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Microbes harbor many traits that are dispensable or even unfavorable under industrial and laboratory settings. The elimination of such traits could improve the host's efficiency, genetic stability, and robustness, thereby increasing the predictability and boosting its performance as a microbial cell factory. We engineered solvent-tolerant Pseudomonas taiwanensis VLB120 to yield streamlined chassis strains with higher growth rates and biomass yields, enhanced solvent tolerance, and improved process performance. In total, the genome was reduced by up to 10%. This was achieved by the elimination of genes that enable the cell to swim and form biofilms and by the deletion of the megaplasmid pSTY and large proviral segments. The resulting strain GRC1 had a 15% higher growth rate and biomass yield than the wildtype. However, this strain lacks the pSTY-encoded efflux pump TtgGHI, rendering it solvent-sensitive. Through reintegration of ttgGHI by chromosomal insertion without (GRC2) and with (GRC3) the corresponding regulator genes, the solvent-tolerant phenotype was enhanced. The generated P. taiwanensis GRC strains enlarge the repertoire of streamlined chassis with enhanced key performance indicators, making them attractive hosts for biotechnological applications. The different solvent tolerance levels of GRC1, GRC2, and GRC3 enable the selection of a fitting host platform in relation to the desired process requirements in a chassis à la carte principle. This was demonstrated in a metabolic engineering approach for the production of phenol from glycerol. The streamlined producer GRC1Δ5-TPL38 outperformed the equivalent nonstreamlined producer VLB120Δ5-TPL38 concerning phenol titer, rate, and yield, thereby highlighting the added value of the streamlined chassis.

Abstract For a successful transition from internal combustion engines to electric vehicles and from conventional power plants to renewable energy supply, battery technology plays a vital role. Accordingly, battery research and development (R&D) efforts have been increased considerably over the past decades, particularly regarding materials and cell chemistries to further improve the electrochemical performance of lithium ion batteries. The impetus behind such massive R&D has been the replacement of metallic lithium anodes, a notorious for potentially catastrophic shorting by lithium metal dendrites. However, despite the promise of a step improvement in energy density outperforming established LIB technology, the commercial introduction of cells with alternative anode materials in the mass market is slow. Against this backdrop, the aim of the present study is to provide an overview of current developments in the academic and industrial research arena, summarising the historical development of scientific literature and patent landscape beyond established anode materials. The study identifies and critically reviews tin, silicon, silicon oxide, aluminium and titanium-based anode materials as promising pathways to develop high-energy density next-generation LIBs.

Renewable energy projects, such as wind farms and hydropower dams, can indirectly benefit biodiversity by mitigating climate change. However, we explain why such indirect benefits should not contribute towards the accounting of project-level net biodiversity outcomes and provide guidance on the steps needed to legitimately claim no-net-loss of biodiversity.

Studying the thermal performance of Double Skin Facades (DSFs) with vertical layers has dominated the literature,however, there is still a lack of in-depth research on the performance of DSFs with atypical geometries suchas folded cases which can be applied to Building Integrated Photovoltaic (BIPV) systems to improve their performance.To this end, the study evaluates the influence of the fold geometry on heat transfer, flow structure, andairflow rate in the Folded DSF cavities under a hot climate in Iran using an efficient method titled “patching”; themethod integrates Soltrace3 with a 2D steady-state CFD model by ANSYS-Fluent. The results show that the foldposition and its depth can alter the DSFs performance significantly; the higher the fold depth the more distortionof the flow field inside the cavity; from a practical perspective, the fold position in the upper part of the cavity issuitable for BIPVs application since it can capture 250% higher amount of solar radiation compared to a conventionalvertical-layer DSF as the Base Case; the net heat gain through outer layer could improve with increaseof fold depth and reach at least 33% higher than the Base Case, meanwhile, the total electricity generationpotential of folded cases could be up to 169% higher than the Base Case; thus, the study proved that if thearchitectural design is of interest, it is highly recommended to consider folded DSFs as a design option.

We analyzed the role of primary and postoperative low linear energy transfer radiotherapy in 538 patients treated for salivary gland cancer in centers of the Dutch Head and Neck Oncology Cooperative Group, in search for prognostic factors and dose response.The tumor was located in the parotid gland in 59%, submandibular gland in 14%, oral cavity in 23%, and elsewhere in 5%. In 386 of 498 patients surgery was combined with radiotherapy, with a median dose of 62 Gy. Median delay between surgery and radiotherapy was 6 weeks. In the postoperative radiotherapy group, adverse prognostic factors prevailed. Elective radiotherapy to the neck was given in 40%, with a median dose of 50 Gy. Primary radiotherapy (n = 40) was given for unresectable disease or M(1), with a dose range of 28-74 Gy.Postoperative radiotherapy improved 10-year local control significantly compared with surgery alone in T(3-4) tumors (84% vs. 18%), in patients with close (95% vs. 55%) and incomplete resection (82% vs. 44%), in bone invasion (86% vs. 54%), and perineural invasion (88% vs. 60%). Local control was not correlated with interval between surgery and radiotherapy. No dose-response relationship was shown. Postoperative radiotherapy significantly improved regional control in the pN(+) neck (86% vs. 62% for surgery alone). A rating scale for different sites, T stage, and histologic type may be applied to calculate the risk of disease in the neck at presentation, and so indicate the need for elective neck treatment. A marginal dose-response was seen, in favor of a dose > or =46 Gy. A clear dose-response relationship was shown for patients treated with primary radiotherapy. Five-year local control was 50% with a dose of 66-70 Gy.Postoperative radiotherapy with a dose of at least 60 Gy is indicated for patients with T(3-4) tumors, incomplete or close resection, bone invasion, perineural invasion, and pN(+). In unresectable tumors, a dose of at least 66 Gy is advisable.

Gas-based power plants have attracted more attention in providing electrical energy worldwide because of their lower costs and air pollution. In addition, the use of multi-carrier energy systems has several advantages, such as sustainability benefits and improving performance in supplying the energy demand. This study aims to optimize the total operation cost of multi-carrier energy systems considering the uncertain parameters. The storage technology and consumption side assist the operator in achieving lower costs based on conceptions of demand response programs. Therefore, this study presents a comprehensive mathematical model for the coordinated operation of integrated multi-carrier energy systems while the operational constraints of both gas and power networks are considered. Furthermore, this paper utilizes a new uncertainty modeling method based on Hong's two-point estimate method for addressing the uncertainties of load consumption and wind generation. The proposed model is applied to a gas and power multi-carrier energy system through four case studies. The results affirm the high performance of the presented method and investigate the influence of demand response programs in both sides of energy carriers.

Accurate wind power forecasting is one of the most important operations within the economic dispatch problem to increase the performance of power and energy systems. Accordingly, this study proposes a cyber-resilient hybrid approach based on the Federated Learning and Convolutional Neural Network (CNN) procedure for short-term wind power generation forecasting in different regions of Iran. Generalizability, data independence, forecasting for regions where no training data is available, and preserving the security and privacy of data are prominent features of the proposed method. The federated network was designed with an architecture of 9 clients to perform the training process and extract the salient features from the data associated with each region in each client via the CNN technique. Then, the generalized global supermodel is produced based on the extracted features in each client to forecast the wind power in new and unknown regions such as Mahshahr, Bojnord, and Lootak that had no training data available and had no effect on global supermodel generation. Various scenarios were developed to test the robustness of the suggested methodology. In the first scenario, wind power forecasting is performed based on the suggested technique. In this scenario, the accuracy of the generalized supermodel to forecast wind power generation in each of the Mahshahr, Bojnord, and Lootak regions is 84%, 85%, and 74%, respectively. The second scenario models the scaling attack by changing the wind speed parameters to evaluate the performance of forecasting models against the data integrity attack. In this scenario, an evaluation of the forecast results based on various performance metrics is conducted highlighting the accuracy reduction of the forecast model, due to the damage caused by cyber-attacks on the input data. In the third scenario, the detection of cyber-attack is done based on the image processing-based technique. The presented results emphasize the accurate performance and high generalizability of the cyber-resilient global supermodel in forecasting wind power in various regions of Iran.

Humic-like substances (HULIS) account for a major redox-active fraction of biomass burning organic aerosols (BBOA). During atmospheric transport, fresh acidic BB-HULIS in droplets and humid aerosols are subject to neutralization and pH-modified aging process. In this study, solutions containing HULIS isolated from wood smoldering emissions were first adjusted with NaOH and NH3 to pH values in the range of 3.6-9.0 and then aged under oxic dark conditions. Evolution of HULIS oxidative potential (OP) and total peroxide content (equivalent H2O2 concentration, H2O2eq) were measured together with the changes in solution absorbance and chemical composition. Notable immediate responses such as peroxide generation, HULIS autoxidation, and an increase in OP and light absorption were observed under alkaline conditions. Initial H2O2eq, OP, and absorption increased exponentially with pH, regardless of the alkaline species added. Dark aging further oxidized the HULIS and led to pH-dependent toxic and chemical changes, exhibiting an alkaline-facilitated initial increase followed by a decrease of OP and H2O2eq. Although highly correlated with HULIS OP, the contributions of H2O2eq to OP are minor but increased both with solution pH and dark aging time. Alkalinity-assisted autoxidation of phenolic compounds and quinoids with concomitant formation of H2O2 and other alkalinity-favored peroxide oxidation reactions are proposed here for explaining the observed HULIS OP and chemical changes in the dark. Our findings suggest that alkaline neutralization of fresh BB-HULIS represents a previously overlooked peroxide source and pathway for modifying aerosol redox-activity and composition. Additionally, these findings imply that the lung fluid neutral environment can modify the OP and peroxide content of inhaled BB-HULIS. The results also suggest that common separation protocols of HULIS using base extraction methods should be treated with caution when evaluating and comparing their composition, absorption, and relative toxicity.