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Dolomite-based binders are characterised by interesting technical and environmental features. For their synthesis, sources of both CaO and MgO are required. The idea developed in this work is to couple the synthesis of dolomite-based binders, starting from a natural dolomite, through the concept of concentrated solar energy (needed to drive the endothermal dolomite calcination process) in fluidised bed reactors. To this end, a fluidised bed system, where the concentrated solar radiation is mimicked by the use of Xe-lamps (short-arc), has been set up and operated. Natural dolomite (sieved in the 420-590 ?m size range) was calcined at a nominal temperature of 850 °C, and bed temperature profiles during solar-driven calcination were investigated. Then, four binders were prepared by mixing slaked dolomite (obtained from the hydration of solar calcined dolomite) with either blast furnace slag or coal fly ash as supplementary cementitious materials. The binders were hydrated for curing times ranging from 7 to 56 days. X-ray fluorescence, X-ray diffraction and combined differential thermal and thermogravimetric analyses were employed as characterisation techniques both to analyse the chemical composition of starting materials and to investigate the evolution of the hydration in the four systems.

In the present work the influence of accelerated mineral carbonation on the leaching behaviour of basic oxygen furnace steel slag was investigated. The environmental behaviour of the material as evaluated through the release of major elements and toxic metals under varying pH conditions was the main focus of the study. Geochemical modelling of the eluates was used to derive a theoretical description of the underlying leaching phenomena for the carbonated material as compared to the original slag. Among the investigated elements, Ca and Si were most appreciably affected by carbonation. A very clear effect of carbonation on leaching was observed for silicate phases, and lower-Ca/Si-ratio minerals were found to control leaching in carbonated slag eluates as compared to the corresponding untreated slag sample as a result of Ca depletion from the residual slag particles. Clear evidence was also gained of solubility control for Ca, Mg and Mn by a number of carbonate minerals, indicating a significant involvement of the original slag constituents in the carbonation process. The release of toxic metals (Zn, V, Cr, Mo) was found to be variously affected by carbonation, owing to different mechanisms including pH changes, dissolution/precipitation of carbonates as well as sorption onto reactive mineral surfaces. The leaching test results were used to derive further considerations on the expected metal release levels on the basis of specific assumptions on the relevant pH domains for the untreated and carbonated slag.

It has long been established that mature forests are mosaics of patches in different development phases but it has seldom explicitly been taken into account in ecological studies. We demonstrate here that these development phases, which are related to the population dynamics of trees, play an important role in the distribution of fauna based on observations on frugivorous birds. In an area close to the Calakmul Biosphere Reserve in Mexico, we studied the abundance of large forest bird species in relation to forest development phases, with a methodology that seems promising for ecological diagnosis and prognosis in forest management planning. Fine-scale forest mapping and bird counts were carried out in two block-transects of 40 m x 3000 m. Tree sampling in a sub-transect was used to generate population characteristics of trees, Large bird species preferred mature or senescent forest patches, whereas relatively young, growing forest patches were avoided. Important large tree species such as Manilkara zapota, Thouinia paucidentata, Guaiacum sanctum and Esenbeckia pentaphylla, characteristic of older forest patches, showed skewed size distributions indicating stress or overexploitation. The population of M. zapota, a key fruiting species that accounted for 26.5% of the total woody biomass, was most heavily affected by stress. A future collapse in the population of M. zapota, a decrease of the total area of older forest, and a decline in the abundance of large birds is likely if stress on the system continues at this level. (C) 2008 Elsevier B.V. All rights reserved.

The influence of compost on the growth of bean plants irrigated with As-contaminated waters and its influence on the mobility of As in the soils and the uptake of As (as NaAs(III)O2) by plant components was studied at various compost application rates (3·10(4) and 6·10(4) kg ha(-1)) and at three As concentrations (1, 2 and 3 mg kg(-1)). The biomass and As and P concentrations of the roots, shoots and beans were determined at harvest time, as well as the chlorophyll content of the leaves and nonspecific and specifically bound As in the soil. The bean plants exposed to As showed typical phytotoxicity symptoms; no plants however died over the study. The biomass of the bean plants increased with the increasing amounts of compost added to the soil, attributed to the phytonutritive capacity of compost. Biomass decreased with increasing As concentrations, however, the reduction in the biomass was significantly lower with the addition of compost, indicating that the As phytotoxicity was alleviated by the compost. For the same As concentration, the As content of the roots, shoots and beans decreased with increasing compost added compared to the Control. This is due to partial immobilization of the As by the organic functional groups on the compost, either directly or through cation bridging. Most of the As adsorbed by the bean plants accumulated in the roots, while a scant allocation of As occurred in the beans. Hence, the addition of compost to soils could be used as an effective means to limit As accumulation in crops from As-contaminated waters.

In this paper a grid-tied photovoltaic (PV) cascaded H-bridge (CHB) inverter with embedded storage units is proposed. The multi-input single-output inverter architecture allows a distributed maximum power point tracking (DMPPT) approach, thus mitigating the mismatch effects. The energy storage units (ESUs) embedded at each dc-link provides more flexibility to the power circuit compensating for the inherent variability of the PV sources. The proposed power system ensures a continuous power supply to the grid also in case of PV power fluctuations due to irradiance conditions as well as to the MPPT. In particular, the presence of a storage element allows a voltage sweep on the PV source to be implemented, thus guaranteeing the maximization of PV energy harvesting, with no detrimental effect on the power delivery to the utility network. The numerical results, carried out on a single-phase nineteen-level PV CHB inverter, reveal the improved performance of the proposed design and control technique.

Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

The safeguard of power equipments is assuming a major role in the deregulated electricity market, where a malfunctioning power system could be responsible for serious damages to a large number of system operators having access to the shared energy resource. In this context thermal monitoring of power cables represents a key issue in evaluating the risks associated with a given load management policy especially during emergency conditions. In particular this demands for reliable assessment models that should be able to predict the transient thermal behaviour when the load exceeds the nameplate value. In this connection the application of both simplified and detailed power cable thermal models is often complicated by the presence of uncertainties affecting the tolerances of the input data. The effect of these uncertainties could influence the final solution to a considerable extent. A comprehensive tolerance analysis is therefore required in order to incorporate the effect of data uncertainties into the thermal modelling process. To address this problem, in the paper the employment of interval mathematic is proposed. Several numerical results are presented and discussed in order to assess the effectiveness of the proposed methodology which offer a rough qualitative insight of the solution in a very short time, comparable to the time required for a deterministic numerical simulation.

[EN] The objective of this article is to compare the behaviour of the most representative domestic hot water systems (DHW) in single-family buildings. The study evaluates the energy consumption, equivalent CO2 emissions and cost for each system over a 15-year life period. This analysis is carried out in four cli- matic zones across Europe to observe the influence of climatic conditions on the results. The four climatic zones are located in the cities of Athens, Madrid, London and Berlin. The analysed systems are: a) natural gas-fired instantaneous water heaters, b) electric storage water heater, c) solar thermal system with gas- fired instantaneous, d) solar thermal system with electric storage water heater, e) air-source heat pump, f) photovoltaic system with electric storage water heater, and g) photovoltaic system with air-source heat pump. This range of technologies covers the most likely solutions to be implemented across domestic buildings in Europe.The heat pump system (HPWH) with PV considering self-consumption shows the lowest environmen- tal impact in all zones, but is not an attractive investment in the coldest zones due to lower natural gas prices. Thermal solar systems have a high purchase and maintenance costs which do not compensate their energy savings. The PV HPWH system has a greater reduction of emissions and a lower cost than HPWH across a 15-year life. The gas boiler system has the lowest cost in a 15-year period in the coldest areas, despite having a greater environmental impact than the heat pump.(c) 2023 Elsevier B.V. All rights reserved.