AbstractBiodiesel is widely used pure or mixed with diesel fossil fuel in diesel engines. Standards for determining biodiesel quality establish limits for the values of several physicochemical properties. However, the procedures to determine many properties are time‐consuming and demand specialized personnel and expensive equipment. Other methods to characterize biodiesel, such as electrical methods, are particularly interesting. Measurements of electrical properties (permittivity and conductivity) give valuable information about biodiesel, its feedstocks, and its blends with fossil fuel diesel, and solve the usual cost and time drawbacks. This work aims to present a thorough and systematic review of the literature on applications of electrical properties measurements of biodiesel, its feedstocks, and mixtures with other fuels. An overview of the experimental data, typical ranges of values, prediction models, and applications is presented and analyzed in detail, emphasizing blends of biodiesel with fossil fuel diesel. Correlations with important properties (kinematic viscosity, methanol content) are reviewed. Applications include transesterification monitoring, biodiesel aging, the detection of contaminants and electromagnetic heating. This research aimed to determine whether electrical properties are a valuable tool for the biodiesel industry, and what applications may be realized in light of current scientific development. It was determined that, in the current state of research, permittivity measurements could be used to accurately determine the amount of diesel and biodiesel in mixtures. © 2023 Society of Industrial Chemistry and John Wiley & Sons Ltd.