Abstract The common approach for libraries to preserve their paper-based collections from irreversible deterioration is by controlling quantitative parameters, such as temperature and relative humidity. Variations of these parameters for preventive conservation can be expressed by the “performance index” (PI) and the “amplitude index” (AI). Building envelope is the first filter of the external climate, buffering the external weather fluctuations and maintaining the building's indoor climate stable. Its shape, window areas and envelope materials are the most influential parameters. As they capture the relationship of a few geometric and physical variables with the building's performance, the envelope characteristics can be expressed as certain passive envelope indexes. This paper studies the relationship of certain passive envelope indexes and the preventive conservation indexes for books for several libraries and archives located in La Plata, Argentina. The results show the impact of every passive envelope index upon the preventive conservation indexes. The compactness, heaviness, adjacency to spaces and adjacency to ground have a positive linear correlation meanwhile transparency and global transmittance are parameters with a negative correlation. In general, the most influential parameter is the relative area adjacent to other spaces, followed by global transmittance, transparency, heaviness, relative area adjacent to ground and compactness.