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In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

Abstract Synthetic hyperaccumulator biomass (SHB) impregnated with Ni, Zn, Cu, Co or Cr was used to conduct 11 experiments in a lab-scale fluidized bed reactor. Two runs with blank corn stover, with no metal added, were also conducted. The reactor was operated in an entrained mode in a oxygen-free (N2) environment at 873 K and 1 atm . The apparent gas residence time through the lab-scale reactor was 0.6 s at 873 K . The material balance for the lab-scale experiments on N2-free basis varied between 81% and 98%. The presence of a heavy metal in the SHB decreased the char yield and increased the tar yield, compared to the blank. The char and gas yields appeared to depend on the form of the metal salt used to prepare the SHB. However, the metal distribution in the product streams did not seem to be influenced by the chemical form of the metal salt used to prepare the SHB. Greater than 98.5% of the metal in the product stream was concentrated in the char formed by pyrolyzing and gasifying the SHB in the reactor. The metal concentration in the char varied between 0.7 and 15.3% depending on the type of metal in the SHB. However, the metal concentration was increased 4 to 6 times in the char compared to the feed.

Microbial fuel cell (MFC) is an emerging biotechnology to convert the organic substrates in wastewater to electricity by anaerobic electrogenic bacteria. The main challenge for MFC research is to elucidate the fundamental mechanisms of electron generation and transfer and to apply these mechanisms to improve the power production in the engineering operation. This study extensively investigated the effects of three inocula (Geobacter sulfurreducens, soil, and wastewater) on the power production and electrochemical characteristics (i.e., internal resistances, Coulombic Efficiency) of MFCs. The results showed that the extents of bacterial adhesion varied between mixed cultures (soil) and pure cultures (G. sulfurreducens). The voltage output increased 30% when bacterial adhesion was well-developed in the soil inocula. Meanwhile, the inoculum types clearly affected the internal resistance (R(in)) and power production of MFCs. Pure culture inoculum (G. sulfurreducens) had the lowest R(in) (165 Omega) and the highest Coulombic Efficiency (CE, 25.8%) and Energy Conversion Efficiency (ECE, 7.2%), while the mixed culture inocula (soil) with the high concentration of nonelectrogenic bacteria, exhibited the highest R(in) (620 Omega), lowest CE (9.2%) and lowest ECE (2.4%). Additionally, a second-order correlation was established between the anode potential (P(A)) and power output while an exponential correlation was established between the difference between anode and cathode potentials (DeltaP(C-A)) and power output.

In this study, pyrolysis of microalgal remnants was investigated for recovery of energy and nutrients. Chlorella vulgaris biomass was first solvent-extracted for lipid recovery then the remnants were used as the feedstock for fast pyrolysis experiments using a fluidized bed reactor at 500 °C. Yields of bio-oil, biochar, and gas were 53, 31, and 10 wt.%, respectively. Bio-oil from C. vulgaris remnants was a complex mixture of aromatics and straight-chain hydrocarbons, amides, amines, carboxylic acids, phenols, and other compounds with molecular weights ranging from 70 to 1200 Da. Structure and surface topography of the biochar were analyzed. The high inorganic content (potassium, phosphorous, and nitrogen) of the biochar suggests it may be suitable to provide nutrients for crop production. The bio-oil and biochar represented 57% and 36% of the energy content of the microalgae remnant feedstock, respectively.

Abstract A dynamic model of vapour compression refrigeration system is developed. The overall model consists of the following basic components: a compressor, a condenser, an expansion valve, an evaporator, an evaporative cooler and a cool storage. The integrated system is referred to as chilled water cooling system with storage (CWCS). The mathematical modelling of the CWC system undertaken in this study predicts the change in state of refrigerant in the system with respect to time. A computer program is developed to solve the dynamic equations along with empirical correlations describing refrigerant properties. Open-loop tests are carried out to study the performance characteristics of the system under varied cooling load and compressor speed. The model is intended to serve as an analytical design tool and to provide a basis for control analysis. Based on a heuristic method, ‘sub-optimal on–off control’ strategies for the chilled water cool storage system are developed using a reduced order model. The methodology of generating such control profiles is illustrated and the tests for optimality show that the control profiles are near optimal. The on–off control scheme is simulated on the full order CWC system. The operating performance of the system is described under several simulated cases. The results show that the control scheme is capable of maintaining the chilled water temperature in the chosen range.

Abstract Bioproducts from biomass feedstocks and organic wastes have shown great potential to address challenges across food-energy-water systems. However, bioproducts production is at an early, nascent stage that requires new inventions and cost-reducing approaches to meet market needs. Biochar, a byproduct of the pyrolysis process, derived from nutrient-rich biomass feedstocks (e.g., cattle manure and poultry litter) is one of these bioproducts that has numerous applications, such as improving soil fertility and crop productivity. This study investigates the market opportunity and sustainability benefits of converting manure to biochar on-site, using a portable refinery unit. Techno-economic and environmental impact assessments are conducted on a real case study in Twin Falls, Idaho, USA. The techno-economic analysis includes a stochastic optimization model to calculate the total cost of biochar production and distribution. The environmental study employs a life cycle assessment method to evaluate the global warming potential of manure-to-biochar production and distribution network. The total cost of biochar production from cattle manure near the feedlots is approximately $237 per metric ton, and total emission is 951 kg CO2 eq. per metric ton. The on-site operation and manure moisture content are two key parameters that can reduce biochar unit price and carbon footprint of manure management. It is concluded that converting cattle manure, using the presented strategy and process near the collection sites can address upstream and midstream sustainability challenges and stimulate the biochar industry.

Water Research Commission (WRC) and National Research Foundation (NRF) of South Africa for funding the project (K5/1480/1/12).

Abstract The catalyst-free two-step process has been developed for biodiesel production using low-grade feedstocks. The first step consists of triglycerides hydrolysis under subcritical water conditions to generate and increase free fatty acid (FFA) content for ethyl ester production. In its subcritical state, water can be used as both a solvent and a reactant for the hydrolysis of triglycerides. The hydrolyzed product mixture is separated by decantation into the oil phase of FFA (upper layer) and a water phase that contains glycerol (lower layer). In the second step, the hydrolyzed products of free fatty acids were successfully esterified to their ethyl ester in supercritical ethanol conditions without any catalyst. Under the sub- and supercritical conditions of water and ethanol, the hydrolysis and the esterification reactions proceed quickly, with a conversion of greater than 98 % after 10−20 min. This two-step process for biodiesel production offers several advantages, such as milder reaction conditions and pollution reduction due to the use of water instead of organic solvents. Also, the glycerol is removed after the hydrolysis reaction so that the backward reaction between the glycerol and the ethyl ester disappears, and lead to the biodiesel yield and quality improvement. The aim of this study is making a comparison between our previous one-step process and the two-step reaction process to find the best pathway for designing and building an integrated reactor. Indeed, the two-step process is more applicable for low-grade feedstocks with a high amount of FFA and water.

Population variation in ecophysiological traits of four co-occurring montane conifers was measured on a large latitudinal gradient to quantitatively assess their potential for response to environmental change. White fir (Abies concolor) had the highest variability, gross photosynthetic rate (Pg), and foliar carbon (C) and nitrogen (N) content. Despite low water use efficiency (WUE), stomatal conductance (gs) of fir was the most responsive to unfavorable environmental conditions. Pinus lambertiana exhibited the least variability in Pg and WUE, and is likely to be the most vulnerable to environmental changes. Pinus ponderosa had an intermediate level of variability, and high needle growth at its higher elevational limits. Pinus Jeffreyi also had intermediate variability, but high needle growth at its southern latitudinal and lower elevational limits. The attributes used to assess tree vigor were effective in predicting population vulnerability to abiotic (drought) and biotic (herbivore) stresses.