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Abstract Tars and alkali ashes from biomass gasification processes currently constitute one of the major problems in biomass valorisation, generating clogging of filters and issues related with the purity of syngas production. To date, these waste residues find no useful applications and they are generally disposed upon generation in the gasification process. A detailed analysis of these residues pointed out the presence of high quantities of Ca (>30 wt%). TG experiments indicated that a treatment under air at moderate temperatures (400–800°C) decomposed the majority of carbon species, while XRD indicated the presence of a crystalline CaO phase. CaO enriched valorized materials turned out to be good heterogeneous catalysts for biodiesel production from vegetable oils, providing moderate to good activities (50%–70% after 12 h) to fatty acid methyl esters in the transesterification of sunflower oil with methanol.

The purpose of this study was to relate regional variation in litter mass-loss rates (first year) in pine forests to climate across a large, continental-scale area. The variation in mass-loss rate was analyzed using 39 experimental sites spanning climatic regions from the subarctic to subtropical and Mediterranean: the latitudinal gradient ranged from 31 °N to 70 °N and may represent the the largest geographical area that has ever been sampled and observed for the purpose of studying biogeochemical processes. Because of unified site design and uniform laboratory procedures, data from all sites were directly comparable and permitted a determination of the relative influence of climate versus substrate quality viewed from the perspective of broad regional scales. Simple correlation applied to the entire data set indicated that annual actual evapotranspiration (AET) should be the leading climatic constraint on mass-loss rates (Radj2 = 0.496). The combination of AET, average July temp. and average annual temp. could explain about 70% of the sites' variability on litter mass-loss. In an analysis of 23 Scots pine sites north of the Alps and Carpatians AET alone could account for about 65% of the variation and the addition of a substrate-quality variable was sufficiently significant to be used in a model. The influence of litter quality was introduced into a model, using data from 11 sites at which litter of different quality had been incubated. These sites are found in Germany, the Netherlands, Sweden and Finland. At any one site most ( ≫ 90%) of the variation in mass-loss rates could be explained by one of the litter-quality variables giving concentration of nitrogen, phosphorus or water solubles. However, even when these models included nitrogen or phosphorus even small changes in potential evapotranspiration resulted in large changes in early-phase decay rates. Further regional subdivision of the data set, resulted in a range of strength in the relationship between loss rate and climatic variables, from very weak in Central Europe to strong for the Scandinavian and Atlantic coast sites (Radj2 = 0.912; AET versus litter mass loss). Much of the variation in observed loss rates could be related to continental versus marine/Atlantic influences. Inland locations had mass-loss rates lower than should be expected on the basis of for example AET alone. Attempts to include seasonality variables were not successful. It is clear that either unknown errors and biases, or, unknown variables are causing these regional differences in response to climatic variables. Nevertheless these results show the powerful influence of climate as a control of the broad-scale geography of mass-loss rates and substrate quality at the stand level. Some of these relationships between mass-loss rate and climatic variables are among the highest ever reported, probably because of the care taken to select uniform sites and experimental methods. This suggest that superior, base line maps of predicted mass-loss rates could be produced using climatic data. These models should be useful to predict the changing equilibrium litter dynamics resulting from climatic change.

As recognized by the Paris Climate Agreement of the United Nations Framework Convention on Climate Change (UNFCCC), local and subnational regions are crucial actors to achieve international mitigation and adaptation commitments. Scientific literature and empirical evidence point at multi-level climate governance as a crucial factor to engage subnational levels in the achievement of national and international objectives. This work focuses on the multi-level climate governance arrangements in Italy to investigate how Italian regions/provinces/cities are contributing to the achievement of national commitments. To this purpose, the paper undertakes a review of the climate policies of different tiers of government adopted to date and of the interrelationships among them. The results of the analysis show that the effective coordination between the different government levels should be strengthened to further incentivize and support initiatives at the local level. Results also show the relevant role played by international regional and city climate networks in boosting local and regional climate planning in Italy.

Abstract Geodiversity and geoheritage studies are multidisciplinary, drawing from all sides of geosciences and extending them into the humanities, geoarchaeology, spatial planning, territorial and risk management, economics, tourism, or culture using integrated and interdisciplinary research approaches. During the last three decades, geodiversity and geoheritage research experienced a considerable growth that confirms both scientific and public relevance of these topics. In this introductory text, a brief review of current literature is presented and the importance of geodiversity and geoheritage for sustainable development, geohazard resilience and associated themes is discussed. Last, but not least, the aims and structure of this volume are outlined.

The Municipal Solid Waste Management (MSWM) sector has developed considerably during the past century, paving the way for maximum resource (materials and energy) recovery and minimising environmental impacts such as global warming associated with it. The current study is assessing the historical development of MSWM in the municipality of Aalborg, Denmark throughout the period of 1970 to 2010, and its implications regarding Global Warming Potential (GWP(100)), using the Life Cycle Assessment (LCA) approach. Historical data regarding MSW composition, and different treatment technologies such as incineration, recycling and composting has been used in order to perform the analysis. The LCA results show a continuous improvement in environmental performance of MSWM from 1970 to 2010 mainly due to the changes in treatment options, improved efficiency of various treatment technologies and increasing focus on recycling, resulting in a shift from net emission of 618 kg CO(2)-eq.tonne(-1) to net saving of 670 kg CO(2)-eq.tonne(-1) of MSWM.

Abstract Successful conservation of large mammals requires vast areas to maintain viable populations. This often requires to embrace large-scale approaches that extend beyond the borders of formally protected areas. However, the quality of the scientific knowledge about animal movement across large conservation areas vary, and could limit the effectiveness of conservation efforts. Here we used GPS tracking to conduct the first study of large-scale movements of African elephants (Loxodonta africana) in Hwange NP (Zimbabwe), which is an unfenced park part of the Kavango-Zambezi Transfrontier Conservation Area, the world's largest terrestrial conservation area. We show that some, but not all, elephants migrate seasonally, with wet- to dry-season movements linked to the provision of water in Hwange NP. The distance between the most distant locations of individual elephants reaches 260 km. In this partial migration system influenced by management practices, over 20% of the elephants have wet-season ranges established in Botswana, outside of protected areas in private or communal wildlife management areas. Our results call for the urgent drafting of a regional action plan, involving all stakeholders identified by our study and their neighbours, to predict and react to what would happen if water provision in Hwange NP was to suddenly change because of management practices or extreme climate change. Beyond this critical conservation issue for the world's largest elephant meta-population, our results also highlight the relevance of large-scale conservation areas combined with integrative planning involving national wildlife management institutions and the private and communal sector.

AbstractToxic effects of heavy metals on soil microorganisms have been confirmed in a number of laboratory studies. However, most real‐field studies do not allow for strong general conclusions due to a range of problems, such as pseudoreplication and confounding factors, which are almost impossible to control for with the most commonly used polluted versus unpolluted or random sampling designs. Effects of metal contamination on soil microbial community traits were measured along 2 pollution gradients in southern Poland. Employing an experimental regression design, using 2 separate gradients, the authors aimed to control for effects of soil properties and beta‐diversity of microbial communities. General microbial activity was measured as soil basal respiration rate and substrate‐induced respiration, while microbial functional and structural diversity were analyzed with community‐level physiological profiles and phospholipid fatty acid patterns, respectively. Metal concentrations were normalized to their toxicity and integrated in a toxicity index (TI). Microbial activity (basal and substrate‐induced respiration) decreased in both gradients with increasing TI. Community‐level physiological profiles for fungi correlated positively with TI, but no impact of TI on the community‐level physiological profiles of bacteria was observed. The phospholipid fatty acids a:15 and i:17 were positively correlated with TI, whereas 16:1ω9 and 18:2ω9 were negatively correlated with TI. The use of 2 gradients (Olkusz and Miasteczko Śląskie) allowed the authors to reveal a clear effect of pollution on general microbial structure and activities, even though they were not able to control completely for all confounding factors. Soil pH, organic matter content, and nutrient level appeared to be at least as important as TI in determining microbial community structure and activities. Environ Toxicol Chem 2013;32:1992–2002. © 2013 SETAC

ENG: In recent years, the floodplain lakes of the Vistula River in Poland have been drying up and the sediments have been transforming into soils. The data show changes in physical and chemical properties between the sediments and the soils that developed from them. The study included texture, pH, hydrolytic acidity, total alkaline cations, total nitrogen, organic carbon, total content of Al, Ca, Fe, K, Mg, Mn, Na, P as well as heavy metals (Cd, Cr, Cu, Ni, Pb, Zn) and their speciation. In addition, a toxicity assessment of both materials was performed. PL: W ostatnich latach starorzecza Wisły wysychają, a osady przekształcają się w gleby. Dane pokazują zmiany właściwości fizycznych i chemicznych między osadami a glebami, które się z nich wykształciły. Badania obejmowały uziarnienie, pH, kwasowość hydrolityczną, całkowitą zawartość kationów zasadowych, azot całkowity, węgiel organiczny, całkowitą zawartość Al, Ca, Fe, K, Mg, Mn, Na, P, a także metali ciężkich (Cd, Cr, Cu, Ni, Pb, Zn) i ich specjację. Ponadto przeprowadzono ocenę toksyczności obydwu materiałów. The study was funded by the National Science Centre Poland under the Miniatura 6 program.