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As smart cities become a global topic, interest in smart mobility, the core of smart cities, is also growing. The technology that comes closest to general users is “autonomous driving”. In particular, the successful market entry and establishment of some private companies proved that “autonomous driving” is not technology of the future but imminent reality. However, safety in autonomous vehicles that rely on sensors instead of the driver’s five senses has been the focus of attention from the beginning and continues to be so. In this study, we attempted to counter this interest. Based on the actual data of thirty traffic accidents, assuming the AEBS (Autonomous Emergency Braking System) was installed to assist the driver in safe driving, it was reinterpreted through simulation to see what changes occurred in the accident. In the computer program, PC-Crash, the results were first analyzed through simulation using Euro NCAP (New Car Assessment Program)’s AEBS test standards. Subsequently, the other variables in the AEBS were controlled and the accident was reinterpreted by changing only the angle of the radar detection sensor. As a result, it was confirmed that a total of 27 accidents out of thirty accidents could have been prevented with the AEBS. In addition, it proved that the crash avoidance rate of vehicles gradually increased as the radar angle increased.

AbstractThis work reports the synthesis, characterization, photophysical, and photovoltaic properties of five new thieno[3,2‐b][1]benzothiophene isoindigo (TBTI)‐containing low bandgap donor–acceptor conjugated polymers with a series of comonomers and different side chains. When TBTI is combined with different electron‐rich moieties, even small structural variations can have significant impact on thin film morphology of the polymer:phenyl C70 butyric acid methyl ester (PCBM) blends. More importantly, high‐resolution electron energy loss spectroscopy is used to investigate the phase‐separated bulk heterojunction domains, which can be accurately and precisely resolved, enabling an enhanced correlation between polymer chemical structure, photovoltaic device performance, and morphology.

Heat energy storage systems were fabricated with the impregnation method using MgO and Mg(OH)2 as supporting materials and polyethylene glycol (PEG-6000) as the functional phase. MgO and Mg(OH)2 were synthesized from the salt Mg(NO3)·6H2O by performing hydrothermal reactions with various precipitating agents. The precipitating agents were NaOH, KOH, NH3, NH3 with pamoic acid (PA), or (NH4)2CO3. The result shows that the selection of the precipitating agent has a significant impact on the crystallite structure, size, and shape of the final products. Of the precipitating agents tested, only NaOH and NH3 with PA produce single-phase Mg(OH)2 as the as-synthesized product. Pore size distribution analyses revealed that the surfaces of the as-synthesized MgO have a slit-like pore structure with a broad-type pore size distribution, whereas the as-synthesized Mg(OH)2 has a mesoporous structure with a narrow pore size distribution. This structure enhances the latent heat of the phase change material (PCM) as well as super cooling mitigation. The PEG/Mg(OH)2 PCM also exhibits reproducible behavior over a large number of thermal cycles. Both MgO and Mg(OH)2 matrices prevent the leakage of liquid PEG during the phase transition in phase change materials (PCMs). However, MgO/PEG has a low impregnation ratio and efficiency, with a low thermal storage capability. This is due to the large pore diameter, which does not allow MgO to retain a larger amount of PEG. The latent heat values of PEG-1000/PEG-6000 blends with MgO and Mg(OH)2 were also determined with a view to extending the application of the PCMs to energy storage over wider temperature ranges.

Structural, optoelectronic, photovoltaic, and supplementary characterization data for “Benzylammonium-Mediated Formamidinium Lead Iodide Perovskite Phase Stabilization for Photovoltaics”, DOI:10.1002/adfm.202101163. Figure_2_XRD.zip: Data described in Figure 2 (XRD patterns) as Origin (.opj) software file. Figure_3_NMR_data.zip: Data described in Figure 3 (NMR spectra) in the file structure of the TopSpin software, which is available from Bruker. Figure_4_spectra.zip: Data described in Figure 4 (UV-vis absorption, PL and IPCE spectra) as Origin (.opj) software files. Figure_5_PV.zip: Data described in Figure 5 (photovoltaic characterization) as Origin (.opj) software files. Figure_6_spectra.zip: Data described in Figure 6 (PLQY and TRPL) as Origin (.opj) and *.csv files. Figure_7_stability.zip: Data described in Figure 7 (stability analysis) as Origin (.opj) software files. Figure_SI.zip: Data described in the Supporting Information Figures S1, S2, S3, S5, and S6 (XRD data, reciprocal space maps, radial profiles of q-maps, UV-vis absorption spectra, PL spectra, and additional photovoltaic characterization) as Origin (.opj), text (.txt), and image (.tiff) files.

The development of a concrete mixture design process for high-quality concrete production with sustainable values is a complex process because of the multiple required properties at the green/hardened state of concrete and the interdependency of concrete mixture parameters. A new multicriteria decision making (MCDM) technique based on Technique of Order Preference Similarity to the Ideal Solution (TOPSIS) methodology is applied to a fuzzy setting for the selection of concrete mix factors and concrete mixture design methods with the aim towards sustainable concrete quality management. Three objective properties for sustainable quality concrete are adopted as criteria in the proposed MCDM model. The seven most dominant concrete mixture parameters with consideration to sustainable concrete quality issues, i.e., environmental (density, durability) and socioeconomic criteria (cost, optimum mixture ingredients ratios), are proposed as sub-criteria. Three mixture design techniques that have potentiality to include sustainable aspects in their design procedure, two advanced and one conventional concrete mixture design method, are taken as alternatives in the MCDM model. The proposed selection support framework may be utilized in updating concrete design methods for sustainability and in deciding the most dominant concrete mix factors that can provide sustainable quality management in concrete production as well as in concrete construction. The concrete mix factors found to be most influential to produce sustainable concrete quality include the water/cement ratio and density. The outcomes of the proposed MCDM model of fuzzy TOPSIS are consistent with the published literature and theory. The DOE method was found to be more suitable in sustainable concrete quality management considering its applicable objective quality properties and concrete mix factors.

Shading the greenhouses is necessary in summer to reduce the solar radiation load. This however generates a considerable amount of thermal radiation heat load that needs to be removed via cooling systems. This study aimed to evaluate the effect of different shading configurations on the solar and thermal radiation in a greenhouse. Nets at four different locations were employed to shade the roof and side-walls of a polycarbonate, mechanically ventilated greenhouse. The spectral radiative properties of all these plastic materials were measured in short and long wave spectrum bands. The net solar and thermal radiations and air temperature were measured outside and inside two identical shaded and unshaded greenhouses. The results showed that external roof-shading is desirable, as it reduced the generated thermal radiation in the greenhouse by 21% and 15% during the day and night time, respectively and reduced the greenhouse air temperature during the day. The internal shading (roof and side walls) is undesirable, since it drastically increased the generated thermal radiation in the greenhouse by 147% and strongly increased the greenhouse air temperature during the day. Shading the side-walls is not recommended because it significantly reduces the transmitted solar radiation in the morning and afternoon (when the outside irradiance is low) and is useless at around noon when the outside irradiance is extremely high.

Room occupancy prediction based on indoor environmental quality may be the breakthrough to ensure energy efficiency and establish an interior ambience tailored to each user. Identifying whether temperature, humidity, lighting, and CO2 levels may be used as efficient predictors of room occupancy accuracy is needed to help designers better utilize the readings and data collected in order to improve interior design, in an effort to better suit users. It also aims to help in energy efficiency and saving in an ever-increasing energy crisis and dangerous levels of climate change. This paper evaluated the accuracy of room occupancy recognition using a dataset with diverse amounts of light, CO2, and humidity. As classification algorithms, K-nearest neighbors (KNN), hybrid Adam optimizer–artificial neural network–back-propagation network (AO–ANN (BP)), and decision trees (DT) were used. Furthermore, this research is based on machine learning interpretability methodologies. Shapley additive explanations (SHAP) improve interpretability by estimating the significance values for each feature for classifiers applied. The results indicate that the KNN performs better than the DT and AO-ANN (BP) classification models have 99.5%. Though the two classifiers are designed to evaluate variations in interpretations, we must ensure that they have accurate detection. The results show that SHAP provides successful implementation following these metrics, with differences detected amongst classifier models that support the assumption that model complexity plays a significant role when predictability is taken into account.

The environmental control and management of municipal solid waste (MSW) dumping sites is considered one of the sensitive challenges faced by executive municipalities. This is especially true in Makkah due to the gradual increase in urban population and visitors, with an overall MSW generation of about one million tons per year. Consequently, the geo-environmental evaluation of the Kaakia dumping site shed light on the potential environmental threats, in terms of ambient air quality levels and meteorological parameters, in addition to geophysical inspection. An air quality survey discussed the major trends of ambient air pollutants (SO2, NO2, CO, O3, CH4, and PM10) downwind from the Kaakia dumping site. It indicated the presence of a significant increase in sporadic plumes of Methane concentration. The maximum hourly averages ranged between 22.9–26.6 µg/m3 for SO2, 44.4–64.0 µg/m3 for NO2, 0.86–1.38 mg/m3 for CO, 150.2–158.8 µg/m3 for O3, 5.09–5.9 ppm for CH4, and 955–994 µg/m3 for PM10. The ground penetrating radar (GPR) geophysical survey indicated the subsurface sequence of three geological layers, as confirmed by nearby bores of the investigated site: (1) a surface layer formed of alluvial sediments of sand, which were 2.5–3.1 m thick; (2) a second layer represented by sand and gravel, with a thickness of 4.6–6.5 m; and (3) a third layer equivalent to saturated alluvial sediments mixed with rock fragments that extended to a depth of 13 m. The signals of the GPR were attenuated at the base of the conducted profiles due to the percolation of generated leachate to the subsurface sequence and contaminated groundwater aquifer.