scattering processes with a hard scale in the several GeV region is performed in proton-proton collisions at sqrt(s) = 0.9 and 7 TeV, using data collected by the CMS experiment at the LHC. The production of charged particles with pseudorapidity |eta| < 2 and transverse momentum pT > 0.5 GeV/c is studied in the azimuthal region transverse to that of the leading set of charged particles forming a track-jet. A significant growth of the average multiplicity and scalar-pT sum of the particles in the transverse region is observed with increasing pT of the leading track-jet, followed by a much slower rise above a few GeV/c. For track-jet pT larger than a few GeV/c, the activity in the transverse region is approximately doubled with a centre-of-mass energy increase from 0.9 to 7 TeV. Predictions of several QCD-inspired models as implemented in PYTHIA are compared to the data. Journal of high energy physics 2011(9), 109(2011). doi:10.1007/JHEP09(2011)109 Published by Springer, Berlin

Abstract The energy flow, dE/dη, is studied at large pseudorapidities in proton-proton collisions at the LHC, for centre-of-mass energies of 0.9 and 7 TeV. The measurements are made using the CMS detector in the pseudorapidity range 3.15 < |η| < 4.9, for both minimum-bias events and events with at least two high-momentum jets. The data are compared to various pp Monte Carlo event generators whose theoretical models and input parameter values are sensitive to the energy-flow measurements. Inclusion of multiple-parton interactions in the Monte Carlo event generators is found to improve the description of the energy-flow measurements.