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Biomass‐Derived Catalysts for Selective Hydrogenation of Nitroarenes

pmid: 28650569
AbstractDevelopment of catalytically active materials from biowaste represents an important aspect of sustainable chemical research. Three heterogeneous materials were synthesized from inexpensive biomass‐based chitosan and abundant Co(OAc)2 using complexation followed by pyrolysis at various temperatures. These materials were applied in the catalytic hydrogenation of nitroarenes using molecular hydrogen. A variety of diversely functionalized nitroarenes including some pharmaceutically active compounds were converted into aromatic amines in high yields, with high selectivity, and with excellent functional group tolerance. This green protocol has also been implemented for the synthesis of a biologically important TRPC3 inhibitor.
- Roche (Switzerland) Switzerland
- Universidad Albert Einstein El Salvador
- L Hoffman La Roche Switzerland
- University of Rostock Germany
- Roche (Switzerland) Switzerland
Biomass, Hydrogenation, Nitro Compounds, Hydrocarbons, Aromatic, Catalysis
Biomass, Hydrogenation, Nitro Compounds, Hydrocarbons, Aromatic, Catalysis
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).71 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Top 1% influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Top 10% impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Top 1%
