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Abstract Fractures along interfaces between host rock and wellbore cement have long been identified as potential CO2 leakage pathways from subsurface CO2 storage sites. As a consequence, cement alteration due to exposure to CO2 has been studied extensively to assess wellbore integrity. Previous studies have focused on the changes to either chemical or mechanical properties of cement upon exposure to CO2-enriched brine, but not on the effects of loading conditions. This paper aims to correct this deficit by considering the combined effects of the fracture pathway and changing effective stress on chemical and mechanical degradation at conditions relevant to geologic carbon storage. Flow-through experiments on fractured cores composed of cement and tight sandstone caprock halves were conducted to study the alteration of cement due to exposure to CO2-enriched brine at 3, 7, 9, and 12 MPa effective stress. We characterized relevant reactions via solution chemistry; fracture permeability via changes to differential pressure; mechanical changes via micro-hardness testing, and pore structure changes via x-ray tomography. This study showed that the nature and the rates of the chemical reactions between cement and CO2 were not affected by the effective stress. The differences in the permeability responses of the fractures were attributed to interactions among the geometry of the flow path, the porosity increase of the reacted cement, and the mechanical deformation of reacted asperities. The suite of observed chemical reactions contributed to change in cement mechanical properties. Compared to the unreacted cement, the average hardness of the amorphous silica and depleted layers was decreased while the hardness of the calcite layer was increased. Tomographic imaging showed that preferential flow paths formed in some of the core-flood experiments, which had a significant impact on the permeability response of the fractured samples. We interpreted the observed permeability responses in terms of competition between dissolution of cement phases (leading to enhanced permeability) and mechanical deformation of reacted regions (leading to reduced permeability).

Abstract This paper uses research-quality, ground measurements of irradiance and temperature that are accurate to ±2% to estimate the electric energy yield of fixed solar modules for utility-scale solar power plants at 18 sites in Saudi Arabia. The calculation is performed for a range of tilt and azimuth angles and the orientation that gives the optimum annual energy yield is determined. A detailed analysis is presented for Riyadh including the impact of non-optimal tilt and azimuth angles on annual energy yield. It is also found that energy yield in March and October are higher than in April and September, due to milder operating temperatures of the modules. A similar optimization of tilt and azimuth is performed each month separately. Adjusting the orientation each month increases energy yield by 4.01% compared to the annual optimum, but requires considerable labour cost. Further analysis shows that an increase in energy yield of 3.63% can be obtained by adjusting the orientation at five selected times during the year, thus significantly reducing the labour requirement. The optimal orientation and corresponding energy yield for all 18 sites is combined with a site suitability analysis taking into account climate, topography and proximity to roads, transmission lines and protected areas. Six sites are selected as having high suitability and high energy yield: Albaha, Arar, Hail, Riyadh, Tabuk and Taif. For these cities the optimal tilt is only slightly higher than the latitude, however the optimum azimuth is from 20° to 53° west of south due to an asymmetrical daily irradiance profile.

The need for an improved control strategy for the operation of a wind-powered refrigeration system for the storage of apples was investigated. The results are applicable to other systems which employ intermittently available power sources, battery and thermal storage, and an auxiliary, direct current power supply. Tests were conducted on the wind-powered refrigeration system at the Virginia Polytechnic Institute and State University Horticulture Research Farm in Blacksburg, Virginia. Tests were conducted on the individual components of the system. In situ windmill performance were also conducted. The results of these tests have been presented. An improved control strategy was developed to improve the utilization of available wind energy and to reduce the need for electrical energy from an external source while maintaining an adequate apple storage environment. Ph. D.

AbstractElevated CO2 concentration has been reported to decrease grain nutrient concentrations and thus worsen nutritional deficiency and hidden hunger. One nutritional aspect is mineral content, yet mineral bioavailability can be limited by the presence of phytic acid. Given that future climate scenarios predict elevated global temperature driven by elevated atmospheric CO2 concentrations, we used Temperature by Free‐Air CO2 Enrichment (T‐FACE) field experiments to investigate whether elevated temperature alters the effects of elevated CO2 on grain mineral concentrations, grain mineral yields, and their bioavailability in a range of wheat and rice genotypes. We found that the negative effects of elevated CO2 were compensated for by positive effects of elevated temperature. As a result, the combined elevated CO2 and elevated temperature increased concentrations of some minerals by up to ~15% in both rice and wheat relative to control conditions. Moreover, the combined elevated CO2 and elevated temperature did not significantly change total yields of some minerals despite lower grain yields. The combined CO2 and temperature elevation increased phytic acid concentration in rice by 18.1% but decreased it in wheat by 3.5%. The mineral bioavailability, estimated as the mole ratio of phytic acid to minerals in rice and wheat grains, was limited by the combined CO2 and temperature elevation in only a few cases. Our results indicate that under future climate conditions of elevated temperature and CO2, the nutritional quality of rice and wheat with respect to minerals may remain unchanged.

Abstract. Flooding in the Amazon basin is frequently attributed to modes of large-scale climate variability, but little attention is paid to how these modes influence the timing and duration of floods despite their importance to early warning systems and the significant impacts that these flood characteristics can have on communities. In this study, river discharge data from the Global Flood Awareness System (GloFAS 2.1) and observed data at 58 gauging stations are used to examine whether positive or negative phases of several Pacific and Atlantic indices significantly alter the characteristics of river flows throughout the Amazon basin (1979–2015). Results show significant changes in both flood magnitude and duration, particularly in the north-eastern Amazon for negative El Niño–Southern Oscillation (ENSO) phases when the sea surface temperature (SST) anomaly is positioned in the central tropical Pacific. This response is not identified for the eastern Pacific index, highlighting how the response can differ between ENSO types. Although flood magnitude and duration were found to be highly correlated, the impacts of large-scale climate variability on these characteristics are non-linear; some increases in annual flood maxima coincide with decreases in flood duration. The impact of flood timing, however, does not follow any notable pattern for all indices analysed. Finally, observed and simulated changes are found to be much more highly correlated for negative ENSO phases compared to the positive phase, meaning that GloFAS struggles to accurately simulate the differences in flood characteristics between El Niño and neutral years. These results have important implications for both the social and physical sectors working towards the improvement of early warning action systems for floods.

AbstractClimate change poses new and unique challenges that threaten lives and livelihoods. Given the increasing risks and looming uncertainty of climate change, increasing attention has been directed towards adaptation, or the strategies that enable humanity to persist and thrive through climate change the best it can. Though climate change is a global problem often discussed at the national scale, urban areas are increasingly seen as having a distinct role, and distinctive motivation and capacity, for adaptation. The 12 articles in this special issue explore ways of understanding and addressing climate change impacts on urban areas. Together they reveal young but rapidly growing scholarship on how to measure, and then overcome, challenges of climate change. Two key themes emerge in this issue: 1) that we must identify and then overcome current barriers to urban adaptation and 2) frameworks/metrics are necessary to identify and track adaptation progress in urban settings. Both of these themes point to the power of indicators and other quantitative information to inform priorities and illuminate the pathway forward for adaptation. As climate change is an entirely new challenge, careful measurement that enables investment by private and public parties is necessary to provide efficient outcomes that benefit the greatest number of people.

De belangrijkste overwegingen bij een duurzame spieringvisserij zijn: bescherming van de paaistand; reservering van spiering als voedsel voor vogels en roofvis; (baars, snoekbaars), waarbij rekening gehouden moet worden met recente ontwikkelingen in milieuomstandigheden van IJsselmeer en Markermeer. Resultaten van onderzoek, op verzoek van LNV