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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Analytica...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Journal of Analytical and Applied Pyrolysis
Article . 2013 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Validation of a new set-up for continuous catalytic fast pyrolysis of biomass coupled with vapour phase upgrading

Authors: Marko Djokic; Ruben van Duren; Kevin Van Geem; Marty Pronk; Güray Yildiz; Frederik Ronsse; Wolter Prins;

Validation of a new set-up for continuous catalytic fast pyrolysis of biomass coupled with vapour phase upgrading

Abstract

Abstract A fully controlled, continuously operated mini-plant has been designed and constructed based on auger reactor technology. Three types of biomass fast pyrolysis experiments were performed in this set-up, viz. non-catalytic, in situ catalytic fast pyrolysis and ex situ upgrading of non-catalytic fast pyrolysis vapours by means of a downstream, moving-bed catalytic reactor. Pine wood was selected as the reference biomass feedstock. The mini-plant enables variation of the catalyst loading and contact times while producing larger samples suitable for full characterization in continuous operation. Due to short catalyst residence times and the fact that the biomass fed to the reactor is always brought into contact with fresh catalyst (in case of in situ catalysis) or the pyrolysis vapours always contact with fresh catalyst in the moving bed catalytic reactor (in case of ex situ catalysis), catalyst deactivation and coking are prevented ensuring improved experimental repeatability in catalytic pyrolysis experiments. The performance of the system was verified by in- and ex situ application of a single type of heterogeneous ZSM-5 based acidic catalyst while the non-catalytic results were taken as reference. Catalytic fast pyrolysis results in more effective oxygen removal from the bio-oil in the form of water, and resulting in lower yields of the organic fraction. Moreover catalytic decarbonylation reactions gave rise to increased gas yields. With in- and ex situ catalysis, increases in the char yields were observed as well as coke deposition on the catalyst surface. GC × GC-FID and GC × GC-TOF-MS analysis of the produced bio-oils showed that the use of in- and ex situ catalysis causes conversion of high molecular weight compounds to lower ones. Disappearance of detectable sugars and aldehydes, a decrease of the yield of acids, formation of phenols, and favoured aromatics production were the other catalytic effects observed.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
98
Top 10%
Top 10%
Top 1%