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Article . 2016 . Peer-reviewed
License: Wiley TDM
Data sources: Crossref
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Cobalt Sulfide as Counter Electrode in p-Type Dye-Sensitized Solar Cells

Authors: Congiu, Mirko; BONOMO, MATTEO; DE MARCO, MARIA LETIZIA; Dowling, Denis P.; Di Carlo, Aldo; DINI, DANILO; Graeff, Carlos F. O.;

Cobalt Sulfide as Counter Electrode in p-Type Dye-Sensitized Solar Cells

Abstract

We proposed a novel application of cobalt sulfide (CoS) in the configuration of transparent thin film as anode in p-type dye-sensitized solar cell (p-DSC). The anodes here considered have been prepared using a water-based method that is suitable for the large scale production of large-area electrodes. The photoactive cathodes of the p-DSC were mesoporous nickel oxide (NiO) thin films deposited via rapid discharge sintering. The NiO electrodes were sensitized with the benchmark dye erythrosine B (ERY), while the couple I−/I3− was the redox mediator. The CoS anodes showed higher electrocatalytic efficiency in comparison with the commonly used platinized Fluorine-doped Tin Oxide (Pt-FTO). This was determined by means of electrochemical impedance spectroscopy of CoS based dummy cells, with CoS showing a lower charge-transfer resistance with respect to Pt-FTO. The overall conversion efficiency of the p-DSC employing ERY-sensitized NiO as photoactive cathode and CoS anode was 0.026 %, a value very close to that obtained with Pt-FTO anodes (0.030 %). The external quantum efficiency spectra of the p-DSCs with CoS anodes were similar to those obtained with Pt-FTO anodes under illumination with AM 1.5 solar simulator.

Countries
Italy, Brazil
Keywords

Cobalt sulfide, P-type solar cell, solar energy, cobalt sulfide; dye sensitized solar cells; solar energy, 500, Dye Sensitized Solar Cells, Counter electrode

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    22
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    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
22
Top 10%
Average
Top 10%
Related to Research communities
Energy Research