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In this study we show that a chemical ferricyanide cathode can be replaced by a biological oxygen reducing cathode in a plant microbial fuel cell (PMFC) with a new record power output. A biocathode was successfully integrated in a PMFC and operated for 151 days. Plants growth continued and the power density increased reaching a maximum power output of 679 mW/m2 plant growth area (PGA) in a 10 min polarization. The two week record average power densities was 240 mW/m2 PGA. The new records were reached due to the high redox potential of oxygen reduction which was effectively catalyzed by microorganisms in the cathode. This resulted in a 127 mV higher cathode potential of the PMFC with a biocathode than a PMFC with a ferricyanide cathode. We also found that substrate availability in the anode likely limits the current generation. This work is crucial for PMFC application as it shows that PMFC can be a completely sustainable biotechnology with an improved power output.

Hot water heat stores with stratification are a common technology used in solar energy systems and reuse of waste heat. Adding a PCM module at the top of the water tank would give the system higher storage density, and compensate heat loss in the top layer. The work presented here includes experimental results and numerical simulation of the system using an explicit finite-difference method. Experiments and simulations were carried out using different cylindrical PCM modules. With only 1/16 of the volume of the store being PCM, 3/16 of water at the top of the store was held warm for 50% to 200% longer and the average energy density was increased by 20% to 45%. Furthermore, these 3/16 of water were reheated by the heat from the module after being cooled down in only 20 min.

In the last years, even more attention was paid to the alternative fuels that allow both reducing the fossil fuel consumption and the pollutant emissions. Gaseous fuels like methane and hydrogen are the most interesting in terms of engine application. This paper reports a comparison between methane and different methane/hydrogen mixtures in a single-cylinder Port Fuel/Direct Injection spark ignition (PFI/DI SI) engine operating under steady state conditions. It is representative of the gasoline engine for automotive application. Engine performance and exhaust emissions were evaluated. Moreover, 2D-digital cycle resolved imaging was performed with high spatial and temporal resolution in the combustion chamber. In particular, it allows characterizing the combustion by means of the flame propagation in terms of mean radius and velocity. Moreover, the interaction of turbulence with the local flame was evaluated. For both the engine configurations, it was observed that the addition of hydrogen results in a more efficient combustion, even though the engine configuration plays an important role. In PFI mode, the lower density of hydrogen causes a lower energy input. In DI mode, instead, the larger hydrogen diffusivity counteracts the charge stratification especially for larger hydrogen content. © 2016 Elsevier Ltd. All

An increased interest on electric vehicles (EVs) and plug-in hybrid electric vehicles (PHEVs) is dealing with their introduction into low voltage (LV) distribution grids. Lately, analysis on power quality issues has received attention when considering EVs as additional load. The charging of EVs is expected without a centralized coordination in the first years, therefore a study on voltage variations and loading of LV grids is needed to estimate the immediate impact by EVs. In this work, the modeling and simulation of a Danish residential LV grid is conducted considering the two scenarios of dumb charging and overnight charging. The effect of different shares of EVs on voltage variations and transformer loading is assessed and analyzed. Results have shown that if single-phase, 16 A charging is employed, the actual LV grid would withstand the contingency of up to 30–40% of EVs charging overnight.

Due to the increasing awareness of climate change, depletion of natural resources, and increasing world population, companies in the agri-food sector need to redesign their existing supply chains and take into account both the economic and environmental impact of their operations. In practice not all the required information is available in advance due to various sources of uncertainty in agri-food supply chains. In this research a multi-objective two-stage stochastic programming model is proposed to analyse and evaluate the economic and environmental impacts to account for uncertainty in agri-food supply chains. A mushroom supply chain in the Netherlands is presented as an illustrative case study. Optimal production planning decisions calculated with a two-stage stochastic programming model are compared with the results of an equivalent deterministic model. The results of the optimizations show that accounting for stochasticity in important model parameters can reduce the difference between expected and realized economic performance by approximately 4% on average. Moreover, this paper demonstrates that including stochastic model parameters can reduce the environmental impact without compromising the current economic performance. Given the assumptions in the setup of the case study and the available information, it is concluded that applying a 2-stage stochastic programming approach for production planning decisions can lead to improved economic and environmental performance in an agri-food supply chain. New findings in real-life case studies are needed to get profound insights and understanding on the impact of uncertainty on production planning decisions in sustainable agri-food supply chains.

Chemical looping combustion allows a simple separation of CO2 during the combustion of fossil fuels, thanks to the use of regenerable oxygen carriers. In this work, novel materials containing manganese and iron/manganese oxides have been developed via geopolymerization, and characterized in thermogravimetric apparatus and fixed bed reactor. The materials demonstrated suitable characteristics for chemical looping combustion (CLC). The tests conducted in the temperature range 800-900 °C revealed the good performance of the developed oxygen carriers, which also exhibited the ability to release O2 in inert conditions. Efficiencies in CO conversion up to 99% were achieved, as well as some synergies between Fe and Mn oxides gave a beneficial effect toward the oxygen yield. X-ray diffraction analyses of the samples confirmed the effective reduction/oxidation behavior of the materials, as well as the morphological characterization did not reveal dramatic changes of the internal microstructure up to 900 °C

Capítulos en libros The importance of the natural gas sector in the electric power industry has increased substantially over the last decades, reaching 21% generation capacity in Europe in 2016. Generation companies that own gas fired units (GFUs), such us combined cycle gas turbines, have to take into account not only the fuel and the operation and maintenance costs, but also the costs related to the third-party access (TPA) tariffs to the gas network as any other gas consumer. This paper highlights the importance of modeling these TPA tariffs in a proper manner as they represent a significant share of the total operation cost of GFU. In addition, the fact that TPA final costs depend on the daily gas consumption for the whole month, makes traditional short-term unit-commitment (UC) models unable to capture the impact of the new complicating constraints. This paper presents the mathematical formulation of a UC model that models the TPA tariffs to the gas network in a more realistic manner where a joint assessment is formulated for all the units that withdraw gas from the same node of the gas network. The paper includes an example case that illustrates the impact on the optimal hourly scheduling of such detailed modeling, and it compares the results with the standard formulation based on individual cost functions of each thermal unit. info:eu-repo/semantics/publishedVersion

The reversible dissociation/carbonation of metal carbonates, performed in fluidized bed reactors, is one of the most promising technological solution for thermochemical energy storage (TCES) in concentrating solar power plants (CSP). In this framework, the SrCO3/SrO system is receiving increasing interest due to its high energy density (4 GJ/m3) and working temperatures (up to 1200 ?C). As the more investigated CaCO3/CaO couple, also SrO undergoes a dramatic drop of reactivity over multiple carbonation/calcina- tion cycles due to sintering. Even though the potentiality of this system has already been proved by thermo-gravimetric analyses, its actual reaction performances in a fluidized bed are strongly dependent on the gas-solid contact efficiency and heat/mass transfer between the gaseous and solid phase. In this work, the cyclic carbonation/calcination of the SrO/SrCO3 system for TCES-CSP has been investigated by thermo-gravimetric analysis and, for the first time, in a lab-scale fluidized bed rig, thus providing useful applicative insights. A new Al2O3-stabilized composite has been synthesized, i.e. Al2O3 has been added to SrO/SrCO3 system as both sintering inhibitor and flow conditioner. In particular, composite materials with different Al2O3/SrO composition have been synthesized to investigate the ef- fect of the inhibitor amount on both the fluidizability and energy storage performances.