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Application of hydrides in hydrogen storage and compression: Achievements, outlook and perspectives

Authors: Mykhaylol V. Lototskyy; Martin Dornheim; Andreas Züttel; Andreas Züttel; Gavin S. Walker; Craig E. Buckley; Emil H. Jensen; +23 Authors

Application of hydrides in hydrogen storage and compression: Achievements, outlook and perspectives

Abstract

Metal hydrides are known as a potential efficient, low-risk option for high-density hydrogen storage since the late 1970s. In this paper, the present status and the future perspectives of the use of metal hydrides for hydrogen storage are discussed. Since the early 1990s, interstitial metal hydrides are known as base materials for Ni – metal hydride rechargeable batteries. For hydrogen storage, metal hydride systems have been developed in the 2010s [1] for use in emergency or backup power units, i. e. for stationary applications. With the development and completion of the first submarines of the U212 A series by HDW (now Thyssen Krupp Marine Systems) in 2003 and its export class U214 in 2004, the use of metal hydrides for hydrogen storage in mobile applications has been established, with new application fields coming into focus. In the last decades, a huge number of new intermetallic and partially covalent hydrogen absorbing compounds has been identified and partly more, partly less extensively characterized. In addition, based on the thermodynamic properties of metal hydrides, this class of materials gives the opportunity to develop a new hydrogen compression technology. They allow the direct conversion from thermal energy into the compression of hydrogen gas without the need of any moving parts. Such compressors have been developed and are nowadays commercially available for pressures up to 200 bar. Metal hydride based compressors for higher pressures are under development. Moreover, storage systems consisting of the combination of metal hydrides and high-pressure vessels have been proposed as a realistic solution for on-board hydrogen storage on fuel cell vehicles. In the frame of the “Hydrogen Storage Systems for Mobile and Stationary Applications” Group in the International Energy Agency (IEA) Hydrogen Task 32 “Hydrogen-based energy storage” different compounds have been and will be scaled-up in the near future and tested in the range of 500 g to several hundred kg for use in hydrogen storage applications The research for the lab-scale compressor is part of the activities of SCCER HaE, which is financially supported by Innosuisse - Swiss Innovation Agency . The authors thank the Alexander von Humboldt Foundation in the frame of the post-doctoral fellowship of Dr. J. Puszkiel (No. 1187279 STP ) as well as the European Union for their funding of projects STORHY (contract Nr. SES6-CT-2004-502667 , FP6-2002-Energy-1, 6.1.3.2.2), NESSHY (contract Nr. 518271 , FP6-2004-Energy-3, 6.1.3.2.2) and the EU Horizon 2020 /RISE project HYDRIDE4MOBILITY. Financial support from the S02 and KP8 S05), the European Union's Seventh Framework Programme ( FP7/2007e2013 ) for the Fuel Cells and Hydrogen Joint Technology Initiative under grant agreement no. 256653 (SSH2S), from the European Fuel Cells and Hydrogen Joint Undertaking in the framework of BOR4STORE (Grant agreement no. 303428 ), from the Australian Research Council for grants LP120101848 , LP150100730 , and LE0989180 , The Innovation Fund Denmark (project HyFill-Fast), DST within Hydrogen South Africa/HySA programme (projects KP3 National Research Foundation/NRF of South Africa , incentive funding grant number 109092 and the Research Council of Norway (project 285147 ) is thankfully acknowledged

Countries
Denmark, Australia, Italy, Norway, Australia, Italy, Norway, Norway, Argentina, Argentina, Australia, Spain
Keywords

Technology, Materiales / Ciencia de los Materiales, Energy & Fuels, FLAME PROPAGATION, Engineering, METAL HYDRIDES, https://purl.org/becyt/ford/2.5, Physical, Electrochemistry, Metal hydrides, CRYSTAL-STRUCTURE, https://purl.org/becyt/ford/2, COMPLEX HYDRIDES, METAL-HYDRIDE, HEAT-STORAGE, RENEWABLE ENERGY, Science & Technology, SORPTION BEHAVIOR, Hydrogen compression, HYDROGEN STORAGE, Física, 600, Hydrogen compression; Hydrogen storage; Metal hydrides; Renewable Energy, Sustainability and the Environment; Fuel Technology; Condensed Matter Physics; Energy Engineering and Power Technology, Hydrogen storage; Hydrogen compression; Metal hydrides, Hydrogen storage, 540, SPONTANEOUS IGNITION, 620, Chemistry, Chemical sciences, Physical Sciences, FUEL-CELL VEHICLE, HYDROGEN COMPRESSION, THERMODYNAMIC PROPERTIES, ddc: ddc:620.11

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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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