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As smart cities become a global topic, interest in smart mobility, the core of smart cities, is also growing. The technology that comes closest to general users is “autonomous driving”. In particular, the successful market entry and establishment of some private companies proved that “autonomous driving” is not technology of the future but imminent reality. However, safety in autonomous vehicles that rely on sensors instead of the driver’s five senses has been the focus of attention from the beginning and continues to be so. In this study, we attempted to counter this interest. Based on the actual data of thirty traffic accidents, assuming the AEBS (Autonomous Emergency Braking System) was installed to assist the driver in safe driving, it was reinterpreted through simulation to see what changes occurred in the accident. In the computer program, PC-Crash, the results were first analyzed through simulation using Euro NCAP (New Car Assessment Program)’s AEBS test standards. Subsequently, the other variables in the AEBS were controlled and the accident was reinterpreted by changing only the angle of the radar detection sensor. As a result, it was confirmed that a total of 27 accidents out of thirty accidents could have been prevented with the AEBS. In addition, it proved that the crash avoidance rate of vehicles gradually increased as the radar angle increased.

AbstractThis work reports the synthesis, characterization, photophysical, and photovoltaic properties of five new thieno[3,2‐b][1]benzothiophene isoindigo (TBTI)‐containing low bandgap donor–acceptor conjugated polymers with a series of comonomers and different side chains. When TBTI is combined with different electron‐rich moieties, even small structural variations can have significant impact on thin film morphology of the polymer:phenyl C70 butyric acid methyl ester (PCBM) blends. More importantly, high‐resolution electron energy loss spectroscopy is used to investigate the phase‐separated bulk heterojunction domains, which can be accurately and precisely resolved, enabling an enhanced correlation between polymer chemical structure, photovoltaic device performance, and morphology.

Abstract The variation of properties with temperature have many practical applications in the area of chemical engineering and metallurgy, in the process of extrusion, the materials moving between a feed roll and on carrier belt. Here our intention is to explore the consequences of temperature dependent viscosity and variable thermal conductivity on flow of nanoliquid in a rotating system. Fluid between parallel plates is taken. Energy expression incorporates the exponential heat source. This analysis also explores the attributes of modified Arrhenius energy function with chemical reaction. Boundary layer problems have been computed via NDSolve approach. The obtained solutions are sketched for various estimations of embedded variables of interest. Results pointed out that both axial and transverse velocities show decaying behavior for higher rotation parameter. Thermal field boosts up with an enhancement of thermophoretic and space dependent heat source variables. Moreover the rate of mass transport decays through dimensionless activation energy.

Heat energy storage systems were fabricated with the impregnation method using MgO and Mg(OH)2 as supporting materials and polyethylene glycol (PEG-6000) as the functional phase. MgO and Mg(OH)2 were synthesized from the salt Mg(NO3)·6H2O by performing hydrothermal reactions with various precipitating agents. The precipitating agents were NaOH, KOH, NH3, NH3 with pamoic acid (PA), or (NH4)2CO3. The result shows that the selection of the precipitating agent has a significant impact on the crystallite structure, size, and shape of the final products. Of the precipitating agents tested, only NaOH and NH3 with PA produce single-phase Mg(OH)2 as the as-synthesized product. Pore size distribution analyses revealed that the surfaces of the as-synthesized MgO have a slit-like pore structure with a broad-type pore size distribution, whereas the as-synthesized Mg(OH)2 has a mesoporous structure with a narrow pore size distribution. This structure enhances the latent heat of the phase change material (PCM) as well as super cooling mitigation. The PEG/Mg(OH)2 PCM also exhibits reproducible behavior over a large number of thermal cycles. Both MgO and Mg(OH)2 matrices prevent the leakage of liquid PEG during the phase transition in phase change materials (PCMs). However, MgO/PEG has a low impregnation ratio and efficiency, with a low thermal storage capability. This is due to the large pore diameter, which does not allow MgO to retain a larger amount of PEG. The latent heat values of PEG-1000/PEG-6000 blends with MgO and Mg(OH)2 were also determined with a view to extending the application of the PCMs to energy storage over wider temperature ranges.

Structural, optoelectronic, photovoltaic, and supplementary characterization data for “Benzylammonium-Mediated Formamidinium Lead Iodide Perovskite Phase Stabilization for Photovoltaics”, DOI:10.1002/adfm.202101163. Figure_2_XRD.zip: Data described in Figure 2 (XRD patterns) as Origin (.opj) software file. Figure_3_NMR_data.zip: Data described in Figure 3 (NMR spectra) in the file structure of the TopSpin software, which is available from Bruker. Figure_4_spectra.zip: Data described in Figure 4 (UV-vis absorption, PL and IPCE spectra) as Origin (.opj) software files. Figure_5_PV.zip: Data described in Figure 5 (photovoltaic characterization) as Origin (.opj) software files. Figure_6_spectra.zip: Data described in Figure 6 (PLQY and TRPL) as Origin (.opj) and *.csv files. Figure_7_stability.zip: Data described in Figure 7 (stability analysis) as Origin (.opj) software files. Figure_SI.zip: Data described in the Supporting Information Figures S1, S2, S3, S5, and S6 (XRD data, reciprocal space maps, radial profiles of q-maps, UV-vis absorption spectra, PL spectra, and additional photovoltaic characterization) as Origin (.opj), text (.txt), and image (.tiff) files.

This study searches the impact of tourism growth on emission pollutants in Cyprus (north), which is a small island in the Mediterranean and has shown significant development in hotel and casino sectors in the last two decades. Results from time-series analyses reveal that an inverted U-shaped EKC hypothesis is confirmed for Cyprus with and without tourism development. Tourism also exerts positively significant and long-term effects on the levels of carbon emissions, revealing that growth in the tourism sector causes degradation in the environment.

Abstract Liquefaction of poly-isoprene based rubber (PIR) was performed using ethanol as a solvent for the production of liquid fuel and chemicals. An autoclave batch reactor was used to perform the ethanolysis of PIR at different temperature ranges (250–375 °C), with different ethanol to PIR ratio (0.5:1 to 4:1), and at different reaction times (15–75mins). The experimental results showed that a maximum yield of 86 wt % was achieved at temperature of 325 °C, ethanol to PIR ratio 1/1, and reaction time of 30 min. This liquid oil yield is about 14% higher than the yield obtained from the pyrolysis of PIR at 500 °C and about 10% higher than the yield obtained from hydrothermal liquefaction of PIR at 375 °C. Moreover, the utilization of ethanol in the process was also incorporated and product yields were redefined. Furthermore, ethanol contributed to enhance the quality of liquid-oil, particularly in term of viscosity, acidity, and energy density. Furthermore, the FTIR analysis showed methyl and methylene were most dominating functional groups found in the liquid product and GCMS analysis identified that they were presented by alkenes, aromatics, and alkyls.

Shading the greenhouses is necessary in summer to reduce the solar radiation load. This however generates a considerable amount of thermal radiation heat load that needs to be removed via cooling systems. This study aimed to evaluate the effect of different shading configurations on the solar and thermal radiation in a greenhouse. Nets at four different locations were employed to shade the roof and side-walls of a polycarbonate, mechanically ventilated greenhouse. The spectral radiative properties of all these plastic materials were measured in short and long wave spectrum bands. The net solar and thermal radiations and air temperature were measured outside and inside two identical shaded and unshaded greenhouses. The results showed that external roof-shading is desirable, as it reduced the generated thermal radiation in the greenhouse by 21% and 15% during the day and night time, respectively and reduced the greenhouse air temperature during the day. The internal shading (roof and side walls) is undesirable, since it drastically increased the generated thermal radiation in the greenhouse by 147% and strongly increased the greenhouse air temperature during the day. Shading the side-walls is not recommended because it significantly reduces the transmitted solar radiation in the morning and afternoon (when the outside irradiance is low) and is useless at around noon when the outside irradiance is extremely high.