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Background: The global palm oil market experienced a remarkable boom since the year 2000. Since palm oil can be used for biodiesel production, the global expansion of oil palm cultivation has been associated with the global biofuel boom. Biofuel policies—especially those adopted in the European Union (EU)—have been blamed for the socio-environmental impacts of oil palm expansion. We explore how the global biofuel boom interacts with national geographies and social-economic and political processes to produce country-specific trajectories of biofuel crops expansion. We analyse the expansion of oil palm cultivation in Colombia between 2000 and 2010 from a political ecology perspective. Methods: The analysis is based on a framework that positions expansion of commodity frontiers within the ‘space-of-flows’ and the ‘space-of-place’. Through this approach, we identify the markets and geographies that define the country-specific trajectories of expansion of oil palm in Colombia, and their connections with general patterns of land control. The empirical analysis is based on primary data collected during fieldwork, and on an extensive review of secondary data about the palm oil sector and the socio-environmental effects of oil palm expansion in the country. Results: The contemporary oil palm expansion in Colombia was not specifically influenced by the international biofuel market. Expansion was characterized by an increasing production of palm oil for biodiesel, to supply a policy-driven national biofuel market controlled by national palm oil producers. The evidence shows that this oil palm expansion proceeded through a variety of land control practices that constitute forms of ‘accumulation by dispossession’ and ‘assimilation’. These are embedded in contextual factors that include the agrarian history of Colombia, the armed conflict, and government policies. Conclusions: Our study shows that the ways in which expansion of biofuel crops unfold in each producing country depend not only on the global biofuel market. They are also shaped by the country-specific geographies and political economies. Therefore, research and policies on the global expansion of energy crops should account for the complex and interrelated factors that mediate the specific ways in which the global demand for biofuels creates biofuel crop booms at country level.

This study focuses on formulating the most sustainable concrete by incorporating recycled concrete aggregates and other products retrieved from construction and demolition (C&D) activities. Both recycled coarse aggregates (RCA) and recycled fine aggregates (RFA) are firstly used to fully replace the natural coarse and fine aggregates in the concrete mix design. Later, the cement rich ultrafine particles, recycled glass powder and mineral fibres recovered from construction and demolition wastes (CDW) are further incorporated at a smaller rate either as cement substituent or as supplementary additives. Remarkable properties are noticed when the RCA (4–12 mm) and RFA (0.25–4 mm) are fully used to replace the natural aggregates in a new concrete mix. The addition of recycled cement rich ultrafines (RCU), Recycled glass ultrafines (RGU) and recycled mineral fibres (RMF) into recycled concrete improves the modulus of elasticity. The final concrete, which comprises more than 75% (wt.) of recycled components/materials, is believed to be the most sustainable and green concrete mix. Mechanical properties and durability of this concrete have been studied and found to be within acceptable limits, indicating the potential of recycled aggregates and other CDW components in shaping sustainable and circular construction practices. The authors wish to acknowledge the financial support from EU Horizon 2020 Project VEEP ‘‘Cost-Effective Recycling of C&DW in High Added Value Energy Efficient Prefabricated Concrete Compo-nents for Massive Retrofitting of our Built Environment” (No.723582).

Current energy market designs and pricing schemes fail to give investors the appropriate market signals. In particular, energy prices are not high enough to attract investors to build new or maintain existing power capacity. In this paper we propose a method to compute second-best Pareto optimal equilibrium prices for any market exhibiting non-convexities and, based on this result, an energy market design able to restore the correct energy price signals for supply investors.

Abstract Global hydropower growth continues to accelerate with 25% of total capacity installed in just the last 10 years. This accelerating expansion and the important storage facility hydropower means it is increasingly important to understand the reasons for operational failures. This is a challenge because the major reason for failures involves the complex interaction of hydraulic, mechanical and electric subsystems. Historically, reliability modelling has been split in two directions, focusing on different sub-systems, and has not yet been unified. Here these approaches are unified with a novel expression of unbalanced forces. This model with operational data are validated and the important modes of oscillation in the shaft are identified. Finally, the mechanism of the first-order oscillation mode exciting a second-order mode is presented. This integrated and accurate mathematical model is a major advance in the diagnosis and prediction of failures in hydropower operation.

The unpredictable nature of wind energy makes its integration to the electric grid highly challenging. However, these challenges can be addressed by incorporating storage devices (batteries) in the system. We perform an overall assessment of a single domestic power system with a wind turbine supported by an energy storage device. The aim is to investigate the best operation mode of the storage device such that the occurrence of large power spills can be minimized. For estimating the small probability of large power spills, we use the splitting technique for rare-event simulations. An appropriate Importance Function for splitting is formulated such that it reduces the work-load of the probability estimator as compared to the conventional Crude Monte Carlo probability estimator. Simulation results show that the ramp constraints imposed on the charging/discharging rate of the storage device plays a pivotal role in mitigating large power spills. It is observed that by employing a new charging strategy for the storage device large power spills can be minimized further. There exists a trade-off between reducing the large power spills versus reducing the average power spills.

Biomass is considered as a potential source of renewable energy. One of the major problems for biomass gasification is the presence of tar in the product gas. We are investigating catalytic behaviour of olivine as a prospective bed additive for biomass gasifiers for tar removal. In the present paper, the pretreatment of olivine is investigated to improve its activity. Pretreatment method includes heating olivine at 900 °C in the presence of air for different treatment times. The catalytic activity of olivine is investigated via steam-reforming reaction of naphthalene as model biomass tar compound. Improvement in naphthalene conversion of around 30% is observed with 1 h of pretreatment. Also effect of pretreatment time is investigated. With increasing pretreatment time, conversion increases; more than 80% naphthalene conversion is observed with 10 h of pretreatment time for olivine. Both steam and dry reforming reaction of naphthalene forms more than 50% gaseous products over 10 h pretreated olivine. Besides the gaseous products and light tars, polymerization reactions occur producing higher tars in small quantity. Naphthalene conversion under syngas mixture is somewhat lower than that of only in steam and CO2. Apparent activation energy of 187 kJ mol-1 is determined for 10 h pretreated olivine under gasification-gas mixture.

The present work focuses on the sampling procedure and quantification of the PAH yield from the fast pyrolysis of waste softwood. In particular, fast pyrolysis experiments were conducted using a CDS Pyroprobe 5200 at temperatures between 500 °C and 1000 °C, at a heating rate of 600 °C/s for a sample size of 30 mg. High performance liquid chromatography (HPLC) was used for the determination of the PAH compounds present in the liquid sample fraction, while a micro – GC was employed for the analysis of the main gaseous products (CO, CO2, CH4 and H2). An alternative tar sampling protocol was proposed, which employed the use of a cold trap (50 °C) and an isopropanol filled impinger bottle for the collection of the condensable products. The experiments were compared to heated foil reactor based pyrolysis tests within the same temperature range and heating rate, except for a slightly lower sample size (10 mg). The Pyroprobe and adapted sampling system proved to be more efficient regarding PAH capture and quantification compared to the heated foil reactor. Naphthalene, acenaphthylene and phenanthrene were the main PAH compounds detected. The PAH yields increased with pyrolysis temperature, up to values corresponding to roughly 0.2 wt% of the overall yield at 1000 °C. From the results it was derived that PAH evolution is mainly a product of secondary decomposition of primary tar, since the char yield stabilized for higher temperatures and the yields of CO, H2 and CH4 increased. Overall mass balance closure values were around 80 wt% on average. Char and gas yields were determined with high reproducibility, however gravimetric liquid analysis lacked due to the inability to gravimetrically measure the yield condensing in the impinger bottle. Future work is aimed on improving on this particular aspect. Overall, the alternative tar sampling system proposed was successful in the quantification of PAH from biomass fast pyrolysis experiments offering increased flexibility, accuracy and practicality of use.

As part of the Copenhagen Accord, individual countries have submitted greenhouse gas reduction proposals for the year 2020. This paper analyses the implications for emission reductions, the carbon price, and abatement costs of these submissions. The submissions of the Annex I (industrialised) countries are estimated to lead to a total reduction target of 12-18% below 1990 levels. The submissions of the seven major emerging economies are estimated to lead to an 11-14% reduction below baseline emissions, depending on international (financial) support. Global abatement costs in 2020 are estimated at about USD 60-100 billion, assuming that at least two-thirds of Annex I emission reduction targets need to be achieved domestically. The largest share of these costs are incurred by Annex I countries, although the costs as share of GDP are similar for Annex I as a group and the seven emerging economies as a group, even when assuming substantial international transfers from Annex I countries to the emerging economies to finance their abatement costs. If the restriction of achieving two-thirds of the emission reduction target domestically is abandoned, it would more than double the international carbon price and at the same time reduce global abatement costs by almost 25%.