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Wide‐bandgap (WBG) perovskite solar cells (PSCs) are acknowledged as promising candidates for tandem solar cells and building photovoltaics. It is well known that cesium‐based all‐inorganic halide WBG perovskites possess the comparable optoelectronic properties as the organic–inorganic counterparts, but exhibit superior thermal stability. Among them, CsPbIBr2 is considered a feasible material for tandem solar cells after balancing the bandgap and stability of the inorganic perovskite. However, CsPbIBr2 PSCs are often subjected to drastic interfacial charge recombination especially in carbon‐based device structure derived from the chemical bonding defects (i.e., uncoordinated Pb2+) naked on CsPbIBr2 soft lattice, which dramatically limits overall efficiency of CsPbIBr2 WBG PSCs. Herein, a trimethyl ammonium salt hexyltrimethylammonium bromide is presented for CsPbIBr2/carbon interfacial modification. Benefiting from the −N+(CH3)3 passivation effect and −C6H13 hydrophobic alkyl chain, the optimal device with highly smooth morphology and sufficient charge extraction exhibits a champion power conversion efficiency of 11.24% and improved long‐term stability with 99.7% and 79.7% efficiency retention under dry air atmosphere and continuous 85 °C thermal stress, indicating the valuable potential application of the lattice solidified CsPbIBr2 WBG PSCs.

Interfacial resistance at electrode‐high Li+ conductive solid electrolytes must be reduced well to develop high‐power all‐solid‐state batteries using oxide‐based solid electrolytes (Ox‐SSBs). Herein, crystalline electrode films of LiCoO2 (LCO) are formed on a high Li+ conductive crystalline‐glass solid electrolyte sheet, Li1.3Al0.3Ti2(PO4)3 (LATP) (σ25 °C = 1 × 10−4 S cm−1), at room temperature by aerosol deposition (AD), and the effects of the annealing temperature on the interfacial resistivities (Rint) at the LCO/LATP are investigated. The Rint visibly increases by annealing over 500 °C with the growth of Co3O4 as a reactant. In contrast, Rint is reduced to ≈100 Ω cm2 by low‐temperature annealing at 250–350 °C due to superior contact through the structural rearrangement of an artificial metastable interface formed by the AD. These results are applied to bulk‐type Ox‐SSB, Li/Li7La3Zr2O12(LLZ)/LCO–LATP, and our best Ox‐SSB delivers a discharge capacity of 100 mA cm−2 at 100 °C.

Abstract We report all-polymer solar cells with new electron-accepting (n-type) polymer nanoparticles, poly(2,7-bis(4-hexylthiophen-2-yl)-9H-fluoren-9-one-co-benzothiadiazole) (BHTF-co-BT), which were in-situ generated during polymerization reaction. The size of the BHTF-co-BT nanoparticles was ca. 5–15 nm with a particular single X-ray diffraction peak (d-spacing=1.3 nm), indicative of a highly ordered crystalline state, while their glass transition temperature was ~140 °C. Their band gap energy and ionization potential were 1.8 eV and 5.7 eV, respectively. The possibility of the BHTF-co-BT nanoparticles as an electron acceptor for both normal-type and inverted-type all-polymer (polymer:polymer) solar cells was examined by employing poly(3-hexylthiophene) (P3HT) as an electron donor. The normal-type P3HT:BHTF-co-BT solar cells exhibited promising open circuit voltage ( V oc =0.67–0.73 V) and fill factor (FF=51.3%), while a three-fold improved short circuit current density and higher V oc (0.77 V) were achieved for their inverted-type solar cells.

Mixed transition metal oxides with high theoretical capacity show great potential to replace carbonaceous anode materials in lithium-ion batteries.

Abstract Economically harvesting energy from a microbial fuel cell (MFC), increasing its electrical power production, and developing its role as a practical energy supply, needs a low-cost and high-performance design of the MFC compartments. According to this strategy, a novel monolithic membrane electrode assembly (MEA) was fabricated and evaluated as an air–cathode in a single-chamber MFC (SCMFC). The MEA was made of bacterial cellulose (BC), conductive multi-walled carbon nanotubes (CNT), and nano-zycosil (NZ). BC, as a nano-celluloses with oxygen barrier property, can maintain anaerobic conditions for the anode compartment. Binder-less CNT coating on BC avoids costly binders such as poly-tetra fluoro ethylene (PTFE) and Nafion and decreases the MEA charge transfer resistance. NZ, as a very cheap modifier, not only prevents the anolyte leakage but also provides more MEA’s active sites for the oxygen reduction reaction (ORR). The electrochemical performance of the MEA was compared to a PTFE- based gas diffusion electrode (GDE) in the SCMFC. The MEA cell provided a pulse power density of 1790 mW/m2, roughly twice as high as the pulse power density of GDE (920 mW/m2). SCMFC’s internal resistance decreased from 1.84 KΩ (with GDE) to 0.8 KΩ (with MEA). Also, the cell’s columbic efficiency increased from 4.2% (with GDE) to11.7% (with MEA). Additionally, the capacitance of the MEA (65 mF) was much higher than the value for GDE (0.73 mF). Thus, the MEA compared to the GDE showed higher performance in the SCMFC for electricity generation and wastewater treatment at a lower cost.

SnOx attracts considerable attention as an anode of lithium‐ion batteries (LIBs) because of its high theoretical capacity. However, SnOx suffers from poor cyclability and rate capability caused by large volume change upon cycling and low conductivity, which severely limits its application for LIBs. Herein, a nanocomposite of Sn/SnO2/C is synthesized for the first time under an elevated pressure originated from the pyrolysis of dimethyltin oxide in a sealed vessel. The Sn/SnO2/C nanocomposite consists of a homogeneous dispersion of Sn and SnO2 nanocrystals (<10 nm) into the carbon matrix, which endows it with an enhanced lithium storage performance. The Sn/SnO2/C nanocomposite delivers an excellent cyclability (0.025% capacity loss per cycle during 1000 cycles at 1 A g−1) with an improved rate performance (243.8 mAh g−1 at 5 A g−1).

Anode with good electrocatalytic capabilities is more specifically required to reduce the ohimic losses during microbial fuel cell (MFC) operation. Highly conductive polymers viz., Polyaniline (PANi) and Polyaniline/Carbon nanotube (PANi/CNT) composite were prepared by in situ oxidative chemical polymerization method. Anodes were fabricated independently by coating PANi and CNT/PANi composites on the surface of SSM. The fabricated electrodes were evaluated as anode against stainless steel mess (SSM) as cathode during MFC operation. Maximum bioelectricity generation was observed in SSM-PANi/CNT-anode with power density of 48 mW/m2 and COD removal efficiency of 80% compared with SSM-PANi-anode (38 mW/m2; 65%) and SSM-anode (28 mW/m2; 58%). Bioelectrochemical characterization of the electrode materials using cyclic voltammetry and electrochemical impedance spectroscopy showed high electrocatalytic activity of PANi/CNT composite electrode. The study concluded the efficiency of PANi/CNT composite electrodes as bioanode in operation of MFCs towards achieving increased bioelectricity production along with wastewater treatment.

Abstract A major component of solar thermal systems is the solar absorber, which converts light into heat. We report on achieving high absorptance, excellent adhesion, and high thermal stability of carbon nanotube-based black coatings by applying a layer of Boehmite (AlOOH) on top of the carbon nanotube (CNT) film by solution-processed spray deposition. The CNT layer made-up by spraying, functions as an absorbing layer and the AlOOH serves as an anti-reflecting and protecting film. The anti-reflecting property of AlOOH layer effectively increases the absorptance of CNT coating by decreasing the reflectance. The effect of the thickness of AlOOH layer on the absorptance, adhesion, and thermal stability of the resulting CNT/AlOOH coating was investigated. The CNT/AlOOH coating with optimized thickness of AlOOH layer shows very high absorptance ( α ) of 0.975. The adhesion of the coating is in the range of 95–100% with significant increase of thermal stability. This new approach is expected to open new possibilities for fabricating low-cost, highly efficient and thermally stable solar-thermal devices which are based on simple coating processes.

AbstractThis paper presents an understanding of the fundamental carrier transport mechanism in hydrogenated amorphous silicon (a‐Si:H)‐based n/p junctions. These n/p junctions are, then, used as tunneling and recombination junctions (TRJ) in tandem solar cells, which were constructed by stacking the a‐Si:H‐based solar cell on the heterojunction with intrinsic thin layer (HIT) cell. First, the effect of activation energy (Ea) and Urbach parameter (Eu) of n‐type hydrogenated amorphous silicon (a‐Si:H(n)) on current transport in an a‐Si:H‐based n/p TRJ has been investigated. The photoluminescence spectra and temperature‐dependent current–voltage characteristics in dark condition indicates that the tunneling is the dominant carrier transport mechanism in our a‐Si:H‐based n/p‐type TRJ. The fabrication of a tandem cell structure consists of an a‐Si:H‐based top cell and an HIT‐type bottom cell with the a‐Si:H‐based n/p junction developed as a TRJ in between. The development of a‐Si:H‐based n/p junction as a TRJ leads to an improved a‐Si:H/HIT‐type tandem cell with a better open circuit voltage (Voc), fill factor (FF), and efficiency. The improvements in the cell performance was attributed to the wider band‐tail states in the a‐Si:H(n) layer that helps to an enhanced tunneling and recombination process in the TRJ. The best photovoltage parameters of the tandem cell were found to be Voc = 1430 mV, short circuit current density = 10.51 mA/cm2, FF = 0.65, and efficiency = 9.75%. Copyright © 2015 John Wiley & Sons, Ltd.