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This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

The influence of compost on the growth of bean plants irrigated with As-contaminated waters and its influence on the mobility of As in the soils and the uptake of As (as NaAs(III)O2) by plant components was studied at various compost application rates (3·10(4) and 6·10(4) kg ha(-1)) and at three As concentrations (1, 2 and 3 mg kg(-1)). The biomass and As and P concentrations of the roots, shoots and beans were determined at harvest time, as well as the chlorophyll content of the leaves and nonspecific and specifically bound As in the soil. The bean plants exposed to As showed typical phytotoxicity symptoms; no plants however died over the study. The biomass of the bean plants increased with the increasing amounts of compost added to the soil, attributed to the phytonutritive capacity of compost. Biomass decreased with increasing As concentrations, however, the reduction in the biomass was significantly lower with the addition of compost, indicating that the As phytotoxicity was alleviated by the compost. For the same As concentration, the As content of the roots, shoots and beans decreased with increasing compost added compared to the Control. This is due to partial immobilization of the As by the organic functional groups on the compost, either directly or through cation bridging. Most of the As adsorbed by the bean plants accumulated in the roots, while a scant allocation of As occurred in the beans. Hence, the addition of compost to soils could be used as an effective means to limit As accumulation in crops from As-contaminated waters.

AbstractThe potential impacts of future climate scenarios on water balance and flow regime are presented and discussed for a temporary river system in southern Italy. Different climate projections for the future (2030–2059) and the recent conditions (1980–2009) were investigated. A hydrological model (Soil and Water Assessment Tool) was used to simulate water balance at the basin scale and streamflow in a number of river sections under various climate change scenarios, based on different combinations of global and regional models (global circulation models and regional climate models). The impact on water balance components was quantified at the basin and subbasin levels as deviation from the baseline (1980–2009), and the flow regime alteration under changing climate was estimated using a number of hydrological indicators. An increase in mean temperature for all months between 0.5–2.4 °C and a reduction in precipitation (by 4–7%) was predicted for the future. As a consequence, a decline of blue water (7–18%) and total water yield (11–28%) was estimated. Although the river type classification remains unvaried, the flow regime distinctly moves towards drier conditions and the divergence from the current status increases in future scenarios, especially for those reaches classified as I‐D (ie, intermittent‐dry) and E (ephemeral). Hydrological indicators showed a decrease in both high flow and low flow magnitudes for various time durations, an extension of the dry season and an exacerbation of extreme low flow conditions. A reduction of snowfall in the mountainous part of the basin and an increase in potential evapotranspiration was also estimated (4–4.4%). Finally, the paper analyses the implications of the climate change for river ecosystems and for River Basin Management Planning. The defined quantitative estimates of water balance alteration could support the identification of priorities that should be addressed in upcoming years to set water‐saving actions.

An experiment in open-top chambers was carried out in summer 2008 in Curno (northern Italy) in order to study the effects of ozone and drought stress on net photosynthesis, growth and stable isotope partitioning on cuttings of an ozone-sensitive poplar clone (Oxford). The biomass (as dry weight) of stems, leaves and roots was assessed five times during the growing season on a set of plants intended for destructive measurements (set 1). Another set of plants (set 2) was used for repeated measurements (net photosynthesis) and then destroyed at the end of the experiment. The dry weight of the stems in set 1 plants was calculated using allometric relations. The results showed that drought stress had a strong effect on all the parameters assessed. Ozone did not have any effect on biomass allocation in woody stems and stable isotope composition but reduced root/shoot ratios and caused loss of leaves during the growing season. The loss of leaves in the lower part of the crown was partly recovered with the emission of new young leaves in the upper part, thus restoring the overall photosynthetic apparatus. We conclude that the metabolic costs suffered to repair damage and support growth, and the reduction in starch reserves in the roots can compromise growth and the capacity to cope with stress factors in subsequent years.

&lt;p&gt;The non-perennial streams and rivers are predominant in the Mediterranean region and play an important ecological role in the ecosystem diversity in this region. This class of streams is particularly vulnerable to climate change effects that are expected to amplify further under most climatic projections. Understanding the potential response of the hydrologic regime attributes to climatic stress helps in planning better conservation and management strategies. Bouregreg watershed (BW) in Morocco, is a strategic watershed for the region with a developed non-perennial stream network, and with typical assets and challenges of most Mediterranean watersheds. In this study, a hybrid modeling approach, based on the Soil and Water Assessment Tool (SWAT) model and Indicator of Hydrologic Alteration (IHA) program, was used to simulate the response of BW's stream network to climate change during the period: 2035-2050. Downscaled daily climate data from the global circulation model CNRM-CM5 were used to force the hybrid modeling framework over the study area. Results showed that, under the changing climate, the magnitude of the alteration will be different across the stream network; however, almost the entire flow regime attributes will be affected. Under the RCP8.5 scenario, the average number of zero-flow days will rise up from 3 to 17.5 days per year in some streams, the timing of the maximum flow was calculated to occur earlier by 17 days than in baseline, and the timing of the minimal flow should occur later by 170 days in some streams. The used modeling approach in this study contributed in identifying the most vulnerable streams in the BW to climate change for potential prioritization in conservation plans.&lt;/p&gt;

Aiming to retard the self-polymerization of the reaction intermediates during bio-oil upgrading process, a large amount of alcohol (e.g., 50 wt% with respect to bio-oil) was used in the stabilization of fast pyrolysis oil by esterification before hydrotreatment by the authors in a previous work. In order to reduce the amount of alcohol use and hence improve the process economy, effects of stabilizing fast pyrolysis oil by esterification with methanol, ethanol or glycerol at a small loading (5 wt% w.r.t. bio-oil) in the presence of Amberlyst-35 DRY - A solid acid catalyst on the subsequent hydrotreatment of the oil were investigated. The bio-oil hydrotreatment experiments were carried out at 300 and 350 °C in a combined batch and semi-batch operation mode with Ru/C catalyst. The results demonstrated that, although stabilization of the pyrolysis oil by esterification with a small alcohol loading had least effects on the mass and carbon distribution in the hydrotreatment products and the elemental composition of the hydrotreated oil products, it could effectively reduce the molecular weight of the feed, prevent self-polymerization and decrease the overall molecular weight of the hydrotreated oil products.

Water quality agencies and scientists are increasingly adopting standardized sampling methodologies because of the challenges associated with interpreting data derived from dissimilar protocols. Here, we compare 13 protocols for monitoring streams from different regions and countries around the globe. Despite the spatially diverse range of countries assessed, many aspects of bioassessment structure and protocols were similar, thereby providing evidence of key characteristics that might be incorporated in a global sampling methodology. Similarities were found regarding sampler type, mesh size, sampling period, subsampling methods, and taxonomic resolution. Consistent field and laboratory methods are essential for merging data sets collected by multiple institutions to enable large-scale comparisons. We discuss the similarities and differences among protocols and present current trends and future recommendations for monitoring programs, especially for regions where large-scale protocols do not yet exist. We summarize the current state in one of these regions, Latin America, and comment on the possible development path for these techniques in this region. We conclude that several aspects of stream biomonitoring need additional performance evaluation (accuracy, precision, discriminatory power, relative costs), particularly when comparing targeted habitat (only the commonest habitat type) versus site-wide sampling (multiple habitat types), appropriate levels of sampling and processing effort, and standardized indicators to resolve dissimilarities among biomonitoring methods. Global issues such as climate change are creating an environment where there is an increasing need to have universally consistent data collection, processing and storage to enable large-scale trend analysis. Biomonitoring programs following standardized methods could aid international data sharing and interpretation.